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Bifunctional and recyclable polyesters by chemoselective ring-opening polymerization of a δ-lactone derived from CO2 and butadiene

Author

Listed:
  • Jinbo Zhang

    (Qingdao University of Science and Technology)

  • Lihang Jiang

    (Dalian Medical University)

  • Shaofeng Liu

    (Qingdao University of Science and Technology)

  • Junhao Shen

    (Qingdao University of Science and Technology)

  • Pierre Braunstein

    (Université de Strasbourg)

  • Yong Shen

    (Qingdao University of Science and Technology)

  • Xiaohui Kang

    (Dalian Medical University)

  • Zhibo Li

    (Qingdao University of Science and Technology
    Qingdao University of Science and Technology)

Abstract

When aiming at the direct use of CO2 for the preparation of advanced/value-added materials, the synthesis of CO2/olefin copolymers is very appealing but challenging. The δ-lactone 3-ethylidene-6-vinyltetrahydro-2H-pyran-2-one (EVP), synthesized by telomerization of CO2 with 1,3-butadiene, is a promising monomer. However, its chemoselective ring-opening polymerization (ROP) is hampered by unfavorable thermodynamics and the competitive polymerization of highly reactive C=C double bonds under usual conditions. Herein, we report the chemoselective ROP of EVP using a phosphazene/urea binary catalyst, affording exclusively a linear unsaturated polyester poly(EVP)ROP, with a molar mass (Mn) up to 16.1 kg·mol−1 and a narrow distribution (Ð

Suggested Citation

  • Jinbo Zhang & Lihang Jiang & Shaofeng Liu & Junhao Shen & Pierre Braunstein & Yong Shen & Xiaohui Kang & Zhibo Li, 2024. "Bifunctional and recyclable polyesters by chemoselective ring-opening polymerization of a δ-lactone derived from CO2 and butadiene," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-52090-2
    DOI: 10.1038/s41467-024-52090-2
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    References listed on IDEAS

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    1. Yunqing Zhu & Charles Romain & Charlotte K. Williams, 2016. "Sustainable polymers from renewable resources," Nature, Nature, vol. 540(7633), pages 354-362, December.
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