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Comprehensive feasibility assessment of a poly-generation process integrating fast pyrolysis of S. japonica and the Rankine cycle

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  • Brigljević, Boris
  • Liu, Jay J.
  • Lim, Hankwon

Abstract

Marine macroalgae or seaweeds are increasingly becoming strong candidates for sustainable biofuel feedstocks of the future. This study features a large-scale process design and comprehensive analysis of an industrial-scale (400,000 tons dry feedstock per year) poly-generation pyrolysis process that utilizes 3rd generation biofuel feedstock, Saccharina japonica brown seaweed, and produces diesel-range hydrocarbon fuel, heat, and power. Process design relied predominately on published experimental data regarding fast pyrolysis of S. japonica in a fixed-bed reactor system, followed by dewatering and catalytic upgrading of the produced biocrude. The design featured acid wash pretreatment for the reduction of mineral content, and subsequently a Rankine power cycle utilizing biochar. The design also considered two distinct cases of on-site hydrogen production and hydrogen purchase. Based on the experimental data, a rigorous steady-state flowsheet model was constructed using Aspen Plus for each design case. The results of comprehensive techno-economic assessment, sensitivity, and Monte Carlo analyses provided insight into capital cost for the process, minimum product selling price, and selling price ranges. Finally, the process is compared with traditional crude oil extraction and processing in terms of significant reductions in CO2 emissions, hence providing strong evidence of its environmental sustainability.

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  • Brigljević, Boris & Liu, Jay J. & Lim, Hankwon, 2019. "Comprehensive feasibility assessment of a poly-generation process integrating fast pyrolysis of S. japonica and the Rankine cycle," Applied Energy, Elsevier, vol. 254(C).
    • Handle: RePEc:eee:appene:v:254:y:2019:i:c:s0306261919313911
    DOI: 10.1016/j.apenergy.2019.113704
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    4. Yue Wang & Yuanjiang Zhao & Changwei Hu, 2024. "Slow Pyrolysis of De-Oiled Rapeseed Cake: Influence of Pyrolysis Parameters on the Yield and Characteristics of the Liquid Obtained," Energies, MDPI, vol. 17(3), pages 1-14, January.
    5. Gu, Xiangyu & Yu, Liang & Pang, Na & Martinez-Fernandez, Jose Salomon & Fu, Xiao & Chen, Shulin, 2020. "Comparative techno-economic analysis of algal biofuel production via hydrothermal liquefaction: One stage versus two stages," Applied Energy, Elsevier, vol. 259(C).
    6. Dickson, Rofice & Liu, J. Jay, 2021. "A strategy for advanced biofuel production and emission utilization from macroalgal biorefinery using superstructure optimization," Energy, Elsevier, vol. 221(C).
    7. Apip Amrullah & Obie Farobie & Asep Bayu & Novi Syaftika & Edy Hartulistiyoso & Navid R. Moheimani & Surachai Karnjanakom & Yukihiko Matsumura, 2022. "Slow Pyrolysis of Ulva lactuca (Chlorophyta) for Sustainable Production of Bio-Oil and Biochar," Sustainability, MDPI, vol. 14(6), pages 1-14, March.
    8. Kouhgardi, Esmaeil & Zendehboudi, Sohrab & Mohammadzadeh, Omid & Lohi, Ali & Chatzis, Ioannis, 2023. "Current status and future prospects of biofuel production from brown algae in North America: Progress and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 172(C).

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