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Effect of MEA activation method on the long-term performance of PEM fuel cell

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  • Taghiabadi, Mohammad Mohammadi
  • Zhiani, Mohammad
  • Silva, Valter

Abstract

In this paper, the influence of activation procedure on the long-term performance of membrane electrode assembly (MEA) is investigated. The MEAs are activated by most commonly used procedures; constant voltage and constant current. After activation, MEAs are implemented under 9000 aging cycles. During aging process, MEAs performance is evaluated using polarization curves, electrochemical impedance spectroscopy and cyclic voltammetry. The obtained results show that the activated MEA by constant current method shows an average voltage decay of 11.33 µV/cycle at 1 A/cm2, compared to 4.4 µV/cycle for the activated MEA by constant voltage procedure. This is due to the more reduction of electrochemical surface area for the activated MEA by constant current method (32% vs. 19%). Also, after 9000 degradation cycles, more severe platinum nanoparticles agglomeration is seen in the cathode catalyst layer of activated MEA by constant current procedure. This shows that MEA activation by constant current activation method not only need to the longer activation time, but also causes higher catalyst layer degradation.

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  • Taghiabadi, Mohammad Mohammadi & Zhiani, Mohammad & Silva, Valter, 2019. "Effect of MEA activation method on the long-term performance of PEM fuel cell," Applied Energy, Elsevier, vol. 242(C), pages 602-611.
    • Handle: RePEc:eee:appene:v:242:y:2019:i:c:p:602-611
    DOI: 10.1016/j.apenergy.2019.03.157
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    References listed on IDEAS

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    1. Baricci, Andrea & Mereu, Riccardo & Messaggi, Mirko & Zago, Matteo & Inzoli, Fabio & Casalegno, Andrea, 2017. "Application of computational fluid dynamics to the analysis of geometrical features in PEM fuel cells flow fields with the aid of impedance spectroscopy," Applied Energy, Elsevier, vol. 205(C), pages 670-682.
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    4. Jung, Guo-Bin & Chuang, Kai-Yuan & Jao, Ting-Chu & Yeh, Chia-Chen & Lin, Chih-Yuan, 2012. "Study of high voltage applied to the membrane electrode assemblies of proton exchange membrane fuel cells as an accelerated degradation technique," Applied Energy, Elsevier, vol. 100(C), pages 81-86.
    5. Zhiani, Mohammad & Majidi, Somayeh & Silva, Valter Bruno & Gharibi, Hussein, 2016. "Comparison of the performance and EIS (electrochemical impedance spectroscopy) response of an activated PEMFC (proton exchange membrane fuel cell) under low and high thermal and pressure stresses," Energy, Elsevier, vol. 97(C), pages 560-567.
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    Cited by:

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    2. Yang, Yange & Li, Xiang & Tang, Fumin & Ming, Pingwen & Li, Bing & Zhang, Cunman, 2022. "Power evolution of fuel cell stack driven by anode gas diffusion layer degradation," Applied Energy, Elsevier, vol. 313(C).
    3. Park, Jin Young & Lim, In Seop & Choi, Eun Jung & Lee, Yeong Ho & Kim, Min Soo, 2021. "Comparative study of reverse flow activation and conventional activation with polymer electrolyte membrane fuel cell," Renewable Energy, Elsevier, vol. 167(C), pages 162-171.
    4. Lin, Rui & Diao, Xiaoyu & Ma, Tiancai & Tang, Shenghao & Chen, Liang & Liu, Dengcheng, 2019. "Optimized microporous layer for improving polymer exchange membrane fuel cell performance using orthogonal test design," Applied Energy, Elsevier, vol. 254(C).
    5. Chen, Kui & Badji, Abderrezak & Laghrouche, Salah & Djerdir, Abdesslem, 2022. "Polymer electrolyte membrane fuel cells degradation prediction using multi-kernel relevance vector regression and whale optimization algorithm," Applied Energy, Elsevier, vol. 318(C).

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