IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-33912-7.html
   My bibliography  Save this article

Insights into memory effect mechanisms of layered double hydroxides with solid-state NMR spectroscopy

Author

Listed:
  • Li Jin

    (Nanjing University)

  • Xiaoyuan Zhou

    (Nanjing University)

  • Fang Wang

    (Nanjing University)

  • Xiang Ning

    (Nanjing University)

  • Yujie Wen

    (Nanjing University)

  • Benteng Song

    (Nanjing University)

  • Changju Yang

    (Nanjing University)

  • Di Wu

    (Nanjing University of Finance and Economics)

  • Xiaokang Ke

    (Nanjing University)

  • Luming Peng

    (Nanjing University
    Nanjing University
    Nanjing University)

Abstract

Layered double oxides (LDOs) can restore the parent layered double hydroxides (LDHs) structure under hydrous conditions, and this “memory effect” plays a critical role in the applications of LDHs, yet the detailed mechanism is still under debate. Here, we apply a strategy based on ex situ and in situ solid-state NMR spectroscopy to monitor the Mg/Al-LDO structure changes during recovery at the atomic scale. Despite the common belief that aqueous solution is required, we discover that the structure recovery can occur in a virtually solid-state process. Local structural information obtained with NMR spectroscopy shows that the recovery in aqueous solution follows dissolution-recrystallization mechanism, while the solid-state recovery is retro-topotactic, indicating a true “memory effect”. The amount of water is key in determining the interactions of water with oxides, thus the memory effect mechanism. The results also provide a more environmentally friendly and economically feasible LDHs preparation route.

Suggested Citation

  • Li Jin & Xiaoyuan Zhou & Fang Wang & Xiang Ning & Yujie Wen & Benteng Song & Changju Yang & Di Wu & Xiaokang Ke & Luming Peng, 2022. "Insights into memory effect mechanisms of layered double hydroxides with solid-state NMR spectroscopy," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33912-7
    DOI: 10.1038/s41467-022-33912-7
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-33912-7
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-022-33912-7?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Evan Wenbo Zhao & Tao Liu & Erlendur Jónsson & Jeongjae Lee & Israel Temprano & Rajesh B. Jethwa & Anqi Wang & Holly Smith & Javier Carretero-González & Qilei Song & Clare P. Grey, 2020. "In situ NMR metrology reveals reaction mechanisms in redox flow batteries," Nature, Nature, vol. 579(7798), pages 224-228, March.
    2. Zhimi Hu & Xu Xiao & Huanyu Jin & Tianqi Li & Ming Chen & Zhun Liang & Zhengfeng Guo & Jia Li & Jun Wan & Liang Huang & Yanrong Zhang & Guang Feng & Jun Zhou, 2017. "Rapid mass production of two-dimensional metal oxides and hydroxides via the molten salts method," Nature Communications, Nature, vol. 8(1), pages 1-9, August.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yuanyuan Zhang & Xiaohua Zhang & Quanquan Pang & Jianhua Yan, 2023. "Control of metal oxides’ electronic conductivity through visual intercalation chemical reactions," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Dominic Hey & Rajesh B. Jethwa & Nadia L. Farag & Bernardine L. D. Rinkel & Evan Wenbo Zhao & Clare P. Grey, 2023. "Identifying and preventing degradation in flavin mononucleotide-based redox flow batteries via NMR and EPR spectroscopy," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Jing-Yang Chung & Yanwen Yuan & Tara P. Mishra & Chithralekha Joseph & Pieremanuele Canepa & Pranay Ranjan & El Hadi S. Sadki & Silvija Gradečak & Slaven Garaj, 2024. "Structure and exfoliation mechanism of two-dimensional boron nanosheets," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    4. Tingting Lian & Li Xu & Diana Piankova & Jin-Lin Yang & Nadezda V. Tarakina & Yang Wang & Markus Antonietti, 2024. "Metal-organic framework derived crystalline nanocarbon for Fenton-like reaction," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    5. Rémy Richard Jacquemond & Maxime van der Heijden & Emre Burak Boz & Eric Ricardo Carreón Ruiz & Katharine Virginia Greco & Jeffrey Adam Kowalski & Vanesa Muñoz Perales & Fikile Richard Brushett & Kitt, 2024. "Quantifying concentration distributions in redox flow batteries with neutron radiography," Nature Communications, Nature, vol. 15(1), pages 1-16, December.
    6. Tianze Zhang & Libo Chang & Xiaofeng Zhang & Hujie Wan & Na Liu & Liujiang Zhou & Xu Xiao, 2022. "Simultaneously tuning interlayer spacing and termination of MXenes by Lewis-basic halides," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    7. Sanat Vibhas Modak & Wanggang Shen & Siddhant Singh & Dylan Herrera & Fairooz Oudeif & Bryan R. Goldsmith & Xun Huan & David G. Kwabi, 2023. "Understanding capacity fade in organic redox-flow batteries by combining spectroscopy with statistical inference techniques," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    8. Chunchun Ye & Anqi Wang & Charlotte Breakwell & Rui Tan & C. Grazia Bezzu & Elwin Hunter-Sellars & Daryl R. Williams & Nigel P. Brandon & Peter A. A. Klusener & Anthony R. Kucernak & Kim E. Jelfs & Ne, 2022. "Development of efficient aqueous organic redox flow batteries using ion-sieving sulfonated polymer membranes," Nature Communications, Nature, vol. 13(1), pages 1-13, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33912-7. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.