IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v292y2021ics0306261921003998.html
   My bibliography  Save this article

Facile technique to encapsulate phase change material in an amphiphilic polymeric matrix for thermal energy storage

Author

Listed:
  • Pandey, Kalpana
  • Ali, Sana Fatima
  • Gupta, Sumit Kumar
  • Saikia, Pranaynil
  • Rakshit, Dibakar
  • Saha, Sampa

Abstract

A facile fabrication technique of producing novel porous microcapsules encapsulating n-Eicosane as phase change material (PCM) with a random copolymer of poly (methyl methacrylate0.9-co-2-hydroxyethyl methacrylate0.1) (poly(MMA0.9-co-HEMA0.1)) as shell material is being reported. The porous microparticles (particle size: 31.8 ± 9 µm; porosity: ~30 ± 13%) with a hollow core (shell thickness: 1.60 ± 0.2 µm) were obtained by adopting a synthetic pathway of hot water assisted double emulsion (water/oil/water) system. Strikingly, the microcapsule system was found to entrap > 95% n-Eicosane, thus achieving significantly high thermal energy storage capability (~95%). The porous microcapsules with a phase transition enthalpy of ~ 160 J/g exhibited high phase transfer repeatability and long durability. The non-isothermal and isothermal DSC study further revealed the heat charging and discharging conditions for the microcapsules. Moreover, in contrast to neat hydrophobic PCM, the porous particles with partially hydrophilic shell (owing to polyHEMA unit) displayed better water dispersibility along with efficient thermal management characteristic as revealed by Infrared thermography. Thus, the microencapsulated phase change material in porous microcapsules can be a smart combination of good thermal energy storage function with wettability. Potentially such microcapsules may be exploited as thermal energy storage materials for space conditioning in buildings because of the suitable phase transition temperature (37 °C) displayed by the selected PCM (n-Eicosane). Our study comprehensively demonstrated water dispersible porous polymeric particles with significantly high thermal energy storage (>95%) performance that was not reported till date.

Suggested Citation

  • Pandey, Kalpana & Ali, Sana Fatima & Gupta, Sumit Kumar & Saikia, Pranaynil & Rakshit, Dibakar & Saha, Sampa, 2021. "Facile technique to encapsulate phase change material in an amphiphilic polymeric matrix for thermal energy storage," Applied Energy, Elsevier, vol. 292(C).
    • Handle: RePEc:eee:appene:v:292:y:2021:i:c:s0306261921003998
    DOI: 10.1016/j.apenergy.2021.116917
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261921003998
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2021.116917?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. SarI, Ahmet & Alkan, Cemil & Karaipekli, Ali, 2010. "Preparation, characterization and thermal properties of PMMA/n-heptadecane microcapsules as novel solid-liquid microPCM for thermal energy storage," Applied Energy, Elsevier, vol. 87(5), pages 1529-1534, May.
    2. Rao, Zhonghao & Wang, Shuangfeng & Peng, Feifei & Zhang, Wei & Zhang, Yanlai, 2012. "Dissipative particle dynamics investigation of microencapsulated thermal energy storage phase change materials," Energy, Elsevier, vol. 44(1), pages 805-812.
    3. Saxena, Rajat & Rakshit, Dibakar & Kaushik, S.C., 2020. "Experimental assessment of Phase Change Material (PCM) embedded bricks for passive conditioning in buildings," Renewable Energy, Elsevier, vol. 149(C), pages 587-599.
    4. Li, Gang & Zheng, Xuefei, 2016. "Thermal energy storage system integration forms for a sustainable future," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 736-757.
    5. Ling, Ziye & Wen, Xiaoyan & Zhang, Zhengguo & Fang, Xiaoming & Gao, Xuenong, 2018. "Thermal management performance of phase change materials with different thermal conductivities for Li-ion battery packs operated at low temperatures," Energy, Elsevier, vol. 144(C), pages 977-983.
    6. Nikpourian, Hediyeh & Bahramian, Ahmad Reza & Abdollahi, Mahdi, 2020. "On the thermal performance of a novel PCM nanocapsule: The effect of core/shell," Renewable Energy, Elsevier, vol. 151(C), pages 322-331.
    7. Milián, Yanio E. & Gutiérrez, Andrea & Grágeda, Mario & Ushak, Svetlana, 2017. "A review on encapsulation techniques for inorganic phase change materials and the influence on their thermophysical properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 983-999.
    8. Yin, Dezhong & Ma, Li & Liu, Jinjie & Zhang, Qiuyu, 2014. "Pickering emulsion: A novel template for microencapsulated phase change materials with polymer–silica hybrid shell," Energy, Elsevier, vol. 64(C), pages 575-581.
    9. Alva, Guruprasad & Lin, Yaxue & Fang, Guiyin, 2018. "An overview of thermal energy storage systems," Energy, Elsevier, vol. 144(C), pages 341-378.
    10. Sun, Kun & Liu, Huan & Wang, Xiaodong & Wu, Dezhen, 2019. "Innovative design of superhydrophobic thermal energy-storage materials by microencapsulation of n-docosane with nanostructured ZnO/SiO2 shell," Applied Energy, Elsevier, vol. 237(C), pages 549-565.
    11. Du, Kun & Calautit, John & Wang, Zhonghua & Wu, Yupeng & Liu, Hao, 2018. "A review of the applications of phase change materials in cooling, heating and power generation in different temperature ranges," Applied Energy, Elsevier, vol. 220(C), pages 242-273.
    12. Sharma, Atul & Tyagi, V.V. & Chen, C.R. & Buddhi, D., 2009. "Review on thermal energy storage with phase change materials and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(2), pages 318-345, February.
    13. Zhang, Xiaoyu & Wang, Xiaodong & Wu, Dezhen, 2016. "Design and synthesis of multifunctional microencapsulated phase change materials with silver/silica double-layered shell for thermal energy storage, electrical conduction and antimicrobial effectivene," Energy, Elsevier, vol. 111(C), pages 498-512.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chinnasamy, Veerakumar & Heo, Jaehyeok & Jung, Sungyong & Lee, Hoseong & Cho, Honghyun, 2023. "Shape stabilized phase change materials based on different support structures for thermal energy storage applications–A review," Energy, Elsevier, vol. 262(PB).
    2. Palmer, Ben & Arshad, Adeel & Yang, Yan & Wen, Chuang, 2023. "Energy storage performance improvement of phase change materials-based triplex-tube heat exchanger (TTHX) using liquid–solid interface-informed fin configurations," Applied Energy, Elsevier, vol. 333(C).
    3. Liu, Changhui & Xiao, Tong & Zhao, Jiateng & Liu, Qingyi & Sun, Wenjie & Guo, Chenglong & Ali, Hafiz Muhammad & Chen, Xiao & Rao, Zhonghao & Gu, Yanlong, 2023. "Polymer engineering in phase change thermal storage materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sun, Kun & Liu, Huan & Wang, Xiaodong & Wu, Dezhen, 2019. "Innovative design of superhydrophobic thermal energy-storage materials by microencapsulation of n-docosane with nanostructured ZnO/SiO2 shell," Applied Energy, Elsevier, vol. 237(C), pages 549-565.
    2. Li, Zhi & Lu, Yiji & Huang, Rui & Chang, Jinwei & Yu, Xiaonan & Jiang, Ruicheng & Yu, Xiaoli & Roskilly, Anthony Paul, 2021. "Applications and technological challenges for heat recovery, storage and utilisation with latent thermal energy storage," Applied Energy, Elsevier, vol. 283(C).
    3. Jayathunga, D.S. & Karunathilake, H.P. & Narayana, M. & Witharana, S., 2024. "Phase change material (PCM) candidates for latent heat thermal energy storage (LHTES) in concentrated solar power (CSP) based thermal applications - A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    4. Liu, Yang & Zheng, Ruowei & Li, Ji, 2022. "High latent heat phase change materials (PCMs) with low melting temperature for thermal management and storage of electronic devices and power batteries: Critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    5. Gao, Wei & Liu, Feifan & Yu, Cheng & Chen, Yongping & Liu, Xiangdong, 2023. "Microfluidic method–based encapsulated phase change materials: Fundamentals, progress, and prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 171(C).
    6. Chinnasamy, Veerakumar & Heo, Jaehyeok & Jung, Sungyong & Lee, Hoseong & Cho, Honghyun, 2023. "Shape stabilized phase change materials based on different support structures for thermal energy storage applications–A review," Energy, Elsevier, vol. 262(PB).
    7. Mendecka, Barbara & Cozzolino, Raffaello & Leveni, Martina & Bella, Gino, 2019. "Energetic and exergetic performance evaluation of a solar cooling and heating system assisted with thermal storage," Energy, Elsevier, vol. 176(C), pages 816-829.
    8. Faraj, Khaireldin & Khaled, Mahmoud & Faraj, Jalal & Hachem, Farouk & Castelain, Cathy, 2020. "Phase change material thermal energy storage systems for cooling applications in buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    9. Daniarta, Sindu & Nemś, Magdalena & Kolasiński, Piotr, 2023. "A review on thermal energy storage applicable for low- and medium-temperature organic Rankine cycle," Energy, Elsevier, vol. 278(PA).
    10. Amaral, C. & Vicente, R. & Marques, P.A.A.P. & Barros-Timmons, A., 2017. "Phase change materials and carbon nanostructures for thermal energy storage: A literature review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1212-1228.
    11. Zhang, Xiaoyu & Wang, Xiaodong & Wu, Dezhen, 2016. "Design and synthesis of multifunctional microencapsulated phase change materials with silver/silica double-layered shell for thermal energy storage, electrical conduction and antimicrobial effectivene," Energy, Elsevier, vol. 111(C), pages 498-512.
    12. Cao, Lei & Su, Di & Tang, Yaojie & Fang, Guiyin & Tang, Fang, 2015. "Properties evaluation and applications of thermal energystorage materials in buildings," Renewable and Sustainable Energy Reviews, Elsevier, vol. 48(C), pages 500-522.
    13. Cao, Lei & Tang, Yaojie & Fang, Guiyin, 2015. "Preparation and properties of shape-stabilized phase change materials based on fatty acid eutectics and cellulose composites for thermal energy storage," Energy, Elsevier, vol. 80(C), pages 98-103.
    14. Zhang, Ying & Wang, Xiaodong & Wu, Dezhen, 2016. "Microencapsulation of n-dodecane into zirconia shell doped with rare earth: Design and synthesis of bifunctional microcapsules for photoluminescence enhancement and thermal energy storage," Energy, Elsevier, vol. 97(C), pages 113-126.
    15. Ewelina Radomska & Lukasz Mika & Karol Sztekler, 2020. "The Impact of Additives on the Main Properties of Phase Change Materials," Energies, MDPI, vol. 13(12), pages 1-34, June.
    16. Umair, Malik Muhammad & Zhang, Yuang & Iqbal, Kashif & Zhang, Shufen & Tang, Bingtao, 2019. "Novel strategies and supporting materials applied to shape-stabilize organic phase change materials for thermal energy storage–A review," Applied Energy, Elsevier, vol. 235(C), pages 846-873.
    17. Rostami, Sara & Afrand, Masoud & Shahsavar, Amin & Sheikholeslami, M. & Kalbasi, Rasool & Aghakhani, Saeed & Shadloo, Mostafa Safdari & Oztop, Hakan F., 2020. "A review of melting and freezing processes of PCM/nano-PCM and their application in energy storage," Energy, Elsevier, vol. 211(C).
    18. Ahmed Hassan & Mohammad Shakeel Laghari & Yasir Rashid, 2016. "Micro-Encapsulated Phase Change Materials: A Review of Encapsulation, Safety and Thermal Characteristics," Sustainability, MDPI, vol. 8(10), pages 1-32, October.
    19. Tavakoli, Ali & Hashemi, Javad & Najafian, Mahyar & Ebrahimi, Amin, 2023. "Physics-based modelling and data-driven optimisation of a latent heat thermal energy storage system with corrugated fins," Renewable Energy, Elsevier, vol. 217(C).
    20. Costa, Sol Carolina & Kenisarin, Murat, 2022. "A review of metallic materials for latent heat thermal energy storage: Thermophysical properties, applications, and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:292:y:2021:i:c:s0306261921003998. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.