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Many-body van der Waals interactions in multilayer structures studied by atomic force microscopy

Author

Listed:
  • Xiao Wang

    (Nanjing University of Aeronautics and Astronautics)

  • Zepu Kou

    (Nanjing University of Aeronautics and Astronautics)

  • Ruixi Qiao

    (Nanjing University of Aeronautics and Astronautics)

  • Yuyang Long

    (Nanjing University of Aeronautics and Astronautics)

  • Baowen Li

    (Nanjing University of Aeronautics and Astronautics)

  • Xuemei Li

    (Nanjing University of Aeronautics and Astronautics
    Nanjing University of Aeronautics and Astronautics)

  • Wanlin Guo

    (Nanjing University of Aeronautics and Astronautics
    Nanjing University of Aeronautics and Astronautics)

  • Xiaofei Liu

    (Nanjing University of Aeronautics and Astronautics)

  • Jun Yin

    (Nanjing University of Aeronautics and Astronautics)

Abstract

Van der Waals interaction in multilayer structures was predicted to be of many-body character, almost in parallel with the establishment of Lifshitz theory. However, the diminishing interaction between layers separated by a finite-thickness intermediate layer prevents experimental verification of the many-body nature. Here we verify the substrate contribution at the adhesion between the atomic force microscopy tip and the supported graphene, by taking advantage of the atomic-scale proximity of two objects separated by graphene. While the pairwise dispersion theory overestimates the substrate contribution at critical adhesive pressures, the many-body dispersion theory remedies this deficiency, highlighting the non-additivity nature of substrate contribution. The many-body effect is further understood through the energy spectrum of charge density fluctuations. These findings open the door to modulating the van der Waals interaction on two-dimensional material surfaces, which would be relevant to various technologies, including microelectromechanical systems and surface molecular assembly.

Suggested Citation

  • Xiao Wang & Zepu Kou & Ruixi Qiao & Yuyang Long & Baowen Li & Xuemei Li & Wanlin Guo & Xiaofei Liu & Jun Yin, 2025. "Many-body van der Waals interactions in multilayer structures studied by atomic force microscopy," Nature Communications, Nature, vol. 16(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:16:y:2025:i:1:d:10.1038_s41467-024-54484-8
    DOI: 10.1038/s41467-024-54484-8
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    References listed on IDEAS

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    1. Anna V. Prydatko & Liubov A. Belyaeva & Lin Jiang & Lia M. C. Lima & Grégory F. Schneider, 2018. "Contact angle measurement of free-standing square-millimeter single-layer graphene," Nature Communications, Nature, vol. 9(1), pages 1-7, December.
    2. Paul Hauseux & Thanh-Tung Nguyen & Alberto Ambrosetti & Katerine Saleme Ruiz & Stéphane P. A. Bordas & Alexandre Tkatchenko, 2020. "From quantum to continuum mechanics in the delamination of atomically-thin layers from substrates," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    3. Filippo Pizzocchero & Lene Gammelgaard & Bjarke S. Jessen & José M. Caridad & Lei Wang & James Hone & Peter Bøggild & Timothy J. Booth, 2016. "The hot pick-up technique for batch assembly of van der Waals heterostructures," Nature Communications, Nature, vol. 7(1), pages 1-10, September.
    4. Hossein Rokni & Wei Lu, 2020. "Direct measurements of interfacial adhesion in 2D materials and van der Waals heterostructures in ambient air," Nature Communications, Nature, vol. 11(1), pages 1-14, December.
    5. Martin Stöhr & Mainak Sadhukhan & Yasmine S. Al-Hamdani & Jan Hermann & Alexandre Tkatchenko, 2021. "Coulomb interactions between dipolar quantum fluctuations in van der Waals bound molecules and materials," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
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