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An N-type Naphthalene Diimide Ionene Polymer as Cathode Interlayer for Organic Solar Cells

Author

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  • Roberto Sorrentino

    (Consiglio Nazionale delle Ricerche, Istituto di Scienze e Tecnologie Chimiche “G. Natta”, CNR—SCITEC, via A. Corti 12, 20133 Milan, Italy)

  • Marta Penconi

    (Consiglio Nazionale delle Ricerche, Istituto di Scienze e Tecnologie Chimiche “G. Natta”, CNR—SCITEC, via A. Corti 12, 20133 Milan, Italy)

  • Anita Andicsová-Eckstein

    (Polymer Institute, Slovak Academy of Sciences, Dúbravská cesta 9, 84541 Bratislava, Slovakia)

  • Guido Scavia

    (Consiglio Nazionale delle Ricerche, Istituto di Scienze e Tecnologie Chimiche “G. Natta”, CNR—SCITEC, via A. Corti 12, 20133 Milan, Italy)

  • Helena Švajdlenková

    (Polymer Institute, Slovak Academy of Sciences, Dúbravská cesta 9, 84541 Bratislava, Slovakia)

  • Erika Kozma

    (Consiglio Nazionale delle Ricerche, Istituto di Scienze e Tecnologie Chimiche “G. Natta”, CNR—SCITEC, via A. Corti 12, 20133 Milan, Italy)

  • Silvia Luzzati

    (Consiglio Nazionale delle Ricerche, Istituto di Scienze e Tecnologie Chimiche “G. Natta”, CNR—SCITEC, via A. Corti 12, 20133 Milan, Italy)

Abstract

Polymer solar cells (PSCs) based on non-fullerene acceptors have the advantages of synthetic versatility, strong absorption ability, and high thermal stability. These characteristics result in impressive power conversion efficiency values, but to further push both the performance and the stability of PSCs, the insertion of appropriate interlayers in the device structure remains mandatory. Herein, a naphthalene diimide-based cathode interlayer (NDI-OH) is synthesized with a facile three-step reaction and used as a cathode interlayer for fullerene and non-fullerene PSCs. This cationic polyelectrolyte exhibited good solubility in alcohol solvents, transparency in the visible range, self-doping behavior, and good film forming ability. All these characteristics allowed the increase in the devices’ power conversion efficiencies (PCE) both for fullerene and non-fullerene-based PSCs. The successful results make NDI-OH a promising cathode interlayer to apply in PSCs.

Suggested Citation

  • Roberto Sorrentino & Marta Penconi & Anita Andicsová-Eckstein & Guido Scavia & Helena Švajdlenková & Erika Kozma & Silvia Luzzati, 2021. "An N-type Naphthalene Diimide Ionene Polymer as Cathode Interlayer for Organic Solar Cells," Energies, MDPI, vol. 14(2), pages 1-11, January.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:2:p:454-:d:481277
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    References listed on IDEAS

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    1. Chao Li & Jiadong Zhou & Jiali Song & Jinqiu Xu & Huotian Zhang & Xuning Zhang & Jing Guo & Lei Zhu & Donghui Wei & Guangchao Han & Jie Min & Yuan Zhang & Zengqi Xie & Yuanping Yi & He Yan & Feng Gao , 2021. "Non-fullerene acceptors with branched side chains and improved molecular packing to exceed 18% efficiency in organic solar cells," Nature Energy, Nature, vol. 6(6), pages 605-613, June.
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    Cited by:

    1. Xinlei Wu & Yuanpeng Zhang & Kaihang Shi & Xiaoling Ma & Fujun Zhang, 2023. "Advanced Progress of Organic Photovoltaics," Energies, MDPI, vol. 16(3), pages 1-3, January.
    2. Jaemin Kong, 2022. "Advanced Polymer and Perovskite Solar Cells," Energies, MDPI, vol. 15(2), pages 1-2, January.
    3. Yu Jiang & Youjun Bai & Shenghao Wang, 2023. "Organic Solar Cells: From Fundamental to Application," Energies, MDPI, vol. 16(5), pages 1-3, February.

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