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Layered Pd oxide on PdSn nanowires for boosting direct H2O2 synthesis

Author

Listed:
  • Hong-chao Li

    (Xiamen University
    Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM))

  • Qiang Wan

    (Fuzhou University)

  • Congcong Du

    (Xiamen University
    Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM))

  • Jiafei Zhao

    (Xiamen University
    Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM))

  • Fumin Li

    (Xiamen University
    Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM))

  • Ying Zhang

    (Xiamen University
    Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM))

  • Yanping Zheng

    (Xiamen University)

  • Mingshu Chen

    (Xiamen University)

  • Kelvin H. L. Zhang

    (Xiamen University
    Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM))

  • Jianyu Huang

    (Yanshan University)

  • Gang Fu

    (Xiamen University
    Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM))

  • Sen Lin

    (Fuzhou University)

  • Xiaoqing Huang

    (Xiamen University
    Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM))

  • Haifeng Xiong

    (Xiamen University
    Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM))

Abstract

Hydrogen peroxide (H2O2) has the wide range of applications in industry and living life. However, the development of the efficient heterogeneous catalyst in the direct H2O2 synthesis (DHS) from H2 and O2 remains a formidable challenge because of the low H2O2 producibility. Herein, we develop a two-step approach to prepare PdSn nanowire catalysts, which comprises Pd oxide layered on PdSn nanowires (PdL/PdSn-NW). The PdL/PdSn-NW displays superior reactivity in the DHS at zero Celcius, presenting the H2O2 producibility of 528 mol kgcat−1·h−1 and H2O2 selectivity of >95%. A layer of Pd oxide on the PdSn nanowire generates bi-coordinated Pd, leading to the different adsorption behaviors of O2, H2 and H2O2 on the PdL/PdSn-NW. Furthermore, the weak adsorption of H2O2 on the PdL/PdSn-NW contributes to the low activation energy and high H2O2 producibility. This surface engineering approach, depositing metal layer on metal nanowires, provides a new insight in the rational designing of efficient catalyst for DHS.

Suggested Citation

  • Hong-chao Li & Qiang Wan & Congcong Du & Jiafei Zhao & Fumin Li & Ying Zhang & Yanping Zheng & Mingshu Chen & Kelvin H. L. Zhang & Jianyu Huang & Gang Fu & Sen Lin & Xiaoqing Huang & Haifeng Xiong, 2022. "Layered Pd oxide on PdSn nanowires for boosting direct H2O2 synthesis," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33757-0
    DOI: 10.1038/s41467-022-33757-0
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    References listed on IDEAS

    as
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    3. Tao Ling & Dong-Yang Yan & Yan Jiao & Hui Wang & Yao Zheng & Xueli Zheng & Jing Mao & Xi-Wen Du & Zhenpeng Hu & Mietek Jaroniec & Shi-Zhang Qiao, 2016. "Engineering surface atomic structure of single-crystal cobalt (II) oxide nanorods for superior electrocatalysis," Nature Communications, Nature, vol. 7(1), pages 1-8, November.
    4. Qingyao Wu & Jingjing Cao & Xiao Wang & Yan Liu & Yajie Zhao & Hui Wang & Yang Liu & Hui Huang & Fan Liao & Mingwang Shao & Zhenghui Kang, 2021. "Author Correction: A metal-free photocatalyst for highly efficient hydrogen peroxide photoproduction in real seawater," Nature Communications, Nature, vol. 12(1), pages 1-2, December.
    5. Qingyao Wu & Jingjing Cao & Xiao Wang & Yan Liu & Yajie Zhao & Hui Wang & Yang Liu & Hui Huang & Fan Liao & Mingwang Shao & Zhenghui Kang, 2021. "A metal-free photocatalyst for highly efficient hydrogen peroxide photoproduction in real seawater," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
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