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Niobium-doped layered cathode material for high-power and low-temperature sodium-ion batteries

Author

Listed:
  • Qinhao Shi

    (Shanghai University)

  • Ruijuan Qi

    (East China Normal University)

  • Xiaochen Feng

    (Shanghai University)

  • Jing Wang

    (Yanshan University)

  • Yong Li

    (Shanghai University)

  • Zhenpeng Yao

    (Shanghai Jiao Tong University)

  • Xuan Wang

    (Shanghai University)

  • Qianqian Li

    (Shanghai University)

  • Xionggang Lu

    (Shanghai University)

  • Jiujun Zhang

    (Shanghai University
    Fuzhou University)

  • Yufeng Zhao

    (Shanghai University)

Abstract

The application of sodium-based batteries in grid-scale energy storage requires electrode materials that facilitate fast and stable charge storage at various temperatures. However, this goal is not entirely achievable in the case of P2-type layered transition-metal oxides because of the sluggish kinetics and unfavorable electrode|electrolyte interphase formation. To circumvent these issues, we propose a P2-type Na0.78Ni0.31Mn0.67Nb0.02O2 (P2-NaMNNb) cathode active material where the niobium doping enables reduction in the electronic band gap and ionic diffusion energy barrier while favoring the Na-ion mobility. Via physicochemical characterizations and theoretical calculations, we demonstrate that the niobium induces atomic scale surface reorganization, hindering metal dissolution from the cathode into the electrolyte. We also report the testing of the cathode material in coin cell configuration using Na metal or hard carbon as anode active materials and ether-based electrolyte solutions. Interestingly, the Na||P2-NaMNNb cell can be cycled up to 9.2 A g−1 (50 C), showing a discharge capacity of approximately 65 mAh g−1 at 25 °C. Furthermore, the Na||P2-NaMNNb cell can also be charged/discharged for 1800 cycles at 368 mA g−1 and −40 °C, demonstrating a capacity retention of approximately 76% and a final discharge capacity of approximately 70 mAh g−1.

Suggested Citation

  • Qinhao Shi & Ruijuan Qi & Xiaochen Feng & Jing Wang & Yong Li & Zhenpeng Yao & Xuan Wang & Qianqian Li & Xionggang Lu & Jiujun Zhang & Yufeng Zhao, 2022. "Niobium-doped layered cathode material for high-power and low-temperature sodium-ion batteries," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-30942-z
    DOI: 10.1038/s41467-022-30942-z
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    References listed on IDEAS

    as
    1. Yuesheng Wang & Ruijuan Xiao & Yong-Sheng Hu & Maxim Avdeev & Liquan Chen, 2015. "P2-Na0.6[Cr0.6Ti0.4]O2 cation-disordered electrode for high-rate symmetric rechargeable sodium-ion batteries," Nature Communications, Nature, vol. 6(1), pages 1-9, November.
    2. Lianfeng Zou & Yang He & Zhenyu Liu & Haiping Jia & Jian Zhu & Jianming Zheng & Guofeng Wang & Xiaolin Li & Jie Xiao & Jun Liu & Ji-Guang Zhang & Guoying Chen & Chongmin Wang, 2020. "Unlocking the passivation nature of the cathode–air interfacial reactions in lithium ion batteries," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    3. Jang-Yeon Hwang & Seung-Min Oh & Seung-Taek Myung & Kyung Yoon Chung & Ilias Belharouak & Yang-Kook Sun, 2015. "Radially aligned hierarchical columnar structure as a cathode material for high energy density sodium-ion batteries," Nature Communications, Nature, vol. 6(1), pages 1-9, November.
    4. Shaohua Guo & Qi Li & Pan Liu & Mingwei Chen & Haoshen Zhou, 2017. "Environmentally stable interface of layered oxide cathodes for sodium-ion batteries," Nature Communications, Nature, vol. 8(1), pages 1-9, December.
    5. Chenchen Wang & Luojia Liu & Shuo Zhao & Yanchen Liu & Yubo Yang & Haijun Yu & Suwon Lee & Gi-Hyeok Lee & Yong-Mook Kang & Rong Liu & Fujun Li & Jun Chen, 2021. "Tuning local chemistry of P2 layered-oxide cathode for high energy and long cycles of sodium-ion battery," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
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    Cited by:

    1. Gupta, Yamini & Siwatch, Poonam & Karwasra, Reetika & Sharma, Kriti & Tripathi, S.K., 2024. "Recent progress of layered structured P2- and O3- type transition metal oxides as cathode material for sodium-ion batteries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 192(C).
    2. Mengyao Tang & Shuai Dong & Jiawei Wang & Liwei Cheng & Qiaonan Zhu & Yanmei Li & Xiuyi Yang & Lin Guo & Hua Wang, 2023. "Low-temperature anode-free potassium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.

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