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Site-specific anisotropic assembly of amorphous mesoporous subunits on crystalline metal–organic framework

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Listed:
  • Minchao Liu

    (Fudan University)

  • Cheng Shang

    (Fudan University)

  • Tiancong Zhao

    (Fudan University)

  • Hongyue Yu

    (Fudan University)

  • Yufang Kou

    (Fudan University)

  • Zirui Lv

    (Fudan University)

  • Mengmeng Hou

    (Fudan University)

  • Fan Zhang

    (Fudan University)

  • Qiaowei Li

    (Fudan University)

  • Dongyuan Zhao

    (Fudan University)

  • Xiaomin Li

    (Fudan University)

Abstract

As an important branch of anisotropic nanohybrids (ANHs) with multiple surfaces and functions, the porous ANHs (p-ANHs) have attracted extensive attentions because of the unique characteristics of high surface area, tunable pore structures and controllable framework compositions, etc. However, due to the large surface-chemistry and lattice mismatches between the crystalline and amorphous porous nanomaterials, the site-specific anisotropic assembly of amorphous subunits on crystalline host is challenging. Here, we report a selective occupation strategy to achieve site-specific anisotropic growth of amorphous mesoporous subunits on crystalline metal–organic framework (MOF). The amorphous polydopamine (mPDA) building blocks can be controllably grown on the {100} (type 1) or {110} (type 2) facets of crystalline ZIF-8 to form the binary super-structured p-ANHs. Based on the secondary epitaxial growth of tertiary MOF building blocks on type 1 and 2 nanostructures, the ternary p-ANHs with controllable compositions and architectures are also rationally synthesized (type 3 and 4). These intricate and unprecedented superstructures provide a good platform for the construction of nanocomposites with multiple functionalities and understanding of the structure-property-function relationships.

Suggested Citation

  • Minchao Liu & Cheng Shang & Tiancong Zhao & Hongyue Yu & Yufang Kou & Zirui Lv & Mengmeng Hou & Fan Zhang & Qiaowei Li & Dongyuan Zhao & Xiaomin Li, 2023. "Site-specific anisotropic assembly of amorphous mesoporous subunits on crystalline metal–organic framework," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36832-2
    DOI: 10.1038/s41467-023-36832-2
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    References listed on IDEAS

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    1. Chao Liu & Qiang Sun & Lina Lin & Jing Wang & Chaoqi Zhang & Chunhong Xia & Tong Bao & Jingjing Wan & Rong Huang & Jin Zou & Chengzhong Yu, 2020. "Ternary MOF-on-MOF heterostructures with controllable architectural and compositional complexity via multiple selective assembly," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    2. Joon Suk Oh & Sangmin Lee & Sharon C. Glotzer & Gi-Ra Yi & David J. Pine, 2019. "Colloidal fibers and rings by cooperative assembly," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
    3. Meiting Zhao & Kuo Yuan & Yun Wang & Guodong Li & Jun Guo & Lin Gu & Wenping Hu & Huijun Zhao & Zhiyong Tang, 2016. "Metal–organic frameworks as selectivity regulators for hydrogenation reactions," Nature, Nature, vol. 539(7627), pages 76-80, November.
    4. Qian Chen & Sung Chul Bae & Steve Granick, 2011. "Directed self-assembly of a colloidal kagome lattice," Nature, Nature, vol. 469(7330), pages 381-384, January.
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