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Phenanthroline-carbolong interface suppress chemical interactions with active layer enabling long-time stable organic solar cells

Author

Listed:
  • Xue Lai,

    (Harbin Institute of Technology
    Southern University of Science and Technology Shenzhen)

  • Shiyan Chen,

    (Southern University of Science and Technology Shenzhen)

  • Xiaoyu Gu,

    (Southern University of Science and Technology)

  • Hanjian Lai,

    (Southern University of Science and Technology Shenzhen)

  • Yunpeng Wang,

    (Southern University of Science and Technology Shenzhen)

  • Yulin Zhu,

    (Southern University of Science and Technology Shenzhen)

  • Hui Wang,

    (Southern University of Science and Technology Shenzhen)

  • Jianfei Qu,

    (Southern University of Science and Technology Shenzhen)

  • Aung Ko Ko Kyaw

    (Southern University of Science and Technology)

  • Haiping Xia

    (Southern University of Science and Technology Shenzhen
    Southern University of Science and Technology Shenzhen)

  • Feng He

    (Southern University of Science and Technology Shenzhen
    Southern University of Science and Technology Shenzhen)

Abstract

To restrain the chemical reaction at cathode interface of organic solar cells, two cathode interfacial materials are synthesized by connecting phenanthroline with carbolong unit. Consequently, the D18:L8-BO based organic solar cell with double-phenanthroline-carbolong achieve the highest efficiency of 18.2%. Double-phenanthroline-carbolong with larger steric hindrance and stronger electron-withdrawing property confirms to suppress the interfacial reaction with norfullerene acceptor, resulting the most stable device. Double-phenanthroline-carbolong based device can sustain 80% of its initial efficiency for 2170 h in dark N2 atmosphere, 96 h under 85 oC and keep 68% initial efficiency after been illuminated for 2200 h, which are significantly better than bathocuproin based devices. Moreover, superb interfacial stability of double-phenanthroline-carbolong cathode interface enables thermal posttreatment of organic sub-cell in perovskite/organic tandem solar cells and obtained a remarkable efficiency of 21.7% with excellent thermal stability, which indicates the potentially wide application of phenanthroline-carbolong materials for stable and efficient solar device fabrications.

Suggested Citation

  • Xue Lai, & Shiyan Chen, & Xiaoyu Gu, & Hanjian Lai, & Yunpeng Wang, & Yulin Zhu, & Hui Wang, & Jianfei Qu, & Aung Ko Ko Kyaw & Haiping Xia & Feng He, 2023. "Phenanthroline-carbolong interface suppress chemical interactions with active layer enabling long-time stable organic solar cells," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39223-9
    DOI: 10.1038/s41467-023-39223-9
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