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Thermodynamic analysis of a hard coal oxyfuel power plant with high temperature three-end membrane for air separation

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  • Castillo, Renzo

Abstract

Cryogenic air separation is a mature state-of-the-art technology to produce the high tonnage of oxygen required for oxyfuel power plants. However, this technology represents an important burden to the net plant efficiency (losses between 8% and 12%-points). High temperature ceramic membranes, associated with significantly lower efficiency losses, are foreseen as the best candidate to challenge cryogenics for high tonnage oxygen production. Although this technology is still at an embryonic state of development, the three-end membrane operation mode offers important technical advantages over the four-end mode that can be a good technological option in the near future. This paper analyzes the influence of both, the cryogenic and three-end high temperature membrane air separation units on the net oxyfuel plant efficiency considering the same boundary conditions and different equivalent thermal integrations. Moreover, the oxygen permeation rate, heat recovery, and required membrane area are also evaluated at different membrane operating conditions. Using a state-of-the-art perovskite BSCF as membrane material, net plant efficiency losses up to 5.1%-points can be reached requiring around 400,000Â m2 of membrane area. Applying this membrane-based technology it is possible to improve the oxyfuel plant efficiency over 4%-points (compared with cryogenic technology); however, it is still necessary to develop new ceramic materials to reduce the amount of membrane area required.

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  • Castillo, Renzo, 2011. "Thermodynamic analysis of a hard coal oxyfuel power plant with high temperature three-end membrane for air separation," Applied Energy, Elsevier, vol. 88(5), pages 1480-1493, May.
    • Handle: RePEc:eee:appene:v:88:y:2011:i:5:p:1480-1493
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    3. Habib, Mohamed A. & Imteyaz, Binash & Nemitallah, Medhat A., 2020. "Second law analysis of premixed and non-premixed oxy-fuel combustion cycles utilizing oxygen separation membranes," Applied Energy, Elsevier, vol. 259(C).
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    5. Puig-Arnavat, Maria & Søgaard, Martin & Hjuler, Klaus & Ahrenfeldt, Jesper & Henriksen, Ulrik Birk & Hendriksen, Peter Vang, 2015. "Integration of oxygen membranes for oxygen production in cement plants," Energy, Elsevier, vol. 91(C), pages 852-865.
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    7. Gładysz, Paweł & Stanek, Wojciech & Czarnowska, Lucyna & Sładek, Sławomir & Szlęk, Andrzej, 2018. "Thermo-ecological evaluation of an integrated MILD oxy-fuel combustion power plant with CO2 capture, utilisation, and storage – A case study in Poland," Energy, Elsevier, vol. 144(C), pages 379-392.
    8. Miroslav Variny & Dominika Jediná & Miroslav Rimár & Ján Kizek & Marianna Kšiňanová, 2021. "Cutting Oxygen Production-Related Greenhouse Gas Emissions by Improved Compression Heat Management in a Cryogenic Air Separation Unit," IJERPH, MDPI, vol. 18(19), pages 1-32, October.
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    11. Meriläinen, Arttu & Seppälä, Ari & Kauranen, Pertti, 2012. "Minimizing specific energy consumption of oxygen enrichment in polymeric hollow fiber membrane modules," Applied Energy, Elsevier, vol. 94(C), pages 285-294.
    12. Prabu, V. & Jayanti, S., 2012. "Underground coal-air gasification based solid oxide fuel cell system," Applied Energy, Elsevier, vol. 94(C), pages 406-414.
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    14. Cabral, Renato P. & Mac Dowell, Niall, 2017. "A novel methodological approach for achieving £/MWh cost reduction of CO2 capture and storage (CCS) processes," Applied Energy, Elsevier, vol. 205(C), pages 529-539.
    15. Serrano, José Ramón & Arnau, Francisco José & García-Cuevas, Luis Miguel & Gutiérrez, Fabio Alberto, 2022. "Thermo-economic analysis of an oxygen production plant powered by an innovative energy recovery system," Energy, Elsevier, vol. 255(C).
    16. Kotowicz, Janusz & Michalski, Sebastian, 2015. "Influence of four-end HTM (high temperature membrane) parameters on the thermodynamic and economic characteristics of a supercritical power plant," Energy, Elsevier, vol. 81(C), pages 662-673.
    17. Janusz Kotowicz & Sebastian Michalski & Mateusz Brzęczek, 2019. "The Characteristics of a Modern Oxy-Fuel Power Plant," Energies, MDPI, vol. 12(17), pages 1-34, September.
    18. Shin, Donghwan & Kang, Sanggyu, 2018. "Numerical analysis of an ion transport membrane system for oxy–fuel combustion," Applied Energy, Elsevier, vol. 230(C), pages 875-888.
    19. Janusz-Szymańska, Katarzyna & Dryjańska, Aleksandra, 2015. "Possibilities for improving the thermodynamic and economic characteristics of an oxy-type power plant with a cryogenic air separation unit," Energy, Elsevier, vol. 85(C), pages 45-61.
    20. García-Luna, S. & Ortiz, C. & Carro, A. & Chacartegui, R. & Pérez-Maqueda, L.A., 2022. "Oxygen production routes assessment for oxy-fuel combustion," Energy, Elsevier, vol. 254(PB).
    21. Kotowicz, Janusz & Michalski, Sebastian, 2014. "Efficiency analysis of a hard-coal-fired supercritical power plant with a four-end high-temperature membrane for air separation," Energy, Elsevier, vol. 64(C), pages 109-119.
    22. Gładysz, Paweł & Stanek, Wojciech & Czarnowska, Lucyna & Węcel, Gabriel & Langørgen, Øyvind, 2017. "Thermodynamic assessment of an integrated MILD oxyfuel combustion power plant," Energy, Elsevier, vol. 137(C), pages 761-774.

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