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D-mannitol@silica/graphene oxide nanoencapsulated phase change material with high phase change properties and thermal reliability

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  • He, Lijuan
  • Mo, Songping
  • Lin, Pengcheng
  • Jia, Lisi
  • Chen, Ying
  • Cheng, Zhengdong

Abstract

Sugar alcohols have considerable potential for usage in medium-temperature thermal energy storage applications; however, they suffer from poor thermal reliability and low thermal conductivity. Nanoencapsulation is an effective approach to improve the thermal energy storage performance of the phase-change materials. Until now, nanoencapsulation of sugar alcohols with a high phase-change performance has been rarely reported. The objective of this study is to develop a method for the nanoencapsulation of sugar alcohols with an enhanced phase-change performance. D-mannitol nanocapsules with a silica–graphene oxide composite shell were synthesized and investigated to demonstrate the validity of this novel method. The morphology, size distribution, and core–shell microstructure of the nanocapsules were observed using a scanning electron microscope, particle size and zeta potential analyzer, and transmission electron microscope. In addition, the phase-change performance of the nanocapsules was studied using a differential scanning calorimeter, a thermogravimetric analyzer, and weight loss and appearance investigation. The results demonstrate that the melting and solidifying latent heat of the nanocapsules are 216.7 and 174.4 kJ/kg, respectively. The energy storage efficiency of the nanocapsules was 75.8% and its 96.1% was maintained after repeated thermal cycling. Compared with pure D-mannitol, the thermal conductivity of the nanocapsules was observed to increase by up to 128.6%. The novel nanocapsules exhibited good medium-temperature thermal energy storage prospects.

Suggested Citation

  • He, Lijuan & Mo, Songping & Lin, Pengcheng & Jia, Lisi & Chen, Ying & Cheng, Zhengdong, 2020. "D-mannitol@silica/graphene oxide nanoencapsulated phase change material with high phase change properties and thermal reliability," Applied Energy, Elsevier, vol. 268(C).
    • Handle: RePEc:eee:appene:v:268:y:2020:i:c:s0306261920305328
    DOI: 10.1016/j.apenergy.2020.115020
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    3. Liu, Huan & Jing, Jianwei & Liu, Jianxin & Wang, Xiaodong, 2024. "Sugar alcohol-based phase change materials for thermal energy storage: Optimization design and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 199(C).
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    6. Tao, Jialu & Luan, Jingde & Liu, Yue & Qu, Daoyu & Yan, Zheng & Ke, Xin, 2022. "Technology development and application prospects of organic-based phase change materials: An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    7. Liu, Chenzhen & Cheng, Qingjiang & Li, Baohuan & Liu, Xinjian & Rao, Zhonghao, 2023. "Recent advances of sugar alcohols phase change materials for thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).

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