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Development of a numerical model for biomass packed bed pyrolysis based on experimental validation

Author

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  • Borello, D.
  • Cedola, L.
  • Frangioni, G.V.
  • Meloni, R.
  • Venturini, P.
  • De Filippis, P.
  • de Caprariis, B.

Abstract

A mathematical CFD model of pyrolysis process was developed to predict the volatiles in terms of tar and light gas as well as char fraction released in a biomass packed porous bed system. In particular, phenol was considered as tar representative while the main gas species were individually considered (in particular H2, CO, CO2, CH4 and steam). The model was implemented in a commercial CFD code through several original User Defined Functions (UDFs) to reproduce the source terms in the continuity, energy and chemical species mass fraction equations. Furthermore, both inertial and viscous resistances within the packed bed were modeled and coded to assess the pressure drop in the porous media. Code validation was achieved by comparing the numerical results against experimental data obtained in a small-scale biomass reactor using N2 as carrier gas. To assess the kinetic parameters of the pyrolysis model at different operating conditions, the experiments were carried out by varying, in a wide range, the temperature of both the N2 flux and reactor walls.

Suggested Citation

  • Borello, D. & Cedola, L. & Frangioni, G.V. & Meloni, R. & Venturini, P. & De Filippis, P. & de Caprariis, B., 2016. "Development of a numerical model for biomass packed bed pyrolysis based on experimental validation," Applied Energy, Elsevier, vol. 164(C), pages 956-962.
    • Handle: RePEc:eee:appene:v:164:y:2016:i:c:p:956-962
    DOI: 10.1016/j.apenergy.2015.08.007
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    References listed on IDEAS

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    1. Huang, Y.F. & Chiueh, P.T. & Kuan, W.H. & Lo, S.L., 2013. "Pyrolysis kinetics of biomass from product information," Applied Energy, Elsevier, vol. 110(C), pages 1-8.
    2. Borello, Domenico & Venturini, Paolo & Rispoli, Franco & Rafael, Saavedra G.Z., 2013. "Prediction of multiphase combustion and ash deposition within a biomass furnace," Applied Energy, Elsevier, vol. 101(C), pages 413-422.
    3. Görling, Martin & Larsson, Mårten & Alvfors, Per, 2013. "Bio-methane via fast pyrolysis of biomass," Applied Energy, Elsevier, vol. 112(C), pages 440-447.
    4. Lehto, Jani & Oasmaa, Anja & Solantausta, Yrjö & Kytö, Matti & Chiaramonti, David, 2014. "Review of fuel oil quality and combustion of fast pyrolysis bio-oils from lignocellulosic biomass," Applied Energy, Elsevier, vol. 116(C), pages 178-190.
    5. Ahmed, I.I. & Gupta, A.K., 2013. "Experiments and stochastic simulations of lignite coal during pyrolysis and gasification," Applied Energy, Elsevier, vol. 102(C), pages 355-363.
    6. Venturini, P. & Borello, D. & Iossa, C. & Lentini, D. & Rispoli, F., 2010. "Modeling of multiphase combustion and deposit formation in a biomass-fed furnace," Energy, Elsevier, vol. 35(7), pages 3008-3021.
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