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High-performing organic electronics using terpene green solvents from renewable feedstocks

Author

Listed:
  • Daniel Corzo

    (King Abdullah University of Science and Technology (KAUST))

  • Diego Rosas-Villalva

    (King Abdullah University of Science and Technology (KAUST))

  • Amruth C

    (King Abdullah University of Science and Technology (KAUST))

  • Guillermo Tostado-Blázquez

    (King Abdullah University of Science and Technology (KAUST))

  • Emily Bezerra Alexandre

    (King Abdullah University of Science and Technology (KAUST))

  • Luis Huerta Hernandez

    (King Abdullah University of Science and Technology (KAUST))

  • Jianhua Han

    (King Abdullah University of Science and Technology (KAUST))

  • Han Xu

    (King Abdullah University of Science and Technology (KAUST))

  • Maxime Babics

    (King Abdullah University of Science and Technology (KAUST))

  • Stefaan Wolf

    (King Abdullah University of Science and Technology (KAUST))

  • Derya Baran

    (King Abdullah University of Science and Technology (KAUST))

Abstract

Accelerating the shift towards renewable materials and sustainable processes for printed organic electronic devices is crucial for a green circular economy. Currently, the fabrication of organic devices with competitive performances is linked to toxic petrochemical-based solvents with considerable carbon emissions. Here we show that terpene solvents obtained from renewable feedstocks can replace non-renewable environmentally hazardous solvent counterparts in the production of highly efficient organic photovoltaics (OPVs) light-emitting diodes (OLEDs) and field-effect transistors (OFETs) with on-par performances. Using a Hansen solubility ink formulation framework, we identify various terpene solvent systems and investigate effective film formation and drying mechanisms required for optimal charge transport. This approach is universal for state-of-the-art materials in OPVs, OLEDs and OFETs. We created an interactive library for green solvent selections and made it publicly available through the OMEGALab website. As potential carbon-negative solvents, terpenes open a unique and universal approach towards efficient, large-area and stable organic electronic devices.

Suggested Citation

  • Daniel Corzo & Diego Rosas-Villalva & Amruth C & Guillermo Tostado-Blázquez & Emily Bezerra Alexandre & Luis Huerta Hernandez & Jianhua Han & Han Xu & Maxime Babics & Stefaan Wolf & Derya Baran, 2023. "High-performing organic electronics using terpene green solvents from renewable feedstocks," Nature Energy, Nature, vol. 8(1), pages 62-73, January.
    • Handle: RePEc:nat:natene:v:8:y:2023:i:1:d:10.1038_s41560-022-01167-7
    DOI: 10.1038/s41560-022-01167-7
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    References listed on IDEAS

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    1. Jingbo Zhao & Yunke Li & Guofang Yang & Kui Jiang & Haoran Lin & Harald Ade & Wei Ma & He Yan, 2016. "Efficient organic solar cells processed from hydrocarbon solvents," Nature Energy, Nature, vol. 1(2), pages 1-7, February.
    2. Ying Zhang & Kuan Liu & Jiaming Huang & Xinxin Xia & Jiupeng Cao & Guangming Zhao & Patrick W. K. Fong & Ye Zhu & Feng Yan & Yang Yang & Xinhui Lu & Gang Li, 2021. "Graded bulk-heterojunction enables 17% binary organic solar cells via nonhalogenated open air coating," Nature Communications, Nature, vol. 12(1), pages 1-13, December.
    3. Chao Li & Jiadong Zhou & Jiali Song & Jinqiu Xu & Huotian Zhang & Xuning Zhang & Jing Guo & Lei Zhu & Donghui Wei & Guangchao Han & Jie Min & Yuan Zhang & Zengqi Xie & Yuanping Yi & He Yan & Feng Gao , 2021. "Non-fullerene acceptors with branched side chains and improved molecular packing to exceed 18% efficiency in organic solar cells," Nature Energy, Nature, vol. 6(6), pages 605-613, June.
    4. Christian Larsen & Petter Lundberg & Shi Tang & Joan Ràfols-Ribé & Andreas Sandström & E. Mattias Lindh & Jia Wang & Ludvig Edman, 2021. "A tool for identifying green solvents for printed electronics," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
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