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Water-assisted hydrogen spillover in Pt nanoparticle-based metal–organic framework composites

Author

Listed:
  • Zhida Gu

    (Northeastern University
    Nanjing Tech University (NanjingTech))

  • Mengke Li

    (Nanjing Tech University (NanjingTech))

  • Cheng Chen

    (Nanjing Tech University (NanjingTech))

  • Xinglong Zhang

    (Nanjing Tech University (NanjingTech))

  • Chengyang Luo

    (Nanjing Tech University (NanjingTech))

  • Yutao Yin

    (Nanjing Tech University (NanjingTech))

  • Ruifa Su

    (Nanjing Tech University (NanjingTech))

  • Suoying Zhang

    (Nanjing Tech University (NanjingTech))

  • Yu Shen

    (Nanjing University of Posts & Telecommunications)

  • Yu Fu

    (Northeastern University)

  • Weina Zhang

    (Nanjing Tech University (NanjingTech))

  • Fengwei Huo

    (Nanjing Tech University (NanjingTech))

Abstract

Hydrogen spillover is the migration of activated hydrogen atoms from a metal particle onto the surface of catalyst support, which has made significant progress in heterogeneous catalysis. The phenomenon has been well researched on oxide supports, yet its occurrence, detection method and mechanism on non-oxide supports such as metal–organic frameworks (MOFs) remain controversial. Herein, we develop a facile strategy for efficiency enhancement of hydrogen spillover on various MOFs with the aid of water molecules. By encapsulating platinum (Pt) nanoparticles in MOF-801 for activating hydrogen and hydrogenation of C=C in the MOF ligand as activated hydrogen detector, a research platform is built with Pt@MOF-801 to measure the hydrogenation region for quantifying the efficiency and spatial extent of hydrogen spillover. A water-assisted hydrogen spillover path is found with lower migration energy barrier than the traditional spillover path via ligand. The synergy of the two paths explains a significant boost of hydrogen spillover in MOF-801 from imperceptible existence to spanning at least 100-nm-diameter region. Moreover, such strategy shows universality in different MOF and covalent organic framework materials for efficiency promotion of hydrogen spillover and improvement of catalytic activity and antitoxicity, opening up new horizons for catalyst design in porous crystalline materials.

Suggested Citation

  • Zhida Gu & Mengke Li & Cheng Chen & Xinglong Zhang & Chengyang Luo & Yutao Yin & Ruifa Su & Suoying Zhang & Yu Shen & Yu Fu & Weina Zhang & Fengwei Huo, 2023. "Water-assisted hydrogen spillover in Pt nanoparticle-based metal–organic framework composites," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-40697-w
    DOI: 10.1038/s41467-023-40697-w
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    References listed on IDEAS

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    1. Waiz Karim & Clelia Spreafico & Armin Kleibert & Jens Gobrecht & Joost VandeVondele & Yasin Ekinci & Jeroen A. van Bokhoven, 2017. "Catalyst support effects on hydrogen spillover," Nature, Nature, vol. 541(7635), pages 68-71, January.
    2. Juhwan Im & Hyeyoung Shin & Haeyoun Jang & Hyungjun Kim & Minkee Choi, 2014. "Maximizing the catalytic function of hydrogen spillover in platinum-encapsulated aluminosilicates with controlled nanostructures," Nature Communications, Nature, vol. 5(1), pages 1-8, May.
    3. Mi Xiong & Zhe Gao & Peng Zhao & Guofu Wang & Wenjun Yan & Shuangfeng Xing & Pengfei Wang & Jingyuan Ma & Zheng Jiang & Xingchen Liu & Jiping Ma & Jie Xu & Yong Qin, 2020. "In situ tuning of electronic structure of catalysts using controllable hydrogen spillover for enhanced selectivity," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    4. Kohsuke Mori & Naoki Hashimoto & Naoto Kamiuchi & Hideto Yoshida & Hisayoshi Kobayashi & Hiromi Yamashita, 2021. "Hydrogen spillover-driven synthesis of high-entropy alloy nanoparticles as a robust catalyst for CO2 hydrogenation," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    5. Guowu Zhan & Hua Chun Zeng, 2018. "Hydrogen spillover through Matryoshka-type (ZIFs@)n−1ZIFs nanocubes," Nature Communications, Nature, vol. 9(1), pages 1-12, December.
    6. Mingwu Tan & Yanling Yang & Ying Yang & Jiali Chen & Zhaoxia Zhang & Gang Fu & Jingdong Lin & Shaolong Wan & Shuai Wang & Yong Wang, 2022. "Hydrogen spillover assisted by oxygenate molecules over nonreducible oxides," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    7. Jiankang Zhang & Zhe Gao & Sen Wang & Guofu Wang & Xiaofeng Gao & Baiyan Zhang & Shuangfeng Xing & Shichao Zhao & Yong Qin, 2019. "Origin of synergistic effects in bicomponent cobalt oxide-platinum catalysts for selective hydrogenation reaction," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    8. Zhe Gao & Guofu Wang & Tingyu Lei & Zhengxing Lv & Mi Xiong & Liancheng Wang & Shuangfeng Xing & Jingyuan Ma & Zheng Jiang & Yong Qin, 2022. "Enhanced hydrogen generation by reverse spillover effects over bicomponent catalysts," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
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    1. Xiao-Jue Bai & Caoyu Yang & Zhiyong Tang, 2024. "Enabling long-distance hydrogen spillover in nonreducible metal-organic frameworks for catalytic reaction," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

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