IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-39887-3.html
   My bibliography  Save this article

Breathing porous liquids based on responsive metal-organic framework particles

Author

Listed:
  • Athanasios Koutsianos

    (Technische Universität Dortmund)

  • Roman Pallach

    (Technische Universität Dortmund)

  • Louis Frentzel-Beyme

    (Technische Universität Dortmund)

  • Chinmoy Das

    (Technische Universität Dortmund)

  • Michael Paulus

    (Technische Universität Dortmund)

  • Christian Sternemann

    (Technische Universität Dortmund)

  • Sebastian Henke

    (Technische Universität Dortmund)

Abstract

Responsive metal-organic frameworks (MOFs) that display sigmoidal gas sorption isotherms triggered by discrete gas pressure-induced structural transformations are highly promising materials for energy related applications. However, their lack of transportability via continuous flow hinders their application in systems and designs that rely on liquid agents. We herein present examples of responsive liquid systems which exhibit a breathing behaviour and show step-shaped gas sorption isotherms, akin to the distinct oxygen saturation curve of haemoglobin in blood. Dispersions of flexible MOF nanocrystals in a size-excluded silicone oil form stable porous liquids exhibiting gated uptake for CO2, propane and propylene, as characterized by sigmoidal gas sorption isotherms with distinct transition steps. In situ X-ray diffraction studies show that the sigmoidal gas sorption curve is caused by a narrow pore to large pore phase transformation of the flexible MOF nanocrystals, which respond to gas pressure despite being dispersed in silicone oil. Given the established flexible nature and tunability of a range of MOFs, these results herald the advent of breathing porous liquids whose sorption properties can be tuned rationally for a variety of technological applications.

Suggested Citation

  • Athanasios Koutsianos & Roman Pallach & Louis Frentzel-Beyme & Chinmoy Das & Michael Paulus & Christian Sternemann & Sebastian Henke, 2023. "Breathing porous liquids based on responsive metal-organic framework particles," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39887-3
    DOI: 10.1038/s41467-023-39887-3
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-39887-3
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-39887-3?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Huang Liu & Bei Liu & Li-Chiang Lin & Guangjin Chen & Yuqing Wu & Jin Wang & Xueteng Gao & Yining Lv & Yong Pan & Xiaoxin Zhang & Xianren Zhang & Lanying Yang & Changyu Sun & Berend Smit & Wenchuan Wa, 2014. "A hybrid absorption–adsorption method to efficiently capture carbon," Nature Communications, Nature, vol. 5(1), pages 1-7, December.
    2. Nicola Giri & Mario G. Del Pópolo & Gavin Melaugh & Rebecca L. Greenaway & Klaus Rätzke & Tönjes Koschine & Laure Pison & Margarida F. Costa Gomes & Andrew I. Cooper & Stuart L. James, 2015. "Liquids with permanent porosity," Nature, Nature, vol. 527(7577), pages 216-220, November.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chen, Yifeng & Song, Shuailong & Li, Ning & Wu, Jian & Lu, Xiaohua & Ji, Xiaoyan, 2022. "Developing hybrid 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide/titanium dioxide/water absorbent for CO2 separation," Applied Energy, Elsevier, vol. 326(C).
    2. Zhao, Xingxing & Ding, Yudong & Ma, Lijiao & Zhu, Xun & Wang, Hong & Cheng, Min & Liao, Qiang, 2023. "An amine-functionalized strategy to enhance the CO2 absorption of type III porous liquids," Energy, Elsevier, vol. 279(C).
    3. Zhuxiu Zhang & Baolin Yang & Bingjie Zhang & Mifen Cui & Jihai Tang & Xu Qiao, 2022. "Type II porous ionic liquid based on metal-organic cages that enables l-tryptophan identification," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    4. Li, Xiaoqiang & Ding, Yudong & Guo, Liheng & Liao, Qiang & Zhu, Xun & Wang, Hong, 2019. "Non-aqueous energy-efficient absorbents for CO2 capture based on porous silica nanospheres impregnated with amine," Energy, Elsevier, vol. 171(C), pages 109-119.
    5. Yudong Ding & Liheng Guo & Xiaoqiang Li & Qiang Liao & Xun Zhu & Hong Wang, 2021. "CO2 absorption of anhydrous colloidal suspension based silica nanospheres with different microstructures," Energy & Environment, , vol. 32(8), pages 1437-1456, December.
    6. Ding, Yudong & Ma, Lijiao & Yang, Xiaoqiang & Zhu, Xun & Wang, Hong & Cheng, Min & Liao, Qiang, 2023. "Anhydrous multi-hybrid absorbent with low viscosity and high regeneration efficiency for post-combustion CO2 capture," Energy, Elsevier, vol. 263(PA).
    7. Chang He & Yu-Huang Zou & Duan-Hui Si & Zi-Ao Chen & Tian-Fu Liu & Rong Cao & Yuan-Biao Huang, 2023. "A porous metal-organic cage liquid for sustainable CO2 conversion reactions," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    8. Zhang, Ruihang & Wang, Zexin & Wei, Xiaoming & Peng, Xiaowan & Chen, Wan & Deng, Chun & Liu, Bei & Sun, Changyu & Chen, Guangjin, 2023. "Modelling and optimization of ethane recovery process from natural gas via ZIF-8/water-glycol slurry with low energy consumption," Energy, Elsevier, vol. 263(PA).

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39887-3. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.