IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-36714-7.html
   My bibliography  Save this article

Hybrid molecular graphene transistor as an operando and optoelectronic platform

Author

Listed:
  • Jorge Trasobares

    (IMDEA-Nanociencia, Cantoblanco
    Universidad Complutense de Madrid)

  • Juan Carlos Martín-Romano

    (IMDEA-Nanociencia, Cantoblanco)

  • Muhammad Waqas Khaliq

    (ALBA Synchrotron, Carrer de la llum 2-26
    University of Barcelona)

  • Sandra Ruiz-Gómez

    (ALBA Synchrotron, Carrer de la llum 2-26)

  • Michael Foerster

    (ALBA Synchrotron, Carrer de la llum 2-26)

  • Miguel Ángel Niño

    (ALBA Synchrotron, Carrer de la llum 2-26)

  • Patricia Pedraz

    (IMDEA-Nanociencia, Cantoblanco)

  • Yannick. J. Dappe

    (Centro de Astrobiología (CSIC-INTA))

  • Marina Calero Ory

    (SPEC, CEA, CNRS Université Paris‐Saclay)

  • Julia García-Pérez

    (IMDEA-Nanociencia, Cantoblanco)

  • María Acebrón

    (IMDEA-Nanociencia, Cantoblanco)

  • Manuel Rodríguez Osorio

    (IMDEA-Nanociencia, Cantoblanco)

  • María Teresa Magaz

    (Centro de Astrobiología (CSIC-INTA))

  • Alicia Gomez

    (Centro de Astrobiología (CSIC-INTA))

  • Rodolfo Miranda

    (SPEC, CEA, CNRS Université Paris‐Saclay
    Universidad Autónoma de Madrid)

  • Daniel Granados

    (IMDEA-Nanociencia, Cantoblanco)

Abstract

Lack of reproducibility hampers molecular devices integration into large-scale circuits. Thus, incorporating operando characterization can facilitate the understanding of multiple features producing disparities in different devices. In this work, we report the realization of hybrid molecular graphene field effect transistors (m-GFETs) based on 11-(Ferrocenyl)undecanethiol (FcC11SH) micro self-assembled monolayers (μSAMs) and high-quality graphene (Gr) in a back-gated configuration. On the one hand, Gr enables redox electron transfer, avoids molecular degradation and permits operando spectroscopy. On the other hand, molecular electrode decoration shifts the Gr Dirac point (VDP) to neutrality and generates a photocurrent in the Gr electron conduction regime. Benefitting from this heterogeneous response, the m-GFETs can implement optoelectronic AND/OR logic functions. Our approach represents a step forward in the field of molecular scale electronics with implications in sensing and computing based on sustainable chemicals.

Suggested Citation

  • Jorge Trasobares & Juan Carlos Martín-Romano & Muhammad Waqas Khaliq & Sandra Ruiz-Gómez & Michael Foerster & Miguel Ángel Niño & Patricia Pedraz & Yannick. J. Dappe & Marina Calero Ory & Julia García, 2023. "Hybrid molecular graphene transistor as an operando and optoelectronic platform," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36714-7
    DOI: 10.1038/s41467-023-36714-7
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-36714-7
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-36714-7?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. N. Clément & K. Nishiguchi & A. Fujiwara & D. Vuillaume, 2010. "One-by-one trap activation in silicon nanowire transistors," Nature Communications, Nature, vol. 1(1), pages 1-8, December.
    2. K. S. Novoselov & A. K. Geim & S. V. Morozov & D. Jiang & M. I. Katsnelson & I. V. Grigorieva & S. V. Dubonos & A. A. Firsov, 2005. "Two-dimensional gas of massless Dirac fermions in graphene," Nature, Nature, vol. 438(7065), pages 197-200, November.
    3. Michael N. Leuenberger & Daniel Loss, 2001. "Quantum computing in molecular magnets," Nature, Nature, vol. 410(6830), pages 789-793, April.
    4. Gabriel Puebla-Hellmann & Koushik Venkatesan & Marcel Mayor & Emanuel Lörtscher, 2018. "Metallic nanoparticle contacts for high-yield, ambient-stable molecular-monolayer devices," Nature, Nature, vol. 559(7713), pages 232-235, July.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Anffany Chen & Hauke Brand & Tobias Helbig & Tobias Hofmann & Stefan Imhof & Alexander Fritzsche & Tobias Kießling & Alexander Stegmaier & Lavi K. Upreti & Titus Neupert & Tomáš Bzdušek & Martin Greit, 2023. "Hyperbolic matter in electrical circuits with tunable complex phases," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    2. Anh-Luan Phan & Dai-Nam Le, 2021. "Electronic transport in two-dimensional strained Dirac materials under multi-step Fermi velocity barrier: transfer matrix method for supersymmetric systems," The European Physical Journal B: Condensed Matter and Complex Systems, Springer;EDP Sciences, vol. 94(8), pages 1-16, August.
    3. Wang, Qing & Han, Ning & Bokhari, Awais & Li, Xue & Cao, Yue & Asif, Saira & Shen, Zhengfeng & Si, Weimeng & Wang, Fagang & Klemeš, Jiří Jaromír & Zhao, Xiaolin, 2022. "Insights into MXenes-based electrocatalysts for oxygen reduction," Energy, Elsevier, vol. 255(C).
    4. Thanh Luan Phan & Sohyeon Seo & Yunhee Cho & Quoc An Vu & Young Hee Lee & Dinh Loc Duong & Hyoyoung Lee & Woo Jong Yu, 2022. "CNT-molecule-CNT (1D-0D-1D) van der Waals integration ferroelectric memory with 1-nm2 junction area," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    5. Di Molfetta, Giuseppe & Brachet, Marc & Debbasch, Fabrice, 2014. "Quantum walks in artificial electric and gravitational fields," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 397(C), pages 157-168.
    6. Juntao Zhang & Xiaozhi Liu & Yujin Ji & Xuerui Liu & Dong Su & Zhongbin Zhuang & Yu-Chung Chang & Chih-Wen Pao & Qi Shao & Zhiwei Hu & Xiaoqing Huang, 2023. "Atomic-thick metastable phase RhMo nanosheets for hydrogen oxidation catalysis," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    7. Chenli Huang & Rong Sun & Lipiao Bao & Xinyue Tian & Changwang Pan & Mengyang Li & Wangqiang Shen & Kun Guo & Bingwu Wang & Xing Lu & Song Gao, 2023. "A hard molecular nanomagnet from confined paramagnetic 3d-4f spins inside a fullerene cage," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    8. Cao, Rui-rui & Li, Xuan & Chen, Sai & Yuan, Hao-ran & Zhang, Xing-xiang, 2017. "Fabrication and characterization of novel shape-stabilized synergistic phase change materials based on PHDA/GO composites," Energy, Elsevier, vol. 138(C), pages 157-166.
    9. Ping’an Li & Yoram Selzer, 2022. "Molecular ensemble junctions with inter-molecular quantum interference," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    10. González, Ander & Goikolea, Eider & Barrena, Jon Andoni & Mysyk, Roman, 2016. "Review on supercapacitors: Technologies and materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 1189-1206.
    11. Dasari, Bhagya Lakshmi & Nouri, Jamshid M. & Brabazon, Dermot & Naher, Sumsun, 2017. "Graphene and derivatives – Synthesis techniques, properties and their energy applications," Energy, Elsevier, vol. 140(P1), pages 766-778.
    12. Chen, Yuanhan, 2024. "Cleaning Russian oil industry for energy resource exploration and industrial transformation towards zero carbon green recovery: Role of inclusive digital finance," Resources Policy, Elsevier, vol. 88(C).
    13. M. T. Greenaway & P. Kumaravadivel & J. Wengraf & L. A. Ponomarenko & A. I. Berdyugin & J. Li & J. H. Edgar & R. Krishna Kumar & A. K. Geim & L. Eaves, 2021. "Graphene’s non-equilibrium fermions reveal Doppler-shifted magnetophonon resonances accompanied by Mach supersonic and Landau velocity effects," Nature Communications, Nature, vol. 12(1), pages 1-6, December.
    14. Maria Karaulova & Abdullah Gök & Oliver Shackleton & Philip Shapira, 2016. "Science system path-dependencies and their influences: nanotechnology research in Russia," Scientometrics, Springer;Akadémiai Kiadó, vol. 107(2), pages 645-670, May.
    15. Zheyu Cheng & Yi-Jun Guan & Haoran Xue & Yong Ge & Ding Jia & Yang Long & Shou-Qi Yuan & Hong-Xiang Sun & Yidong Chong & Baile Zhang, 2024. "Three-dimensional flat Landau levels in an inhomogeneous acoustic crystal," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    16. Ying Zhou & Hongqian Mu & Tongbiao Wang & Tianbao Yu & Qinghua Liao, 2022. "Tunable broadband superradiance near a graphene/hyperbolic metamaterial/graphene sandwich structure," The European Physical Journal B: Condensed Matter and Complex Systems, Springer;EDP Sciences, vol. 95(11), pages 1-10, November.
    17. Benyahia, Ahmed & Bouamrane, Rachid, 2023. "Modelling the minimum conductivity of graphene using random resistor networks," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 626(C).
    18. Joel M. Fruhman & Hippolyte P.A.G. Astier & Bruno Ehrler & Marcus L. Böhm & Lissa F. L. Eyre & Piran R. Kidambi & Ugo Sassi & Domenico Fazio & Jonathan P. Griffiths & Alexander J. Robson & Benjamin J., 2021. "High-yield parallel fabrication of quantum-dot monolayer single-electron devices displaying Coulomb staircase, contacted by graphene," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    19. Xuefei Liu & Zhaocai Zhang & Bing Lv & Zhao Ding & Zijiang Luo, 2021. "Impact of the vertical strain on the Schottky barrier height for graphene/AlN heterojunction: a study by the first-principles method," The European Physical Journal B: Condensed Matter and Complex Systems, Springer;EDP Sciences, vol. 94(1), pages 1-7, January.
    20. Kumar, Rajesh & Singh, Rajesh Kumar & Singh, Dinesh Pratap, 2016. "Natural and waste hydrocarbon precursors for the synthesis of carbon based nanomaterials: Graphene and CNTs," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 976-1006.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36714-7. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.