IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v208y2017icp867-877.html
   My bibliography  Save this article

The effects of potassium on distributions of bio-oils obtained from fast pyrolysis of agricultural and forest biomass in a fluidized bed

Author

Listed:
  • Zhang, Huiyan
  • Ma, Yuna
  • Shao, Shanshan
  • Xiao, Rui

Abstract

Potassium, due to its strong catalytic effects on biomass pyrolysis vapors, has great influence on the components of the obtained bio-oil. In this work, fast pyrolysis of acid washed and potassium salts impregnated feedstocks (camphor branch, corn cob and walnut shell) were carried out in a fluidized bed. The effects of potassium and the ash in biomass on yields and selectivities of bio-oil compounds were studied. The results showed that the walnut shells yielded the greatest amount of phenol and acids. Potassium promoted the conversion of large molecular compounds (such as levoglucosan) to furans. The existence of potassium reduced the yield of aldehydes and enhanced that of furfural. With the assistance of potassium, the selectivity of monophenols (phenol, methyl phenol, dimethyl phenol, etc.) decreased significantly to around half, while that of polyphenols (ethyl phenol, 2-allylphenol, 4-(2-propenyl)-phenol, 2-allyl-4-methylphenol, etc.) increased obviously. Finally, a possible reaction pathway indicating potassium influences on biomass pyrolysis was proposed according to the experimental results.

Suggested Citation

  • Zhang, Huiyan & Ma, Yuna & Shao, Shanshan & Xiao, Rui, 2017. "The effects of potassium on distributions of bio-oils obtained from fast pyrolysis of agricultural and forest biomass in a fluidized bed," Applied Energy, Elsevier, vol. 208(C), pages 867-877.
    • Handle: RePEc:eee:appene:v:208:y:2017:i:c:p:867-877
    DOI: 10.1016/j.apenergy.2017.09.062
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261917313442
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2017.09.062?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Wang, Kaige & Zhang, Jing & Shanks, Brent H. & Brown, Robert C., 2015. "The deleterious effect of inorganic salts on hydrocarbon yields from catalytic pyrolysis of lignocellulosic biomass and its mitigation," Applied Energy, Elsevier, vol. 148(C), pages 115-120.
    2. Yildiz, Güray & Ronsse, Frederik & Duren, Ruben van & Prins, Wolter, 2016. "Challenges in the design and operation of processes for catalytic fast pyrolysis of woody biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1596-1610.
    3. Lehto, Jani & Oasmaa, Anja & Solantausta, Yrjö & Kytö, Matti & Chiaramonti, David, 2014. "Review of fuel oil quality and combustion of fast pyrolysis bio-oils from lignocellulosic biomass," Applied Energy, Elsevier, vol. 116(C), pages 178-190.
    4. Yin, Sudong & Tan, Zhongchao, 2012. "Hydrothermal liquefaction of cellulose to bio-oil under acidic, neutral and alkaline conditions," Applied Energy, Elsevier, vol. 92(C), pages 234-239.
    5. Meier, Dietrich & van de Beld, Bert & Bridgwater, Anthony V. & Elliott, Douglas C. & Oasmaa, Anja & Preto, Fernando, 2013. "State-of-the-art of fast pyrolysis in IEA bioenergy member countries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 20(C), pages 619-641.
    6. Peters, Jens F. & Banks, Scott W. & Bridgwater, Anthony V. & Dufour, Javier, 2017. "A kinetic reaction model for biomass pyrolysis processes in Aspen Plus," Applied Energy, Elsevier, vol. 188(C), pages 595-603.
    7. Görling, Martin & Larsson, Mårten & Alvfors, Per, 2013. "Bio-methane via fast pyrolysis of biomass," Applied Energy, Elsevier, vol. 112(C), pages 440-447.
    8. Lerkkasemsan, Nuttapol, 2017. "Fuzzy logic-based predictive model for biomass pyrolysis," Applied Energy, Elsevier, vol. 185(P2), pages 1019-1030.
    9. Corton, J. & Donnison, I.S. & Patel, M. & Bühle, L. & Hodgson, E. & Wachendorf, M. & Bridgwater, A. & Allison, G. & Fraser, M.D., 2016. "Expanding the biomass resource: sustainable oil production via fast pyrolysis of low input high diversity biomass and the potential integration of thermochemical and biological conversion routes," Applied Energy, Elsevier, vol. 177(C), pages 852-862.
    10. Delattin, F. & De Ruyck, J. & Bram, S., 2009. "Detailed study of the impact of co-utilization of biomass in a natural gas combined cycle power plant through perturbation analysis," Applied Energy, Elsevier, vol. 86(5), pages 622-629, May.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhang, Yiyun & Wang, Jia & Jiang, Jianchun & Guo, Xiaobo, 2024. "Enhancing coking resistance of ZSM-5 in the conversion of pine sawdust into oxygen-free bio-aromatic hydrocarbons through tandem catalytic hydropyrolysis/vapor-phase hydrotreatment," Energy, Elsevier, vol. 289(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Perkins, Greg & Bhaskar, Thallada & Konarova, Muxina, 2018. "Process development status of fast pyrolysis technologies for the manufacture of renewable transport fuels from biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 292-315.
    2. Peters, Jens F. & Banks, Scott W. & Bridgwater, Anthony V. & Dufour, Javier, 2017. "A kinetic reaction model for biomass pyrolysis processes in Aspen Plus," Applied Energy, Elsevier, vol. 188(C), pages 595-603.
    3. Campuzano, Felipe & Brown, Robert C. & Martínez, Juan Daniel, 2019. "Auger reactors for pyrolysis of biomass and wastes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 102(C), pages 372-409.
    4. Kung, Chih-Chun & Mu, Jianhong E., 2019. "Prospect of China's renewable energy development from pyrolysis and biochar applications under climate change," Renewable and Sustainable Energy Reviews, Elsevier, vol. 114(C), pages 1-1.
    5. Braimakis, Konstantinos & Atsonios, Konstantinos & Panopoulos, Kyriakos D. & Karellas, Sotirios & Kakaras, Emmanuel, 2014. "Economic evaluation of decentralized pyrolysis for the production of bio-oil as an energy carrier for improved logistics towards a large centralized gasification plant," Renewable and Sustainable Energy Reviews, Elsevier, vol. 35(C), pages 57-72.
    6. Douvartzides, Savvas & Charisiou, Nikolaos D. & Wang, Wen & Papadakis, Vagelis G. & Polychronopoulou, Kyriaki & Goula, Maria A., 2022. "Catalytic fast pyrolysis of agricultural residues and dedicated energy crops for the production of high energy density transportation biofuels. Part I: Chemical pathways and bio-oil upgrading," Renewable Energy, Elsevier, vol. 185(C), pages 483-505.
    7. Chiappero, Marco & Norouzi, Omid & Hu, Mingyu & Demichelis, Francesca & Berruti, Franco & Di Maria, Francesco & Mašek, Ondřej & Fiore, Silvia, 2020. "Review of biochar role as additive in anaerobic digestion processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 131(C).
    8. Hu, Xun & Lievens, Caroline & Mourant, Daniel & Wang, Yi & Wu, Liping & Gunawan, Richard & Song, Yao & Li, Chun-Zhu, 2013. "Investigation of deactivation mechanisms of a solid acid catalyst during esterification of the bio-oils from mallee biomass," Applied Energy, Elsevier, vol. 111(C), pages 94-103.
    9. Borello, D. & Cedola, L. & Frangioni, G.V. & Meloni, R. & Venturini, P. & De Filippis, P. & de Caprariis, B., 2016. "Development of a numerical model for biomass packed bed pyrolysis based on experimental validation," Applied Energy, Elsevier, vol. 164(C), pages 956-962.
    10. Heena Panchasara & Nanjappa Ashwath, 2021. "Effects of Pyrolysis Bio-Oils on Fuel Atomisation—A Review," Energies, MDPI, vol. 14(4), pages 1-22, February.
    11. Yang, Y. & Heaven, S. & Venetsaneas, N. & Banks, C.J. & Bridgwater, A.V., 2018. "Slow pyrolysis of organic fraction of municipal solid waste (OFMSW): Characterisation of products and screening of the aqueous liquid product for anaerobic digestion," Applied Energy, Elsevier, vol. 213(C), pages 158-168.
    12. Saraeian, Alireza & Nolte, Michael W. & Shanks, Brent H., 2019. "Deoxygenation of biomass pyrolysis vapors: Improving clarity on the fate of carbon," Renewable and Sustainable Energy Reviews, Elsevier, vol. 104(C), pages 262-280.
    13. Broumand, Mohsen & Khan, Muhammad Shahzeb & Yun, Sean & Hong, Zekai & Thomson, Murray J., 2021. "Feasibility of running a micro gas turbine on wood-derived fast pyrolysis bio-oils: Effect of the fuel spray formation and preparation," Renewable Energy, Elsevier, vol. 178(C), pages 775-784.
    14. Roy, Poritosh & Dias, Goretty, 2017. "Prospects for pyrolysis technologies in the bioenergy sector: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 59-69.
    15. Byun, Jaewon & Han, Jeehoon, 2016. "Process synthesis and analysis for catalytic conversion of lignocellulosic biomass to fuels: Separate conversion of cellulose and hemicellulose using 2-sec-butylphenol (SBP) solvent," Applied Energy, Elsevier, vol. 171(C), pages 483-490.
    16. Raud, M. & Kikas, T. & Sippula, O. & Shurpali, N.J., 2019. "Potentials and challenges in lignocellulosic biofuel production technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 111(C), pages 44-56.
    17. Lee, Seokhwan & Woo, Sang Hee & Kim, Yongrae & Choi, Young & Kang, Kernyong, 2020. "Combustion and emission characteristics of a diesel-powered generator running with N-butanol/coffee ground pyrolysis oil/diesel blended fuel," Energy, Elsevier, vol. 206(C).
    18. Zhang, Jiyuan & Tang, Hailong & Chen, Min, 2019. "Linear substitute model-based uncertainty analysis of complicated non-linear energy system performance (case study of an adaptive cycle engine)," Applied Energy, Elsevier, vol. 249(C), pages 87-108.
    19. Lehto, Jani & Oasmaa, Anja & Solantausta, Yrjö & Kytö, Matti & Chiaramonti, David, 2014. "Review of fuel oil quality and combustion of fast pyrolysis bio-oils from lignocellulosic biomass," Applied Energy, Elsevier, vol. 116(C), pages 178-190.
    20. Peters, Jens F. & Petrakopoulou, Fontina & Dufour, Javier, 2015. "Exergy analysis of synthetic biofuel production via fast pyrolysis and hydroupgrading," Energy, Elsevier, vol. 79(C), pages 325-336.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:208:y:2017:i:c:p:867-877. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.