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Metal-organic framework derived crystalline nanocarbon for Fenton-like reaction

Author

Listed:
  • Tingting Lian

    (Max Planck Institute of Colloids and Interfaces)

  • Li Xu

    (University of Science and Technology of China)

  • Diana Piankova

    (Max Planck Institute of Colloids and Interfaces)

  • Jin-Lin Yang

    (Nanyang Technological University)

  • Nadezda V. Tarakina

    (Max Planck Institute of Colloids and Interfaces)

  • Yang Wang

    (Max Planck Institute of Colloids and Interfaces
    University of Science and Technology of China)

  • Markus Antonietti

    (Max Planck Institute of Colloids and Interfaces)

Abstract

Nanoporous carbons with tailorable nanoscale texture and long-range ordered structure are promising candidates for energy, environmental and catalytic applications, while the current synthetic methods do not allow elaborate control of local structure. Here we report a salt-assisted strategy to obtain crystalline nanocarbon from direct carbonization of metal-organic frameworks (MOFs). The crystalline product maintains a highly ordered two-dimensional (2D) stacking mode and substantially differs from the traditional weakly ordered patterns of nanoporous carbons upon high-temperature pyrolysis. The MOF-derived crystalline nanocarbon (MCC) comes with a high level of nitrogen and oxygen terminating the 2D layers and shows an impressive performance as a carbocatalyst in Fenton-like reaction for water purification. The successful preparation of MCC illustrates the possibility to discover other crystalline heteroatom-doped carbon phases starting from correctly designed organic precursors and appropriate templating reactions.

Suggested Citation

  • Tingting Lian & Li Xu & Diana Piankova & Jin-Lin Yang & Nadezda V. Tarakina & Yang Wang & Markus Antonietti, 2024. "Metal-organic framework derived crystalline nanocarbon for Fenton-like reaction," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50476-w
    DOI: 10.1038/s41467-024-50476-w
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    References listed on IDEAS

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    1. Lu Zhao & Yun Zhang & Lin-Bo Huang & Xiao-Zhi Liu & Qing-Hua Zhang & Chao He & Ze-Yuan Wu & Lin-Juan Zhang & Jinpeng Wu & Wanli Yang & Lin Gu & Jin-Song Hu & Li-Jun Wan, 2019. "Cascade anchoring strategy for general mass production of high-loading single-atomic metal-nitrogen catalysts," Nature Communications, Nature, vol. 10(1), pages 1-11, December.
    2. Zhimi Hu & Xu Xiao & Huanyu Jin & Tianqi Li & Ming Chen & Zhun Liang & Zhengfeng Guo & Jia Li & Jun Wan & Liang Huang & Yanrong Zhang & Guang Feng & Jun Zhou, 2017. "Rapid mass production of two-dimensional metal oxides and hydroxides via the molten salts method," Nature Communications, Nature, vol. 8(1), pages 1-9, August.
    3. Hailian Li & Mohamed Eddaoudi & M. O'Keeffe & O. M. Yaghi, 1999. "Design and synthesis of an exceptionally stable and highly porous metal-organic framework," Nature, Nature, vol. 402(6759), pages 276-279, November.
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