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Ultrathin polymer membrane for improved hole extraction and ion blocking in perovskite solar cells

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  • Lina Shen

    (Huaqiao University)

  • Peiquan Song

    (Huaqiao University)

  • Kui Jiang

    (City University of Hong Kong)

  • Lingfang Zheng

    (Huaqiao University)

  • Jianhang Qiu

    (Chinese Academy of Sciences (CAS))

  • Fangyao Li

    (Huaqiao University)

  • Yu Huang

    (Huaqiao University)

  • Jinxin Yang

    (Huaqiao University)

  • Chengbo Tian

    (Huaqiao University)

  • Alex. K.-Y. Jen

    (City University of Hong Kong)

  • Liqiang Xie

    (Huaqiao University)

  • Zhanhua Wei

    (Huaqiao University)

Abstract

Highly efficient perovskite solar cells (PSCs) in the n-i-p structure have demonstrated limited operational lifetimes, primarily due to the layer-to-layer ion diffusion in the perovskite/doped hole-transport layer (HTL) heterojunction, leading to conductivity drop in HTL and component loss in perovskite. Herein, we introduce an ultrathin (~7 nm) p-type polymeric interlayer (D18) with excellent ion-blocking ability between perovskite and HTL to address these issues. The ultrathin D18 interlayer effectively inhibits the layer-to-layer diffusion of lithium, methylammonium, formamidium, and iodide ions. Additionally, D18 improves the energy-level alignment at the perovskite/HTL interface and facilitates efficient hole extraction. The resulting PSCs achieve efficiencies of 26.39 (certified 26.17) and 25.02% with aperture areas of 0.12 and 1.00 square centimeters, respectively. Remarkably, the devices retain 95.4% of the initial efficiency after 1100 hours of operation in maximum power point tracking, representing significant stability advancements for high-efficiency n-i-p PSCs.

Suggested Citation

  • Lina Shen & Peiquan Song & Kui Jiang & Lingfang Zheng & Jianhang Qiu & Fangyao Li & Yu Huang & Jinxin Yang & Chengbo Tian & Alex. K.-Y. Jen & Liqiang Xie & Zhanhua Wei, 2024. "Ultrathin polymer membrane for improved hole extraction and ion blocking in perovskite solar cells," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-55329-0
    DOI: 10.1038/s41467-024-55329-0
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    1. Kui Jiang & Jie Zhang & Cheng Zhong & Francis R. Lin & Feng Qi & Qian Li & Zhengxing Peng & Werner Kaminsky & Sei-Hum Jang & Jianwei Yu & Xiang Deng & Huawei Hu & Dong Shen & Feng Gao & Harald Ade & M, 2022. "Suppressed recombination loss in organic photovoltaics adopting a planar–mixed heterojunction architecture," Nature Energy, Nature, vol. 7(11), pages 1076-1086, November.
    2. Yuchuan Shao & Zhengguo Xiao & Cheng Bi & Yongbo Yuan & Jinsong Huang, 2014. "Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells," Nature Communications, Nature, vol. 5(1), pages 1-7, December.
    3. Yicheng Zhao & Thomas Heumueller & Jiyun Zhang & Junsheng Luo & Olga Kasian & Stefan Langner & Christian Kupfer & Bowen Liu & Yu Zhong & Jack Elia & Andres Osvet & Jianchang Wu & Chao Liu & Zhongquan , 2022. "A bilayer conducting polymer structure for planar perovskite solar cells with over 1,400 hours operational stability at elevated temperatures," Nature Energy, Nature, vol. 7(2), pages 144-152, February.
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