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Melt-quenched glass formation of a family of metal-carboxylate frameworks

Author

Listed:
  • Wen-Long Xue

    (Capital Normal University
    Technische Universität Dortmund)

  • Guo-Qiang Li

    (Capital Normal University)

  • Hui Chen

    (Capital Normal University
    Xi’an University of Architecture and Technology)

  • Yu-Chen Han

    (Capital Normal University)

  • Li Feng

    (Capital Normal University)

  • Lu Wang

    (Capital Normal University)

  • Xiao-Ling Gu

    (Capital Normal University)

  • Si-Yuan Hu

    (Capital Normal University)

  • Yu-Heng Deng

    (Capital Normal University)

  • Lei Tan

    (Wuhan University of Technology)

  • Martin T. Dove

    (Sichuan University)

  • Wei Li

    (Nankai University)

  • Jiangwei Zhang

    (Inner Mongolia University)

  • Hongliang Dong

    (Center for High Pressure Science and Technology Advanced Research, Pudong)

  • Zhiqiang Chen

    (Center for High Pressure Science and Technology Advanced Research, Pudong)

  • Wei-Hua Deng

    (Chinese Academy of Sciences, Fuzhou)

  • Gang Xu

    (Chinese Academy of Sciences, Fuzhou)

  • Guo Wang

    (Capital Normal University)

  • Chong-Qing Wan

    (Capital Normal University
    Chinese Academy of Sciences, Fuzhou
    Tsinghua University)

Abstract

Metal-organic framework (MOF) glasses are an emerging class of glasses which complement traditional inorganic, organic and metallic counterparts due to their hybrid nature. Although a few zeolitic imidazolate frameworks have been made into glasses, how to melt and quench the largest subclass of MOFs, metal carboxylate frameworks, into glasses remains challenging. Here, we develop a strategy by grafting the zwitterions on the carboxylate ligands and incorporating organic acids in the framework channels to enable the glass formation. The charge delocalization of zwitterion-acid subsystem and the densely filled channels facilitate the coordination bonding mismatch and thus reduce the melting temperature. Following melt-quenching realizes the glass formation of a family of carboxylate MOFs (UiO-67, UiO-68 and DUT-5), which are usually believed to be un-meltable. Our work opens up an avenue for melt-quenching porous molecular solids into glasses.

Suggested Citation

  • Wen-Long Xue & Guo-Qiang Li & Hui Chen & Yu-Chen Han & Li Feng & Lu Wang & Xiao-Ling Gu & Si-Yuan Hu & Yu-Heng Deng & Lei Tan & Martin T. Dove & Wei Li & Jiangwei Zhang & Hongliang Dong & Zhiqiang Che, 2024. "Melt-quenched glass formation of a family of metal-carboxylate frameworks," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-46311-x
    DOI: 10.1038/s41467-024-46311-x
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    References listed on IDEAS

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