IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-51250-8.html
   My bibliography  Save this article

Covalent organic framework membrane reactor for boosting catalytic performance

Author

Listed:
  • Liping Zheng

    (Zhejiang Sci-Tech University)

  • Zhengqing Zhang

    (Tiangong University)

  • Zhuozhi Lai

    (Zhejiang University)

  • Shijie Yin

    (Zhejiang Sci-Tech University)

  • Weipeng Xian

    (Zhejiang University)

  • Qing-Wei Meng

    (Zhejiang University)

  • Zhifeng Dai

    (Zhejiang Sci-Tech University
    Longgang Institute of Zhejiang Sci-Tech University)

  • Yubing Xiong

    (Zhejiang Sci-Tech University
    Longgang Institute of Zhejiang Sci-Tech University)

  • Xiangju Meng

    (Zhejiang University)

  • Shengqian Ma

    (University of North Texas)

  • Feng-Shou Xiao

    (Zhejiang University)

  • Qi Sun

    (Zhejiang University)

Abstract

Membrane reactors are known for their efficiency and superior operability compared to traditional batch processes, but their limited diversity poses challenges in meeting various reaction requirements. Herein, we leverage the molecular tunability of covalent organic frameworks (COFs) to broaden their applicability in membrane reactors. Our COF membrane demonstrates an exceptional ability to achieve complete conversion in just 0.63 s at room temperature—a benchmark in efficiency for Knoevenagel condensation. This performance significantly surpasses that of the corresponding homogeneous catalyst and COF powder by factors of 176 and 375 in turnover frequency, respectively. The enhanced concentration of reactants and the rapid removal of generated water within the membrane greatly accelerate the reaction, reducing the apparent activation energy. Consequently, this membrane reactor enables reactions that are unattainable using both COF powders and homogeneous catalysts. Considering the versatility, our findings highlight the substantial promise of COF-based membrane reactors in organic transformations.

Suggested Citation

  • Liping Zheng & Zhengqing Zhang & Zhuozhi Lai & Shijie Yin & Weipeng Xian & Qing-Wei Meng & Zhifeng Dai & Yubing Xiong & Xiangju Meng & Shengqian Ma & Feng-Shou Xiao & Qi Sun, 2024. "Covalent organic framework membrane reactor for boosting catalytic performance," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51250-8
    DOI: 10.1038/s41467-024-51250-8
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-51250-8
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-51250-8?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Lingting Ye & Hao Li & Kui Xie, 2022. "Sustainable ammonia production enabled by membrane reactor," Nature Sustainability, Nature, vol. 5(9), pages 787-794, September.
    2. Pei-Ye You & Kai-Ming Mo & Yu-Mei Wang & Qiang Gao & Xiao-Chun Lin & Jia-Tong Lin & Mo Xie & Rong-Jia Wei & Guo-Hong Ning & Dan Li, 2024. "Reversible modulation of interlayer stacking in 2D copper-organic frameworks for tailoring porosity and photocatalytic activity," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Meidi Wang & Penghui Zhang & Xu Liang & Junyi Zhao & Yawei Liu & Yu Cao & Hongjian Wang & Yu Chen & Zhiming Zhang & Fusheng Pan & Zhenjie Zhang & Zhongyi Jiang, 2022. "Ultrafast seawater desalination with covalent organic framework membranes," Nature Sustainability, Nature, vol. 5(6), pages 518-526, June.
    4. Qing Guo & Zhuozhi Lai & Xiuhui Zuo & Weipeng Xian & Shaochun Wu & Liping Zheng & Zhifeng Dai & Sai Wang & Qi Sun, 2023. "Photoelectric responsive ionic channel for sustainable energy harvesting," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    5. Hao Yang & Jinhui Xu & Hui Cao & Jie Wu & Dan Zhao, 2023. "Recovery of homogeneous photocatalysts by covalent organic framework membranes," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Shijie Yin & Jianguo Li & Zhuozhi Lai & Qing-Wei Meng & Weipeng Xian & Zhifeng Dai & Sai Wang & Li Zhang & Yubing Xiong & Shengqian Ma & Qi Sun, 2024. "Giant gateable thermoelectric conversion by tuning the ion linkage interactions in covalent organic framework membranes," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Luo, Qizhao & Pei, Junxian & Yun, Panfeng & Hu, Xuejiao & Cao, Bin & Shan, Kunpeng & Tang, Bin & Huang, Kaiming & Chen, Aofei & Huang, Lu & Huang, Zhi & Jiang, Haifeng, 2023. "Simultaneous water production and electricity generation driven by synergistic temperature-salinity gradient in thermo-osmosis process," Applied Energy, Elsevier, vol. 351(C).
    3. Qian Zhang & Bo Gao & Ling Zhang & Xiaopeng Liu & Jixiang Cui & Yijun Cao & Hongbo Zeng & Qun Xu & Xinwei Cui & Lei Jiang, 2023. "Anomalous water molecular gating from atomic-scale graphene capillaries for precise and ultrafast molecular sieving," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    4. Yu-Xin Chen & Haidong Yu & Lihua Wu & Yuan-Jun Tong & Jianqiao Xu & Huan Pang & Chao Wu & Tian Tian & Gangfeng Ouyang, 2024. "Unlocking multi-photon excited luminescence in pyrazolate trinuclear gold clusters for dynamic cell imaging," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    5. Zichuang Li & Yangfan Lu & Jiang Li & Miao Xu & Yanpeng Qi & Sang-Won Park & Masaaki Kitano & Hideo Hosono & Jie-Sheng Chen & Tian-Nan Ye, 2023. "Multiple reaction pathway on alkaline earth imide supported catalysts for efficient ammonia synthesis," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    6. Zongyao Zhou & Kangning Zhao & Heng-Yu Chi & Yueqing Shen & Shuqing Song & Kuang-Jung Hsu & Mojtaba Chevalier & Wenxiong Shi & Kumar Varoon Agrawal, 2024. "Electrochemical-repaired porous graphene membranes for precise ion-ion separation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    7. Qinghua Liu & Ming Liu & Zhe Zhang & Congcong Yin & Jianghai Long & Mingjie Wei & Yong Wang, 2024. "Covalent organic framework membranes with vertically aligned nanorods for efficient separation of rare metal ions," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    8. Si-Hua Liu & Jun-Hao Zhou & Chunrui Wu & Peng Zhang & Xingzhong Cao & Jian-Ke Sun, 2024. "Sub-8 nm networked cage nanofilm with tunable nanofluidic channels for adaptive sieving," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    9. Hai Liu & Xinxi Huang & Yang Wang & Baian Kuang & Wanbin Li, 2024. "Nanowire-assisted electrochemical perforation of graphene oxide nanosheets for molecular separation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51250-8. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.