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Autonomous self-healing supramolecular polymer transistors for skin electronics

Author

Listed:
  • Ngoc Thanh Phuong Vo

    (Kyung Hee University)

  • Tae Uk Nam

    (Kyung Hee University)

  • Min Woo Jeong

    (Kyung Hee University)

  • Jun Su Kim

    (Kyung Hee University)

  • Kyu Ho Jung

    (Kyung Hee University)

  • Yeongjun Lee

    (Stanford University
    KAIST)

  • Guorong Ma

    (University of Southern Mississippi)

  • Xiaodan Gu

    (University of Southern Mississippi)

  • Jeffrey B.-H. Tok

    (Stanford University)

  • Tae Il Lee

    (Gachon University)

  • Zhenan Bao

    (Stanford University)

  • Jin Young Oh

    (Kyung Hee University)

Abstract

Skin-like field-effect transistors are key elements of bio-integrated devices for future user-interactive electronic-skin applications. Despite recent rapid developments in skin-like stretchable transistors, imparting self-healing ability while maintaining necessary electrical performance to these transistors remains a challenge. Herein, we describe a stretchable polymer transistor capable of autonomous self-healing. The active material consists of a blend of an electrically insulating supramolecular polymer with either semiconducting polymers or vapor-deposited metal nanoclusters. A key feature is to employ the same supramolecular self-healing polymer matrix for all active layers, i.e., conductor/semiconductor/dielectric layers, in the skin-like transistor. This provides adhesion and intimate contact between layers, which facilitates effective charge injection and transport under strain after self-healing. Finally, we fabricate skin-like self-healing circuits, including NAND and NOR gates and inverters, both of which are critical components of arithmetic logic units. This work greatly advances practical self-healing skin electronics.

Suggested Citation

  • Ngoc Thanh Phuong Vo & Tae Uk Nam & Min Woo Jeong & Jun Su Kim & Kyu Ho Jung & Yeongjun Lee & Guorong Ma & Xiaodan Gu & Jeffrey B.-H. Tok & Tae Il Lee & Zhenan Bao & Jin Young Oh, 2024. "Autonomous self-healing supramolecular polymer transistors for skin electronics," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-47718-2
    DOI: 10.1038/s41467-024-47718-2
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    References listed on IDEAS

    as
    1. Jin Young Oh & Simon Rondeau-Gagné & Yu-Cheng Chiu & Alex Chortos & Franziska Lissel & Ging-Ji Nathan Wang & Bob C. Schroeder & Tadanori Kurosawa & Jeffrey Lopez & Toru Katsumata & Jie Xu & Chenxin Zh, 2016. "Intrinsically stretchable and healable semiconducting polymer for organic transistors," Nature, Nature, vol. 539(7629), pages 411-415, November.
    2. Siegfried Bauer & Martin Kaltenbrunner, 2016. "Semiconductors that stretch and heal," Nature, Nature, vol. 539(7629), pages 365-367, November.
    3. Jinhong Park & Duhwan Seong & Yong Jun Park & Sang Hyeok Park & Hyunjin Jung & Yewon Kim & Hyoung Won Baac & Mikyung Shin & Seunghyun Lee & Minbaek Lee & Donghee Son, 2022. "Reversible electrical percolation in a stretchable and self-healable silver-gradient nanocomposite bilayer," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    4. Kaushik Parida & Gurunathan Thangavel & Guofa Cai & Xinran Zhou & Sangbaek Park & Jiaqing Xiong & Pooi See Lee, 2019. "Extremely stretchable and self-healing conductor based on thermoplastic elastomer for all-three-dimensional printed triboelectric nanogenerator," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    5. Daewoo Suh & K. P. Faseela & Wonjoon Kim & Chanyong Park & Jang Gyun Lim & Sungwon Seo & Moon Ki Kim & Hyungpil Moon & Seunghyun Baik, 2020. "Electron tunneling of hierarchically structured silver nanosatellite particles for highly conductive healable nanocomposites," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
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