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Thermodynamic analysis of a hard coal oxyfuel power plant with high temperature three-end membrane for air separation

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  • Castillo, Renzo

Abstract

Cryogenic air separation is a mature state-of-the-art technology to produce the high tonnage of oxygen required for oxyfuel power plants. However, this technology represents an important burden to the net plant efficiency (losses between 8% and 12%-points). High temperature ceramic membranes, associated with significantly lower efficiency losses, are foreseen as the best candidate to challenge cryogenics for high tonnage oxygen production. Although this technology is still at an embryonic state of development, the three-end membrane operation mode offers important technical advantages over the four-end mode that can be a good technological option in the near future. This paper analyzes the influence of both, the cryogenic and three-end high temperature membrane air separation units on the net oxyfuel plant efficiency considering the same boundary conditions and different equivalent thermal integrations. Moreover, the oxygen permeation rate, heat recovery, and required membrane area are also evaluated at different membrane operating conditions. Using a state-of-the-art perovskite BSCF as membrane material, net plant efficiency losses up to 5.1%-points can be reached requiring around 400,000Â m2 of membrane area. Applying this membrane-based technology it is possible to improve the oxyfuel plant efficiency over 4%-points (compared with cryogenic technology); however, it is still necessary to develop new ceramic materials to reduce the amount of membrane area required.

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  • Castillo, Renzo, 2011. "Thermodynamic analysis of a hard coal oxyfuel power plant with high temperature three-end membrane for air separation," Applied Energy, Elsevier, vol. 88(5), pages 1480-1493, May.
  • Handle: RePEc:eee:appene:v:88:y:2011:i:5:p:1480-1493
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    4. Janusz Kotowicz & Sebastian Michalski & Mateusz Brzęczek, 2019. "The Characteristics of a Modern Oxy-Fuel Power Plant," Energies, MDPI, vol. 12(17), pages 1-34, September.
    5. Habib, Mohamed A. & Imteyaz, Binash & Nemitallah, Medhat A., 2020. "Second law analysis of premixed and non-premixed oxy-fuel combustion cycles utilizing oxygen separation membranes," Applied Energy, Elsevier, vol. 259(C).
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    7. Shin, Donghwan & Kang, Sanggyu, 2018. "Numerical analysis of an ion transport membrane system for oxy–fuel combustion," Applied Energy, Elsevier, vol. 230(C), pages 875-888.
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    9. Janusz-Szymańska, Katarzyna & Dryjańska, Aleksandra, 2015. "Possibilities for improving the thermodynamic and economic characteristics of an oxy-type power plant with a cryogenic air separation unit," Energy, Elsevier, vol. 85(C), pages 45-61.
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    19. Gładysz, Paweł & Stanek, Wojciech & Czarnowska, Lucyna & Węcel, Gabriel & Langørgen, Øyvind, 2017. "Thermodynamic assessment of an integrated MILD oxyfuel combustion power plant," Energy, Elsevier, vol. 137(C), pages 761-774.
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    21. Cabral, Renato P. & Mac Dowell, Niall, 2017. "A novel methodological approach for achieving £/MWh cost reduction of CO2 capture and storage (CCS) processes," Applied Energy, Elsevier, vol. 205(C), pages 529-539.
    22. Serrano, José Ramón & Arnau, Francisco José & García-Cuevas, Luis Miguel & Gutiérrez, Fabio Alberto, 2022. "Thermo-economic analysis of an oxygen production plant powered by an innovative energy recovery system," Energy, Elsevier, vol. 255(C).

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