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Room-temperature optically detected magnetic resonance of single defects in hexagonal boron nitride

Author

Listed:
  • Hannah L. Stern

    (University of Cambridge)

  • Qiushi Gu

    (University of Cambridge)

  • John Jarman

    (University of Cambridge)

  • Simone Eizagirre Barker

    (University of Cambridge)

  • Noah Mendelson

    (University of Technology Sydney)

  • Dipankar Chugh

    (The Australian National University)

  • Sam Schott

    (University of Cambridge)

  • Hoe H. Tan

    (The Australian National University)

  • Henning Sirringhaus

    (University of Cambridge)

  • Igor Aharonovich

    (University of Technology Sydney)

  • Mete Atatüre

    (University of Cambridge)

Abstract

Optically addressable solid-state spins are important platforms for quantum technologies, such as repeaters and sensors. Spins in two-dimensional materials offer an advantage, as the reduced dimensionality enables feasible on-chip integration into devices. Here, we report room-temperature optically detected magnetic resonance (ODMR) from single carbon-related defects in hexagonal boron nitride with up to 100 times stronger contrast than the ensemble average. We identify two distinct bunching timescales in the second-order intensity-correlation measurements for ODMR-active defects, but only one for those without an ODMR response. We also observe either positive or negative ODMR signal for each defect. Based on kinematic models, we relate this bipolarity to highly tuneable internal optical rates. Finally, we resolve an ODMR fine structure in the form of an angle-dependent doublet resonance, indicative of weak but finite zero-field splitting. Our results offer a promising route towards realising a room-temperature spin-photon quantum interface in hexagonal boron nitride.

Suggested Citation

  • Hannah L. Stern & Qiushi Gu & John Jarman & Simone Eizagirre Barker & Noah Mendelson & Dipankar Chugh & Sam Schott & Hoe H. Tan & Henning Sirringhaus & Igor Aharonovich & Mete Atatüre, 2022. "Room-temperature optically detected magnetic resonance of single defects in hexagonal boron nitride," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-28169-z
    DOI: 10.1038/s41467-022-28169-z
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    References listed on IDEAS

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    1. Hosung Seo & Abram L. Falk & Paul V. Klimov & Kevin C. Miao & Giulia Galli & David D. Awschalom, 2016. "Quantum decoherence dynamics of divacancy spins in silicon carbide," Nature Communications, Nature, vol. 7(1), pages 1-9, December.
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    Cited by:

    1. John C. Thomas & Wei Chen & Yihuang Xiong & Bradford A. Barker & Junze Zhou & Weiru Chen & Antonio Rossi & Nolan Kelly & Zhuohang Yu & Da Zhou & Shalini Kumari & Edward S. Barnard & Joshua A. Robinson, 2024. "A substitutional quantum defect in WS2 discovered by high-throughput computational screening and fabricated by site-selective STM manipulation," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. T. Thu Ha Do & Milad Nonahal & Chi Li & Vytautas Valuckas & Hark Hoe Tan & Arseniy I. Kuznetsov & Hai Son Nguyen & Igor Aharonovich & Son Tung Ha, 2024. "Room-temperature strong coupling in a single-photon emitter-metasurface system," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    3. Xingyu Gao & Sumukh Vaidya & Saakshi Dikshit & Peng Ju & Kunhong Shen & Yuanbin Jin & Shixiong Zhang & Tongcang Li, 2024. "Nanotube spin defects for omnidirectional magnetic field sensing," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    4. Ruotian Gong & Xinyi Du & Eli Janzen & Vincent Liu & Zhongyuan Liu & Guanghui He & Bingtian Ye & Tongcang Li & Norman Y. Yao & James H. Edgar & Erik A. Henriksen & Chong Zu, 2024. "Isotope engineering for spin defects in van der Waals materials," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    5. Nai-Jie Guo & Song Li & Wei Liu & Yuan-Ze Yang & Xiao-Dong Zeng & Shang Yu & Yu Meng & Zhi-Peng Li & Zhao-An Wang & Lin-Ke Xie & Rong-Chun Ge & Jun-Feng Wang & Qiang Li & Jin-Shi Xu & Yi-Tao Wang & Ji, 2023. "Coherent control of an ultrabright single spin in hexagonal boron nitride at room temperature," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    6. Pasquale Cilibrizzi & Muhammad Junaid Arshad & Benedikt Tissot & Nguyen Tien Son & Ivan G. Ivanov & Thomas Astner & Philipp Koller & Misagh Ghezellou & Jawad Ul-Hassan & Daniel White & Christiaan Bekk, 2023. "Ultra-narrow inhomogeneous spectral distribution of telecom-wavelength vanadium centres in isotopically-enriched silicon carbide," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    7. Luca Sortino & Angus Gale & Lucca Kühner & Chi Li & Jonas Biechteler & Fedja J. Wendisch & Mehran Kianinia & Haoran Ren & Milos Toth & Stefan A. Maier & Igor Aharonovich & Andreas Tittl, 2024. "Optically addressable spin defects coupled to bound states in the continuum metasurfaces," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    8. Yeonghun Lee & Yaoqiao Hu & Xiuyao Lang & Dongwook Kim & Kejun Li & Yuan Ping & Kai-Mei C. Fu & Kyeongjae Cho, 2022. "Spin-defect qubits in two-dimensional transition metal dichalcogenides operating at telecom wavelengths," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    9. Ruotian Gong & Guanghui He & Xingyu Gao & Peng Ju & Zhongyuan Liu & Bingtian Ye & Erik A. Henriksen & Tongcang Li & Chong Zu, 2023. "Coherent dynamics of strongly interacting electronic spin defects in hexagonal boron nitride," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

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