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Anionic polymerization of nonaromatic maleimide to achieve full-color nonconventional luminescence

Author

Listed:
  • Xin Ji

    (Institute of Chemistry Chinese Academy of Sciences (CAS)
    University of Chinese Academy of Sciences)

  • Weiguo Tian

    (Institute of Chemistry Chinese Academy of Sciences (CAS))

  • Kunfeng Jin

    (Institute of Chemistry Chinese Academy of Sciences (CAS))

  • Huailing Diao

    (Institute of Chemistry Chinese Academy of Sciences (CAS)
    University of Chinese Academy of Sciences)

  • Xin Huang

    (Tianjin University)

  • Guangjie Song

    (Institute of Chemistry Chinese Academy of Sciences (CAS))

  • Jun Zhang

    (Institute of Chemistry Chinese Academy of Sciences (CAS)
    University of Chinese Academy of Sciences)

Abstract

Nonconventional or nonconjugated luminophore without polycyclic aromatics or extended π-conjugation is a rising star in the area of luminescent materials. However, continuously tuning the emission color within a broad visible region via rational molecular design remains quite challenging because the mechanism of nonconventional luminescence is not fully understood. Herein, we present a new class of nonconventional luminophores, poly(maleimide)s (PMs), with full-color emission that can be finely regulated by anionic polymerization even at ambient temperature. Interestingly, the general characteristics of nonconventional luminescence, cluster-triggered emission, e.g., concentration-enhanced emission, are not observed in PMs. Instead, PMs have features similar to aggregation-caused quenching due to boosted intra/inter-molecular charge transfer. Such a biocompatible luminescent material synthesized from a low-cost monomer shows great prospects in large-scale production and applications, including security printing, fingerprint identification, metal ion recognition, etc. It also provides a new platform of rational molecular design to achieve full-color nonconventional luminescence without any aromatics.

Suggested Citation

  • Xin Ji & Weiguo Tian & Kunfeng Jin & Huailing Diao & Xin Huang & Guangjie Song & Jun Zhang, 2022. "Anionic polymerization of nonaromatic maleimide to achieve full-color nonconventional luminescence," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-31547-2
    DOI: 10.1038/s41467-022-31547-2
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    References listed on IDEAS

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    1. Tianwen Zhu & Tianjia Yang & Qiang Zhang & Wang Zhang Yuan, 2022. "Clustering and halogen effects enabled red/near-infrared room temperature phosphorescence from aliphatic cyclic imides," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
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    Cited by:

    1. Bo Song & Jianyu Zhang & Jiadong Zhou & Anjun Qin & Jacky W. Y. Lam & Ben Zhong Tang, 2023. "Facile conversion of water to functional molecules and cross-linked polymeric films with efficient clusteroluminescence," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    2. Gonzalo Díaz Mirón & Jonathan A. Semelak & Luca Grisanti & Alex Rodriguez & Irene Conti & Martina Stella & Jayaramakrishnan Velusamy & Nicola Seriani & Nadja Došlić & Ivan Rivalta & Marco Garavelli & , 2023. "The carbonyl-lock mechanism underlying non-aromatic fluorescence in biological matter," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    3. Qiuju Li & Xingyi Wang & Qisu Huang & Zhuo Li & Ben Zhong Tang & Shun Mao, 2023. "Molecular-level enhanced clusterization-triggered emission of nonconventional luminophores in dilute aqueous solution," Nature Communications, Nature, vol. 14(1), pages 1-11, December.

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