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Large-area transfer of two-dimensional materials free of cracks, contamination and wrinkles via controllable conformal contact

Author

Listed:
  • Yixuan Zhao

    (Peking University)

  • Yuqing Song

    (Peking University
    Beijing Graphene Institute)

  • Zhaoning Hu

    (Beijing Graphene Institute)

  • Wendong Wang

    (University of Manchester)

  • Zhenghua Chang

    (LNM, Institute of Mechanics Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Yan Zhang

    (Beijing Graphene Institute)

  • Qi Lu

    (Beijing Graphene Institute
    China University of Petroleum)

  • Haotian Wu

    (Beijing Graphene Institute)

  • Junhao Liao

    (Peking University
    Chinese Academy of Sciences)

  • Wentao Zou

    (Beijing Graphene Institute)

  • Xin Gao

    (Peking University
    Peking University)

  • Kaicheng Jia

    (Peking University)

  • La Zhuo

    (Beijing Graphene Institute)

  • Jingyi Hu

    (Peking University)

  • Qin Xie

    (Peking University)

  • Rui Zhang

    (University of Manchester)

  • Xiaorui Wang

    (Beijing Graphene Institute)

  • Luzhao Sun

    (Beijing Graphene Institute)

  • Fangfang Li

    (Beijing Graphene Institute)

  • Liming Zheng

    (Peking University)

  • Ming Wang

    (Beijing Graphene Institute)

  • Jiawei Yang

    (Beijing Graphene Institute
    Beijing University of Technology)

  • Boyang Mao

    (University of Manchester)

  • Tiantian Fang

    (Chinese Academy of Sciences)

  • Fuyi Wang

    (Chinese Academy of Sciences)

  • Haotian Zhong

    (Beijing Graphene Institute)

  • Wenlin Liu

    (Peking University)

  • Rui Yan

    (Beijing Graphene Institute)

  • Jianbo Yin

    (Beijing Graphene Institute)

  • Yanfeng Zhang

    (Peking University)

  • Yujie Wei

    (LNM, Institute of Mechanics Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Hailin Peng

    (Peking University
    Beijing Graphene Institute
    Peking University)

  • Li Lin

    (Peking University)

  • Zhongfan Liu

    (Peking University
    Beijing Graphene Institute
    Peking University)

Abstract

The availability of graphene and other two-dimensional (2D) materials on a wide range of substrates forms the basis for large-area applications, such as graphene integration with silicon-based technologies, which requires graphene on silicon with outperforming carrier mobilities. However, 2D materials were only produced on limited archetypal substrates by chemical vapor deposition approaches. Reliable after-growth transfer techniques, that do not produce cracks, contamination, and wrinkles, are critical for layering 2D materials onto arbitrary substrates. Here we show that, by incorporating oxhydryl groups-containing volatile molecules, the supporting films can be deformed under heat to achieve a controllable conformal contact, enabling the large-area transfer of 2D films without cracks, contamination, and wrinkles. The resulting conformity with enhanced adhesion facilitates the direct delamination of supporting films from graphene, providing ultraclean surfaces and carrier mobilities up to 1,420,000 cm2 V−1 s−1 at 4 K.

Suggested Citation

  • Yixuan Zhao & Yuqing Song & Zhaoning Hu & Wendong Wang & Zhenghua Chang & Yan Zhang & Qi Lu & Haotian Wu & Junhao Liao & Wentao Zou & Xin Gao & Kaicheng Jia & La Zhuo & Jingyi Hu & Qin Xie & Rui Zhang, 2022. "Large-area transfer of two-dimensional materials free of cracks, contamination and wrinkles via controllable conformal contact," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-31887-z
    DOI: 10.1038/s41467-022-31887-z
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    References listed on IDEAS

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    2. Seung-Il Kim & Ji-Yun Moon & Seok-Ki Hyeong & Soheil Ghods & Jin-Su Kim & Jun-Hui Choi & Dong Seop Park & Sukang Bae & Sung Ho Cho & Seoung-Ki Lee & Jae-Hyun Lee, 2024. "Float-stacked graphene–PMMA laminate," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    3. Guowen Yuan & Weilin Liu & Xianlei Huang & Zihao Wan & Chao Wang & Bing Yao & Wenjie Sun & Hang Zheng & Kehan Yang & Zhenjia Zhou & Yuefeng Nie & Jie Xu & Libo Gao, 2023. "Stacking transfer of wafer-scale graphene-based van der Waals superlattices," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

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