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A single site ruthenium catalyst for robust soot oxidation without platinum or palladium

Author

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  • Yuanfeng Li

    (China University of Petroleum)

  • Tian Qin

    (Shanghai Jiao Tong University)

  • Yuechang Wei

    (China University of Petroleum)

  • Jing Xiong

    (China University of Petroleum)

  • Peng Zhang

    (China University of Petroleum)

  • Kezhen Lai

    (China University of Petroleum)

  • Hongjie Chi

    (China University of Petroleum)

  • Xi Liu

    (Shanghai Jiao Tong University)

  • Liwei Chen

    (Shanghai Jiao Tong University)

  • Xiaolin Yu

    (Chinese Academy of Sciences)

  • Zhen Zhao

    (China University of Petroleum)

  • Lina Li

    (Shanghai Advanced Research Institute)

  • Jian Liu

    (China University of Petroleum)

Abstract

The quest for efficient non-Pt/Pd catalysts has proved to be a formidable challenge for auto-exhaust purification. Herein, we present an approach to construct a robust catalyst by embedding single-atom Ru sites onto the surface of CeO2 through a gas bubbling-assisted membrane deposition method. The formed single-atom Ru sites, which occupy surface lattice sites of CeO2, can improve activation efficiency for NO and O2. Remarkably, the Ru1/CeO2 catalyst exhibits exceptional catalytic performance and stability during auto-exhaust carbon particle oxidation (soot), rivaling commercial Pt-based catalysts. The turnover frequency (0.218 h−1) is a nine-fold increase relative to the Ru nanoparticle catalyst. We further show that the strong interfacial charge transfer within the atomically dispersed Ru active site greatly enhances the rate-determining step of NO oxidation, resulting in a substantial reduction of the apparent activation energy during soot oxidation. The single-atom Ru catalyst represents a step toward reducing dependence on Pt/Pd-based catalysts.

Suggested Citation

  • Yuanfeng Li & Tian Qin & Yuechang Wei & Jing Xiong & Peng Zhang & Kezhen Lai & Hongjie Chi & Xi Liu & Liwei Chen & Xiaolin Yu & Zhen Zhao & Lina Li & Jian Liu, 2023. "A single site ruthenium catalyst for robust soot oxidation without platinum or palladium," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-42935-7
    DOI: 10.1038/s41467-023-42935-7
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    References listed on IDEAS

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    1. Zhibo Liu & Fei Huang & Mi Peng & Yunlei Chen & Xiangbin Cai & Linlin Wang & Zenan Hu & Xiaodong Wen & Ning Wang & Dequan Xiao & Hong Jiang & Hongbin Sun & Hongyang Liu & Ding Ma, 2021. "Tuning the selectivity of catalytic nitriles hydrogenation by structure regulation in atomically dispersed Pd catalysts," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    2. Yamei Sun & Ziqian Xue & Qinglin Liu & Yaling Jia & Yinle Li & Kang Liu & Yiyang Lin & Min Liu & Guangqin Li & Cheng-Yong Su, 2021. "Modulating electronic structure of metal-organic frameworks by introducing atomically dispersed Ru for efficient hydrogen evolution," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    3. Kaipeng Liu & Xintian Zhao & Guoqing Ren & Tao Yang & Yujing Ren & Adam Fraser Lee & Yang Su & Xiaoli Pan & Jingcai Zhang & Zhiqiang Chen & Jingyi Yang & Xiaoyan Liu & Tong Zhou & Wei Xi & Jun Luo & C, 2020. "Strong metal-support interaction promoted scalable production of thermally stable single-atom catalysts," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    4. Jiace Hao & Zechao Zhuang & Kecheng Cao & Guohua Gao & Chan Wang & Feili Lai & Shuanglong Lu & Piming Ma & Weifu Dong & Tianxi Liu & Mingliang Du & Han Zhu, 2022. "Unraveling the electronegativity-dominated intermediate adsorption on high-entropy alloy electrocatalysts," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    5. Xueke Wu & Zuochao Wang & Dan Zhang & Yingnan Qin & Minghui Wang & Yi Han & Tianrong Zhan & Bo Yang & Shaoxiang Li & Jianping Lai & Lei Wang, 2021. "Solvent-free microwave synthesis of ultra-small Ru-Mo2C@CNT with strong metal-support interaction for industrial hydrogen evolution," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
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