IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v103y2013icp212-220.html
   My bibliography  Save this article

An overview on non-platinum cathode catalysts for direct methanol fuel cell

Author

Listed:
  • Karim, N.A.
  • Kamarudin, S.K.

Abstract

Platinum is the most effective electro-catalyst for oxidation and reduction processes in direct methanol fuel cells (DMFCs). Although platinum and its alloys show desirable electrochemical activities, these catalysts are expensive and make the commercialization of DMFC less attractive. Beside, literature reviews show that tremendous improvements of the activity and stability of non-platinum cathode catalysts have been achieved over the past few years. However, problems including low reaction rates, high over-potentials and low stabilities that remain unsolved particularly for cathode catalyst are discussed in this paper. This paper also describes the various types of non-platinum materials that can potentially substitute for platinum cathode catalysts in DMFC like macrocyclic molecules such as porphyrins and phthalocyanines, transition metal oxides, transition metal sulfides, amorphous transition metal sulfides, and transition metal-based catalysts. Finally, this paper also summarizes the preparation procedure and the performance of various potential cathode catalysts for DMFC operated in acidic and alkaline media as compared with platinum.

Suggested Citation

  • Karim, N.A. & Kamarudin, S.K., 2013. "An overview on non-platinum cathode catalysts for direct methanol fuel cell," Applied Energy, Elsevier, vol. 103(C), pages 212-220.
  • Handle: RePEc:eee:appene:v:103:y:2013:i:c:p:212-220
    DOI: 10.1016/j.apenergy.2012.09.031
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261912006721
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2012.09.031?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wang, Zhigang & Zhang, Xuelin & Nie, Li & Zhang, Yufeng & Liu, Xiaowei, 2014. "Elimination of water flooding of cathode current collector of micro passive direct methanol fuel cell by superhydrophilic surface treatment," Applied Energy, Elsevier, vol. 126(C), pages 107-112.
    2. Hassan, M.A. & Kamarudin, S.K. & Loh, K.S. & Daud, W.R.W., 2014. "Sensors for direct methanol fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 40(C), pages 1060-1069.
    3. Halima Alnaqbi & Oussama El-Kadri & Mohammad Ali Abdelkareem & Sameer Al-Asheh, 2022. "Recent Progress in Metal-Organic Framework-Derived Chalcogenides (MX; X = S, Se) as Electrode Materials for Supercapacitors and Catalysts in Fuel Cells," Energies, MDPI, vol. 15(21), pages 1-25, November.
    4. Liu, Guicheng & Li, Xinyang & Wang, Hui & Liu, Xiuying & Chen, Ming & Woo, Jae Young & Kim, Ji Young & Wang, Xindong & Lee, Joong Kee, 2017. "Design of 3-electrode system for in situ monitoring direct methanol fuel cells during long-time running test at high temperature," Applied Energy, Elsevier, vol. 197(C), pages 163-168.
    5. Yuan, Rong-hua & He, Yun & He, Wei & Ni, Meng & Leung, Michael K.H., 2019. "Bifunctional electrocatalytic activity of La0.8Sr0.2MnO3-based perovskite with the A-site deficiency for oxygen reduction and evolution reactions in alkaline media," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    6. Nandan, Ravi & Goswami, Gopal Krishna & Nanda, Karuna Kar, 2017. "Direct synthesis of Pt-free catalyst on gas diffusion layer of fuel cell and usage of high boiling point fuels for efficient utilization of waste heat," Applied Energy, Elsevier, vol. 205(C), pages 1050-1058.
    7. Calabriso, Andrea & Borello, Domenico & Romano, Giovanni Paolo & Cedola, Luca & Del Zotto, Luca & Santori, Simone Giovanni, 2017. "Bubbly flow mapping in the anode channel of a direct methanol fuel cell via PIV investigation," Applied Energy, Elsevier, vol. 185(P2), pages 1245-1255.
    8. Xuan Shi & Lingfei Cai & Junzhi Jia, 2018. "The Evolution of International Scientific Collaboration in Fuel Cells during 1998–2017: A Social Network Perspective," Sustainability, MDPI, vol. 10(12), pages 1-20, December.
    9. Kiyani, Roya & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Nitrogen doped graphene supported palladium-cobalt as a promising catalyst for methanol oxidation reaction: Synthesis, characterization and electrocatalytic performance," Energy, Elsevier, vol. 113(C), pages 1162-1173.
    10. Deva Harsha Perugupalli & Tao Xu & Kyu Taek Cho, 2019. "Activation of Carbon Porous Paper for Alkaline Alcoholic Fuel Cells," Energies, MDPI, vol. 12(17), pages 1-12, August.
    11. Song, Xingjuan & Zhang, Dongming, 2014. "Bimetallic Ag–Ni/C particles as cathode catalyst in AFCs (alkaline fuel cells)," Energy, Elsevier, vol. 70(C), pages 223-230.
    12. Zhong, Kengqiang & Li, Meng & Yang, Yue & Zhang, Hongguo & Zhang, Bopeng & Tang, Jinfeng & Yan, Jia & Su, Minhua & Yang, Zhiquan, 2019. "Nitrogen-doped biochar derived from watermelon rind as oxygen reduction catalyst in air cathode microbial fuel cells," Applied Energy, Elsevier, vol. 242(C), pages 516-525.
    13. Wu, Mingjie & Zhang, Enguang & Guo, Qinping & Wang, Yongzhen & Qiao, Jinli & Li, Kaixi & Pei, Pucheng, 2016. "N/S-Me (Fe, Co, Ni) doped hierarchical porous carbons for fuel cell oxygen reduction reaction with high catalytic activity and long-term stability," Applied Energy, Elsevier, vol. 175(C), pages 468-478.
    14. Kim, Joon-Hee & Yang, Min-Jee & Park, Jun-Young, 2014. "Improvement on performance and efficiency of direct methanol fuel cells using hydrocarbon-based membrane electrode assembly," Applied Energy, Elsevier, vol. 115(C), pages 95-102.
    15. Liu, Guicheng & Ding, Xianan & Zhou, Hongwei & Chen, Ming & Wang, Manxiang & Zhao, Zhenxuan & Yin, Zhuang & Wang, Xindong, 2015. "Structure optimization of cathode microporous layer for direct methanol fuel cells," Applied Energy, Elsevier, vol. 147(C), pages 396-401.
    16. Yuan, Wei & Wang, Aoyu & Yan, Zhiguo & Tan, Zhenhao & Tang, Yong & Xia, Hongrong, 2016. "Visualization of two-phase flow and temperature characteristics of an active liquid-feed direct methanol fuel cell with diverse flow fields," Applied Energy, Elsevier, vol. 179(C), pages 85-98.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:103:y:2013:i:c:p:212-220. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.