IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v9y2018i1d10.1038_s41467-017-02607-9.html
   My bibliography  Save this article

Rotator side chains trigger cooperative transition for shape and function memory effect in organic semiconductors

Author

Listed:
  • Hyunjoong Chung

    (University of Illinois at Urbana−Champaign)

  • Dmytro Dudenko

    (University of Mons)

  • Fengjiao Zhang

    (University of Illinois at Urbana−Champaign)

  • Gabriele D’Avino

    (CNRS and Grenoble Alpes University)

  • Christian Ruzié

    (Université Libre de Bruxelles (ULB))

  • Audrey Richard

    (Université Libre de Bruxelles (ULB))

  • Guillaume Schweicher

    (University of Cambridge)

  • Jérôme Cornil

    (University of Mons)

  • David Beljonne

    (University of Mons)

  • Yves Geerts

    (Université Libre de Bruxelles (ULB))

  • Ying Diao

    (University of Illinois at Urbana−Champaign)

Abstract

Martensitic transition is a solid-state phase transition involving cooperative movement of atoms, mostly studied in metallurgy. The main characteristics are low transition barrier, ultrafast kinetics, and structural reversibility. They are rarely observed in molecular crystals, and hence the origin and mechanism are largely unexplored. Here we report the discovery of martensitic transition in single crystals of two different organic semiconductors. In situ microscopy, single-crystal X-ray diffraction, Raman and nuclear magnetic resonance spectroscopy, and molecular simulations combined indicate that the rotating bulky side chains trigger cooperative transition. Cooperativity enables shape memory effect in single crystals and function memory effect in thin film transistors. We establish a molecular design rule to trigger martensitic transition in organic semiconductors, showing promise for designing next-generation smart multifunctional materials.

Suggested Citation

  • Hyunjoong Chung & Dmytro Dudenko & Fengjiao Zhang & Gabriele D’Avino & Christian Ruzié & Audrey Richard & Guillaume Schweicher & Jérôme Cornil & David Beljonne & Yves Geerts & Ying Diao, 2018. "Rotator side chains trigger cooperative transition for shape and function memory effect in organic semiconductors," Nature Communications, Nature, vol. 9(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:9:y:2018:i:1:d:10.1038_s41467-017-02607-9
    DOI: 10.1038/s41467-017-02607-9
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-017-02607-9
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-017-02607-9?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Durga Prasad Karothu & Rodrigo Ferreira & Ghada Dushaq & Ejaz Ahmed & Luca Catalano & Jad Mahmoud Halabi & Zainab Alhaddad & Ibrahim Tahir & Liang Li & Sharmarke Mohamed & Mahmoud Rasras & Panče Naumo, 2022. "Exceptionally high work density of a ferroelectric dynamic organic crystal around room temperature," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    2. Daniel William Davies & Bumjoon Seo & Sang Kyu Park & Stephen B. Shiring & Hyunjoong Chung & Prapti Kafle & Dafei Yuan & Joseph W. Strzalka & Ralph Weber & Xiaozhang Zhu & Brett M. Savoie & Ying Diao, 2023. "Unraveling two distinct polymorph transition mechanisms in one n-type single crystal for dynamic electronics," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    3. Die Zhang & Boyang Fu & Weilong He & Hengtao Li & Fuyang Liu & Luhong Wang & Haozhe Liu & Liujiang Zhou & Weizhao Cai, 2024. "Pressure-induced shape and color changes and mechanical-stimulation-driven reverse transition in a one-dimensional hybrid halide," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    4. Marieh B. Al-Handawi & Patrick Commins & Ahmed S. Dalaq & Pedro A. Santos-Florez & Srujana Polavaram & Pascal Didier & Durga Prasad Karothu & Qiang Zhu & Mohammed Daqaq & Liang Li & Panče Naumov, 2024. "Ferroelastic ionic organic crystals that self-heal to 95%," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:9:y:2018:i:1:d:10.1038_s41467-017-02607-9. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.