IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-36286-6.html
   My bibliography  Save this article

Universal epitaxy of non-centrosymmetric two-dimensional single-crystal metal dichalcogenides

Author

Listed:
  • Peiming Zheng

    (South China Normal University
    South China Normal University)

  • Wenya Wei

    (South China Normal University
    South China Normal University)

  • Zhihua Liang

    (South China Normal University
    South China Normal University)

  • Biao Qin

    (Peking University)

  • Jinpeng Tian

    (Chinese Academy of Sciences)

  • Jinhuan Wang

    (Peking University)

  • Ruixi Qiao

    (Peking University)

  • Yunlong Ren

    (South China Normal University
    South China Normal University)

  • Junting Chen

    (South China Normal University
    South China Normal University)

  • Chen Huang

    (Peking University)

  • Xu Zhou

    (South China Normal University
    South China Normal University)

  • Guangyu Zhang

    (Chinese Academy of Sciences
    Songshan Lake Materials Laboratory, Institute of Physics, Chinese Academy of Sciences)

  • Zhilie Tang

    (South China Normal University
    South China Normal University)

  • Dapeng Yu

    (Southern University of Science and Technology)

  • Feng Ding

    (Chinese Academy of Sciences)

  • Kaihui Liu

    (Peking University
    Peking University
    Songshan Lake Materials Laboratory, Institute of Physics, Chinese Academy of Sciences)

  • Xiaozhi Xu

    (South China Normal University
    South China Normal University)

Abstract

The great challenge for the growth of non-centrosymmetric 2D single crystals is to break the equivalence of antiparallel grains. Even though this pursuit has been partially achieved in boron nitride and transition metal dichalcogenides (TMDs) growth, the key factors that determine the epitaxy of non-centrosymmetric 2D single crystals are still unclear. Here we report a universal methodology for the epitaxy of non-centrosymmetric 2D metal dichalcogenides enabled by accurate time sequence control of the simultaneous formation of grain nuclei and substrate steps. With this methodology, we have demonstrated the epitaxy of unidirectionally aligned MoS2 grains on a, c, m, n, r and v plane Al2O3 as well as MgO and TiO2 substrates. This approach is also applicable to many TMDs, such as WS2, NbS2, MoSe2, WSe2 and NbSe2. This study reveals a robust mechanism for the growth of various 2D single crystals and thus paves the way for their potential applications.

Suggested Citation

  • Peiming Zheng & Wenya Wei & Zhihua Liang & Biao Qin & Jinpeng Tian & Jinhuan Wang & Ruixi Qiao & Yunlong Ren & Junting Chen & Chen Huang & Xu Zhou & Guangyu Zhang & Zhilie Tang & Dapeng Yu & Feng Ding, 2023. "Universal epitaxy of non-centrosymmetric two-dimensional single-crystal metal dichalcogenides," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36286-6
    DOI: 10.1038/s41467-023-36286-6
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-36286-6
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-36286-6?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Li Wang & Xiaozhi Xu & Leining Zhang & Ruixi Qiao & Muhong Wu & Zhichang Wang & Shuai Zhang & Jing Liang & Zhihong Zhang & Zhibin Zhang & Wang Chen & Xuedong Xie & Junyu Zong & Yuwei Shan & Yi Guo & M, 2019. "Epitaxial growth of a 100-square-centimetre single-crystal hexagonal boron nitride monolayer on copper," Nature, Nature, vol. 570(7759), pages 91-95, June.
    2. Tse-An Chen & Chih-Piao Chuu & Chien-Chih Tseng & Chao-Kai Wen & H.-S. Philip Wong & Shuangyuan Pan & Rongtan Li & Tzu-Ang Chao & Wei-Chen Chueh & Yanfeng Zhang & Qiang Fu & Boris I. Yakobson & Wen-Ha, 2020. "Wafer-scale single-crystal hexagonal boron nitride monolayers on Cu (111)," Nature, Nature, vol. 579(7798), pages 219-223, March.
    3. Ting Cao & Gang Wang & Wenpeng Han & Huiqi Ye & Chuanrui Zhu & Junren Shi & Qian Niu & Pingheng Tan & Enge Wang & Baoli Liu & Ji Feng, 2012. "Valley-selective circular dichroism of monolayer molybdenum disulphide," Nature Communications, Nature, vol. 3(1), pages 1-5, January.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chao Chang & Xiaowen Zhang & Weixuan Li & Quanlin Guo & Zuo Feng & Chen Huang & Yunlong Ren & Yingying Cai & Xu Zhou & Jinhuan Wang & Zhilie Tang & Feng Ding & Wenya Wei & Kaihui Liu & Xiaozhi Xu, 2024. "Remote epitaxy of single-crystal rhombohedral WS2 bilayers," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    2. Lu Li & Qinqin Wang & Fanfan Wu & Qiaoling Xu & Jinpeng Tian & Zhiheng Huang & Qinghe Wang & Xuan Zhao & Qinghua Zhang & Qinkai Fan & Xiuzhen Li & Yalin Peng & Yangkun Zhang & Kunshan Ji & Aomiao Zhi , 2024. "Epitaxy of wafer-scale single-crystal MoS2 monolayer via buffer layer control," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Junzhu Li & Abdus Samad & Yue Yuan & Qingxiao Wang & Mohamed Nejib Hedhili & Mario Lanza & Udo Schwingenschlögl & Iwnetim Abate & Deji Akinwande & Zheng Liu & Bo Tian & Xixiang Zhang, 2024. "Single-crystal hBN Monolayers from Aligned Hexagonal Islands," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    2. Zheyi Lu & Yang Chen & Weiqi Dang & Lingan Kong & Quanyang Tao & Likuan Ma & Donglin Lu & Liting Liu & Wanying Li & Zhiwei Li & Xiao Liu & Yiliu Wang & Xidong Duan & Lei Liao & Yuan Liu, 2023. "Wafer-scale high-κ dielectrics for two-dimensional circuits via van der Waals integration," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    3. Su-Beom Song & Sangho Yoon & So Young Kim & Sera Yang & Seung-Young Seo & Soonyoung Cha & Hyeon-Woo Jeong & Kenji Watanabe & Takashi Taniguchi & Gil-Ho Lee & Jun Sung Kim & Moon-Ho Jo & Jonghwan Kim, 2021. "Deep-ultraviolet electroluminescence and photocurrent generation in graphene/hBN/graphene heterostructures," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    4. Fankai Zeng & Ran Wang & Wenya Wei & Zuo Feng & Quanlin Guo & Yunlong Ren & Guoliang Cui & Dingxin Zou & Zhensheng Zhang & Song Liu & Kehai Liu & Ying Fu & Jinzong Kou & Li Wang & Xu Zhou & Zhilie Tan, 2023. "Stamped production of single-crystal hexagonal boron nitride monolayers on various insulating substrates," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    5. Lu Li & Qinqin Wang & Fanfan Wu & Qiaoling Xu & Jinpeng Tian & Zhiheng Huang & Qinghe Wang & Xuan Zhao & Qinghua Zhang & Qinkai Fan & Xiuzhen Li & Yalin Peng & Yangkun Zhang & Kunshan Ji & Aomiao Zhi , 2024. "Epitaxy of wafer-scale single-crystal MoS2 monolayer via buffer layer control," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    6. Xue-Guang Chen & Linhan Lin & Guan-Yao Huang & Xiao-Mei Chen & Xiao-Ze Li & Yun-Ke Zhou & Yixuan Zou & Tairan Fu & Peng Li & Zhengcao Li & Hong-Bo Sun, 2024. "Optofluidic crystallithography for directed growth of single-crystalline halide perovskites," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    7. Taewoo Ha & Yu-Seong Seo & Teun-Teun Kim & Bipin Lamichhane & Young-Hoon Kim & Su Jae Kim & Yousil Lee & Jong Chan Kim & Sang Eon Park & Kyung Ik Sim & Jae Hoon Kim & Yong In Kim & Seon Je Kim & Hu Yo, 2023. "Coherent consolidation of trillions of nucleations for mono-atom step-level flat surfaces," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    8. Jed Kistner-Morris & Ao Shi & Erfu Liu & Trevor Arp & Farima Farahmand & Takashi Taniguchi & Kenji Watanabe & Vivek Aji & Chun Hung Lui & Nathaniel Gabor, 2024. "Electric-field tunable Type-I to Type-II band alignment transition in MoSe2/WS2 heterobilayers," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    9. Marcin Syperek & Raul Stühler & Armando Consiglio & Paweł Holewa & Paweł Wyborski & Łukasz Dusanowski & Felix Reis & Sven Höfling & Ronny Thomale & Werner Hanke & Ralph Claessen & Domenico Sante & Chr, 2022. "Observation of room temperature excitons in an atomically thin topological insulator," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    10. Lingxin Luo & Lingxiang Hou & Xueping Cui & Pengxin Zhan & Ping He & Chuying Dai & Ruian Li & Jichen Dong & Ye Zou & Guoming Liu & Yanpeng Liu & Jian Zheng, 2024. "Self-condensation-assisted chemical vapour deposition growth of atomically two-dimensional MOF single-crystals," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    11. Jun Zhou & Guitao Zhang & Wenhui Wang & Qian Chen & Weiwei Zhao & Hongwei Liu & Bei Zhao & Zhenhua Ni & Junpeng Lu, 2024. "Phase-engineered synthesis of atomically thin te single crystals with high on-state currents," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    12. Qiyao Zhang & Hao Sun & Jiacheng Tang & Xingcan Dai & Zhen Wang & Cun-Zheng Ning, 2022. "Prolonging valley polarization lifetime through gate-controlled exciton-to-trion conversion in monolayer molybdenum ditelluride," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    13. Ramaraj Sukanya & Tara N. Barwa & Yiran Luo & Eithne Dempsey & Carmel B. Breslin, 2022. "Emerging Layered Materials and Their Applications in the Corrosion Protection of Metals and Alloys," Sustainability, MDPI, vol. 14(7), pages 1-28, March.
    14. Shreetu Shrestha & Mingxing Li & Suji Park & Xiao Tong & Donald DiMarzio & Mircea Cotlet, 2023. "Room temperature valley polarization via spin selective charge transfer," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    15. Yixuan Zhao & Yuqing Song & Zhaoning Hu & Wendong Wang & Zhenghua Chang & Yan Zhang & Qi Lu & Haotian Wu & Junhao Liao & Wentao Zou & Xin Gao & Kaicheng Jia & La Zhuo & Jingyi Hu & Qin Xie & Rui Zhang, 2022. "Large-area transfer of two-dimensional materials free of cracks, contamination and wrinkles via controllable conformal contact," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    16. Jingxian Zhong & Dawei Zhou & Qi Bai & Chao Liu & Xinlian Fan & Hehe Zhang & Congzhou Li & Ran Jiang & Peiyi Zhao & Jiaxiao Yuan & Xiaojiao Li & Guixiang Zhan & Hongyu Yang & Jing Liu & Xuefen Song & , 2024. "Growth of millimeter-sized 2D metal iodide crystals induced by ion-specific preference at water-air interfaces," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    17. A. Aliakbarpour & M. S. Akhoundi Khezrabad & S. Shojaei & S. A. Hashemizadeh-Aghda, 2022. "Optical absorption in lateral transition metal dichalcogenide quantum wells," The European Physical Journal B: Condensed Matter and Complex Systems, Springer;EDP Sciences, vol. 95(10), pages 1-9, October.
    18. Xin Li & Guilin Wu & Leining Zhang & Deping Huang & Yunqing Li & Ruiqi Zhang & Meng Li & Lin Zhu & Jing Guo & Tianlin Huang & Jun Shen & Xingzhan Wei & Ka Man Yu & Jichen Dong & Michael S. Altman & Ro, 2022. "Single-crystal two-dimensional material epitaxy on tailored non-single-crystal substrates," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    19. Yue Yuan & Jonas Weber & Junzhu Li & Bo Tian & Yinchang Ma & Xixiang Zhang & Takashi Taniguchi & Kenji Watanabe & Mario Lanza, 2024. "On the quality of commercial chemical vapour deposited hexagonal boron nitride," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    20. Luying Song & Ying Zhao & Bingqian Xu & Ruofan Du & Hui Li & Wang Feng & Junbo Yang & Xiaohui Li & Zijia Liu & Xia Wen & Yanan Peng & Yuzhu Wang & Hang Sun & Ling Huang & Yulin Jiang & Yao Cai & Xue J, 2024. "Robust multiferroic in interfacial modulation synthesized wafer-scale one-unit-cell of chromium sulfide," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36286-6. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.