IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v358y2024ics0306261924000035.html
   My bibliography  Save this article

Iron powder in-situ catalytic pyrolysis on coated wooden board: Kinetic, products, and recovery

Author

Listed:
  • Chen, Qindong
  • Yue, Yuanmao
  • Zhang, Chao
  • Dong, Zihang
  • Wang, Ning
  • Yuan, Tugui
  • Xu, Qiyong

Abstract

Catalytic pyrolysis is a promising method for the resource utilization of wooden waste, and in-situ catalysis enhances the process and reduces treatment costs. The selection of catalysts is crucial, as their catalytic effect and service life directly impact treatment effectiveness and economic benefits. In this study, iron powder was utilized to examine its potential in in-situ catalytic pyrolysis of coated wooden boards. The results showed that some of the iron powder could compete for oxygen from lignin/ hemicellulose during the early pyrolysis stage, resulting in the formation of FeO and a decrease in CO2. The formed FeO then promoted cellulose decomposition, reducing the pyrolysis activation energy by 26% ∼ 48%. Despite the addition of iron powder, no obvious impact was observed on the distribution of product yields. However, there are differences in the specific composition: the gas products showed a decrease of CO2 by 26% and CH4 by 13%, while the bio-oil showed an increase of phenol by 8%. This revealed that the iron powder primarily changed the energy barrier of the pyrolysis reaction. There was magnetic separation followed by particle size screening for the recovery of solid products. After separation, the recovery rate of iron powder was determined to be only 65.39%. Two kinds of char particles appeared in the separated products: magnetic (M3) and non-magnetic (NM). Approximately 44.45% of total Fe (from Fe powder and coating materials) contents and 73.62% of total Ti (main metal in the primary coating) were found in M3, while only 1.32% and 10.90% in NM, respectively. Interestingly, the distribution of elements Zn, Ba, and Mg was found to be opposite to that of Fe, which mainly distributed in NM and M2. It might be attributed to the primary coating on the M3 surface, which likely to help facilitated the adsorption of iron particles according to the combination of SEM/EDS and ICP-MS results. The adsorption competition effect of Fe and other metals resulted in significant differences in the distribution of metals on several char particles.

Suggested Citation

  • Chen, Qindong & Yue, Yuanmao & Zhang, Chao & Dong, Zihang & Wang, Ning & Yuan, Tugui & Xu, Qiyong, 2024. "Iron powder in-situ catalytic pyrolysis on coated wooden board: Kinetic, products, and recovery," Applied Energy, Elsevier, vol. 358(C).
    • Handle: RePEc:eee:appene:v:358:y:2024:i:c:s0306261924000035
    DOI: 10.1016/j.apenergy.2024.122620
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261924000035
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2024.122620?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Chen, Qindong & Hu, Song & Xu, Qiyong & Su, Sheng & Wang, Yi & Xu, Kai & He, Limo & Xiang, Jun, 2021. "Steam synergic effect on oxygen carrier performance and WGS promotion ability of iron-oxides," Energy, Elsevier, vol. 215(PA).
    2. Yildiz, Güray & Ronsse, Frederik & Duren, Ruben van & Prins, Wolter, 2016. "Challenges in the design and operation of processes for catalytic fast pyrolysis of woody biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1596-1610.
    3. Xia, Sunwen & Yang, Haiping & Lei, shuaishuai & Lu, Wang & Cai, Ning & Xiao, Haoyu & Chen, Yingquan & Chen, Hanping, 2023. "Iron salt catalytic pyrolysis of biomass: Influence of iron salt type," Energy, Elsevier, vol. 262(PA).
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Perkins, Greg & Bhaskar, Thallada & Konarova, Muxina, 2018. "Process development status of fast pyrolysis technologies for the manufacture of renewable transport fuels from biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 292-315.
    2. Beims, R.F. & Simonato, C.L. & Wiggers, V.R., 2019. "Technology readiness level assessment of pyrolysis of trygliceride biomass to fuels and chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 112(C), pages 521-529.
    3. Bonassa, Gabriela & Schneider, Lara Talita & Canever, Victor Bruno & Cremonez, Paulo André & Frigo, Elisandro Pires & Dieter, Jonathan & Teleken, Joel Gustavo, 2018. "Scenarios and prospects of solid biofuel use in Brazil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2365-2378.
    4. Mari Rowena C. Tanquilut & Homer C. Genuino & Erwin Wilbers & Rossana Marie C. Amongo & Delfin C. Suministrado & Kevin F. Yaptenco & Marilyn M. Elauria & Jessie C. Elauria & Hero J. Heeres, 2020. "Biorefining of Pigeon Pea: Residue Conversion by Pyrolysis," Energies, MDPI, vol. 13(11), pages 1-19, June.
    5. Merckel, Ryan D. & Heydenrych, Mike D. & Sithole, Bruce B., 2021. "Pyrolysis oil composition and catalytic activity estimated by cumulative mass analysis using Py-GC/MS EGA-MS," Energy, Elsevier, vol. 219(C).
    6. Arteaga-Pérez, Luis E. & Gómez Cápiro, Oscar & Romero, Romina & Delgado, Aaron & Olivera, Patricia & Ronsse, Frederik & Jiménez, Romel, 2017. "In situ catalytic fast pyrolysis of crude and torrefied Eucalyptus globulus using carbon aerogel-supported catalysts," Energy, Elsevier, vol. 128(C), pages 701-712.
    7. Saraeian, Alireza & Nolte, Michael W. & Shanks, Brent H., 2019. "Deoxygenation of biomass pyrolysis vapors: Improving clarity on the fate of carbon," Renewable and Sustainable Energy Reviews, Elsevier, vol. 104(C), pages 262-280.
    8. Zhang, Yu & Jiang, Haifeng & Li, Yuhang & Jia, Wei & Song, Meng & Hong, Wenpeng, 2024. "Efficient production of furans by CO2-assisted pyrolysis of cellulose with carbon-supported Ni/Co catalysts," Energy, Elsevier, vol. 294(C).
    9. Jacek Grams & Agnieszka M. Ruppert, 2017. "Development of Heterogeneous Catalysts for Thermo-Chemical Conversion of Lignocellulosic Biomass," Energies, MDPI, vol. 10(4), pages 1-25, April.
    10. Malico, Isabel & Nepomuceno Pereira, Ricardo & Gonçalves, Ana Cristina & Sousa, Adélia M.O., 2019. "Current status and future perspectives for energy production from solid biomass in the European industry," Renewable and Sustainable Energy Reviews, Elsevier, vol. 112(C), pages 960-977.
    11. Palizdar, A. & Sadrameli, S.M., 2020. "Catalytic upgrading of biomass pyrolysis oil over tailored hierarchical MFI zeolite: Effect of porosity enhancement and porosity-acidity interaction on deoxygenation reactions," Renewable Energy, Elsevier, vol. 148(C), pages 674-688.
    12. Duan, Dengle & Zhang, Yayun & Wang, Yunpu & Lei, Hanwu & Wang, Qin & Ruan, Roger, 2020. "Production of renewable jet fuel and gasoline range hydrocarbons from catalytic pyrolysis of soapstock over corn cob-derived activated carbons," Energy, Elsevier, vol. 209(C).
    13. Wu, Yan & Yu, Yue & Zhu, Ailing & Fu, Junjie & Xia, Yaping & Lan, Guoxing & Fu, Chuan & Ma, Zhicheng & Xue, Jianfu & Tao, Lin & Xie, Xinrui, 2024. "Effect of different digestate biochars as promoters via sludge anaerobic digestion on subsequent pyrolysis products: Focusing on the nitrogen, sulfur, and chlorine releasing characteristics," Renewable Energy, Elsevier, vol. 226(C).
    14. Zhang, Huiyan & Ma, Yuna & Shao, Shanshan & Xiao, Rui, 2017. "The effects of potassium on distributions of bio-oils obtained from fast pyrolysis of agricultural and forest biomass in a fluidized bed," Applied Energy, Elsevier, vol. 208(C), pages 867-877.
    15. Naqvi, Salman Raza & Jamshaid, Sana & Naqvi, Muhammad & Farooq, Wasif & Niazi, Muhammad Bilal Khan & Aman, Zaeem & Zubair, Muhammad & Ali, Majid & Shahbaz, Muhammad & Inayat, Abrar & Afzal, Waheed, 2018. "Potential of biomass for bioenergy in Pakistan based on present case and future perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 1247-1258.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:358:y:2024:i:c:s0306261924000035. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.