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Robust chelated lead octahedron surface for efficient and stable perovskite solar cells

Author

Listed:
  • Bin Wen

    (Shenzhen Campus of Sun Yat-sen University
    Sun Yat-sen University)

  • Tian Chen

    (Shenzhen Campus of Sun Yat-sen University
    Sun Yat-sen University)

  • Qixin Yin

    (Shenzhen Campus of Sun Yat-sen University
    Sun Yat-sen University)

  • Jiangsheng Xie

    (Shenzhen Campus of Sun Yat-sen University
    Sun Yat-sen University)

  • Chaohua Dai

    (Shenzhen Campus of Sun Yat-sen University
    Sun Yat-sen University)

  • Ruohao Lin

    (Shenzhen Campus of Sun Yat-sen University
    Sun Yat-sen University)

  • Sicen Zhou

    (Shenzhen Campus of Sun Yat-sen University
    Sun Yat-sen University)

  • Jiancan Yu

    (Shenzhen Campus of Sun Yat-sen University)

  • Pingqi Gao

    (Shenzhen Campus of Sun Yat-sen University
    Sun Yat-sen University)

Abstract

PbI6 octahedron as a fundamental framework endows the perovskite with excellent photoelectric properties, but also the defective and flimsy surface. Here, we report that the treatment of perovskite surface by bidentate ligands molecules N, N’-Dimethyl-1,2-ethanediamine can in-situ form a lead iodide chelates layer with excellently robust chelated lead octahedron, leading to effectively stabilize and passivate the underlying perovskite. The strong chelation with the lead enables the surface to largely inhibit the defects generation, iodide ion migration and skeleton collapse under external stimuli. It also prolongs the carrier lifetime and adjusts the surface energy-level of perovskite. The resultant perovskite solar cells deliver a power conversion efficiency of 25.7% (certified 25.04%) and retain >90% of their initial value after almost 1000 hours aging at maximum power point under simulated AM1.5 illumination.

Suggested Citation

  • Bin Wen & Tian Chen & Qixin Yin & Jiangsheng Xie & Chaohua Dai & Ruohao Lin & Sicen Zhou & Jiancan Yu & Pingqi Gao, 2024. "Robust chelated lead octahedron surface for efficient and stable perovskite solar cells," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-52198-5
    DOI: 10.1038/s41467-024-52198-5
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