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Silver coordination-induced n-doping of PCBM for stable and efficient inverted perovskite solar cells

Author

Listed:
  • Cheng Gong

    (Chongqing University)

  • Haiyun Li

    (Chongqing University)

  • Huaxin Wang

    (Chongqing University)

  • Cong Zhang

    (Chongqing University)

  • Qixin Zhuang

    (Chongqing University)

  • Awen Wang

    (Huazhong University of Science and Technology)

  • Zhiyuan Xu

    (Chongqing University)

  • Wensi Cai

    (Chongqing University)

  • Ru Li

    (Chongqing University)

  • Xiong Li

    (Huazhong University of Science and Technology)

  • Zhigang Zang

    (Chongqing University
    Yanshan University)

Abstract

The bidirectional migration of halides and silver causes irreversible chemical corrosion to the electrodes and perovskite layer, affecting long-term operation stability of perovskite solar cells. Here we propose a silver coordination-induced n-doping of [6,6]-phenyl-C61-butyric acid methyl ester strategy to safeguard Ag electrode against corrosion and impede the migration of iodine within the PSCs. Meanwhile, the coordination between DCBP and silver induces n-doping in the PCBM layer, accelerating electron extraction from the perovskite layer. The resultant PSCs demonstrate an efficiency of 26.03% (certified 25.51%) with a minimal non-radiative voltage loss of 126 mV. The PCE of resulting devices retain 95% of their initial value after 2500 h of continuous maximum power point tracking under one-sun irradiation, and > 90% of their initial value even after 1500 h of accelerated aging at 85 °C and 85% relative humidity.

Suggested Citation

  • Cheng Gong & Haiyun Li & Huaxin Wang & Cong Zhang & Qixin Zhuang & Awen Wang & Zhiyuan Xu & Wensi Cai & Ru Li & Xiong Li & Zhigang Zang, 2024. "Silver coordination-induced n-doping of PCBM for stable and efficient inverted perovskite solar cells," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-49395-7
    DOI: 10.1038/s41467-024-49395-7
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