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Emissions of NO and CO from counterflow combustion of CH4 under MILD and oxyfuel conditions

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  • Cheong, Kin-Pang
  • Li, Pengfei
  • Wang, Feifei
  • Mi, Jianchun

Abstract

This paper reports on the NO and CO emission characteristics of counterflow combustion of methane simulated under MILD or/and oxyfuel conditions. Simulations using CHEMKIN are conducted for various injection conditions of fuel and oxidizer. Note that the terms “oxyfuel”, “MILD-N2” and “MILD-CO2” combustion adopted hereafter represent the conventional oxy-combustion and those MILD combustions diluted by N2 and CO2, respectively. It is observed that the NO emission of MILD-CO2 combustion is ultra-low for all cases of investigation, even when increasing the combustion temperature up to 2000 K or adding more N2 (up to 20%) to either the fuel stream (to simulate nitrogen-containing fuels like biomass) or the oxidizer stream (to simulate the air-ingress). A higher temperature allowed under MILD-CO2 combustion suggests the improvement of energy efficiency for the MILD combustion technology. Moreover, the presence of steam in the oxidant reduces both NO and CO emissions of combustion for all cases.

Suggested Citation

  • Cheong, Kin-Pang & Li, Pengfei & Wang, Feifei & Mi, Jianchun, 2017. "Emissions of NO and CO from counterflow combustion of CH4 under MILD and oxyfuel conditions," Energy, Elsevier, vol. 124(C), pages 652-664.
    • Handle: RePEc:eee:energy:v:124:y:2017:i:c:p:652-664
    DOI: 10.1016/j.energy.2017.02.083
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    References listed on IDEAS

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    Cited by:

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    7. Wang, Feifei & Li, Pengfei & Mi, Jianchun & Wang, Jinbo, 2018. "A refined global reaction mechanism for modeling coal combustion under moderate or intense low-oxygen dilution condition," Energy, Elsevier, vol. 157(C), pages 764-777.
    8. Li, Bo & Shi, Baolu & Chu, Qingzhao & Zhao, Xiaoyao & Li, Junwei & Wang, Ningfei, 2019. "Characteristics of stoichiometric CH4/O2/CO2 flame up to the pure oxygen condition," Energy, Elsevier, vol. 168(C), pages 151-159.
    9. Tian, Ye & Zhou, Xiong & Ji, Xuanyu & Bai, Jisong & Yuan, Liang, 2019. "Applying moderate or intense low-oxygen dilution combustion to a co-axial-jet I-shaped recuperative radiant tube for further performance enhancement," Energy, Elsevier, vol. 171(C), pages 149-160.
    10. Shaker, Ahmad & Fordoei, E. Ebrahimi & Boyaghchi, Fateme Ahmadi, 2023. "Study of NO emission from CH4-air, oxygen-enriched, and oxy-CH4 combustion under HTC and MILD regimes: Impact of wall thermal condition in different oxidant temperature and dilution level," Energy, Elsevier, vol. 277(C).
    11. Jozaalizadeh, Toomaj & Toghraie, Davood, 2019. "Numerical investigation behavior of reacting flow for flameless oxidation technology of MILD combustion: Effect of fluctuating temperature of inlet co-flow," Energy, Elsevier, vol. 178(C), pages 530-537.
    12. Wang, G. & Si, J. & Xu, M. & Mi, J., 2019. "MILD combustion versus conventional bluff-body flame of a premixed CH4/air jet in hot coflow," Energy, Elsevier, vol. 187(C).
    13. Jia, Huiqiao & Qian, Xiang & Li, Jiarui & Yang, Jinling & Zou, Chun & Cao, Shiying & Yao, Hong, 2021. "The effects of O2 concentrations on the ignition and MILD combustion of intensely diluted C2H6 in a counterflow jets," Energy, Elsevier, vol. 228(C).
    14. Fordoei, E. Ebrahimi & Mazaheri, Kiumars & Mohammadpour, Amirreza, 2021. "Numerical study on the heat transfer characteristics, flame structure, and pollutants emission in the MILD methane-air, oxygen-enriched and oxy-methane combustion," Energy, Elsevier, vol. 218(C).
    15. Tu, Yaojie & Xu, Mingchen & Zhou, Dezhi & Wang, Qingxiang & Yang, Wenming & Liu, Hao, 2019. "CFD and kinetic modelling study of methane MILD combustion in O2/N2, O2/CO2 and O2/H2O atmospheres," Applied Energy, Elsevier, vol. 240(C), pages 1003-1013.
    16. Hu, Fan & Li, Pengfei & Cheng, Pengfei & Shi, Guodong & Gao, Yan & Liu, Yaowei & Ding, Cuijiao & Yang, Chao & Liu, Zhaohui, 2023. "Comparative study on homogeneous NO-reburning in flameless and swirl flame combustion," Energy, Elsevier, vol. 283(C).
    17. Lee, Seungro & Shin, Cheol Hee & Choi, Sun & Kwon, Oh Chae, 2018. "Characteristics of NOx emissions of counterflow nonpremixed water-laden methane/air flames," Energy, Elsevier, vol. 164(C), pages 523-535.

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