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A porous metal-organic cage liquid for sustainable CO2 conversion reactions

Author

Listed:
  • Chang He

    (Chinese Academy of Sciences
    Fujian University of Technology
    University of Chinese Academy of Sciences)

  • Yu-Huang Zou

    (Chinese Academy of Sciences)

  • Duan-Hui Si

    (Chinese Academy of Sciences)

  • Zi-Ao Chen

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Tian-Fu Liu

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Rong Cao

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences
    Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China)

  • Yuan-Biao Huang

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

Abstract

Porous liquids are fluids with the permanent porosity, which can overcome the poor gas solubility limitations of conventional porous solid materials for three phase gas-liquid-solid reactions. However, preparation of porous liquids still requires the complicated and tedious use of porous hosts and bulky liquids. Herein, we develop a facile method to produce a porous metal-organic cage (MOC) liquid (Im-PL-Cage) by self-assembly of long polyethylene glycol (PEG)-imidazolium chain functional linkers, calixarene molecules and Zn ions. The Im-PL-Cage in neat liquid has permanent porosity and fluidity, endowing it with a high capacity of CO2 adsorption. Thus, the CO2 stored in an Im-PL-Cage can be efficiently converted to the value-added formylation product in the atmosphere, which far exceeds the porous MOC solid and nonporous PEG-imidazolium counterparts. This work offers a new method to prepare neat porous liquids for catalytic transformation of adsorbed gas molecules.

Suggested Citation

  • Chang He & Yu-Huang Zou & Duan-Hui Si & Zi-Ao Chen & Tian-Fu Liu & Rong Cao & Yuan-Biao Huang, 2023. "A porous metal-organic cage liquid for sustainable CO2 conversion reactions," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39089-x
    DOI: 10.1038/s41467-023-39089-x
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    1. Daniel P. Erdosy & Malia B. Wenny & Joy Cho & Christopher DelRe & Miranda V. Walter & Felipe Jiménez-Ángeles & Baofu Qiao & Ricardo Sanchez & Yifeng Peng & Brian D. Polizzotti & Monica Olvera Cruz & J, 2022. "Microporous water with high gas solubilities," Nature, Nature, vol. 608(7924), pages 712-718, August.
    2. Nicola Giri & Mario G. Del Pópolo & Gavin Melaugh & Rebecca L. Greenaway & Klaus Rätzke & Tönjes Koschine & Laure Pison & Margarida F. Costa Gomes & Andrew I. Cooper & Stuart L. James, 2015. "Liquids with permanent porosity," Nature, Nature, vol. 527(7577), pages 216-220, November.
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    Cited by:

    1. Yingguo Li & Jialun He & Guilong Lu & Chensheng Wang & Mengmeng Fu & Juan Deng & Fu Yang & Danfeng Jiang & Xiao Chen & Ziyi Yu & Yan Liu & Chao Yu & Yong Cui, 2024. "De novo construction of amine-functionalized metal-organic cages as heterogenous catalysts for microflow catalysis," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    2. Po-Chun Han & Chia-Hui Chuang & Shang-Wei Lin & Xiangmei Xiang & Zaoming Wang & Mako Kuzumoto & Shun Tokuda & Tomoki Tateishi & Alexandre Legrand & Min Ying Tsang & Hsiao-Ching Yang & Kevin C.-W. Wu &, 2024. "Phase-transformable metal-organic polyhedra for membrane processing and switchable gas separation," Nature Communications, Nature, vol. 15(1), pages 1-12, December.

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