IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v12y2021i1d10.1038_s41467-021-26528-w.html
   My bibliography  Save this article

A reasonable approach for the generation of hollow icosahedral kernels in metal nanoclusters

Author

Listed:
  • Xi Kang

    (Anhui University
    Anhui University)

  • Xiao Wei

    (Anhui University
    Anhui University)

  • Xiaokang Liu

    (University of Science and Technology of China)

  • Sicong Wang

    (University of Science and Technology of China)

  • Tao Yao

    (University of Science and Technology of China)

  • Shuxin Wang

    (Anhui University
    Anhui University)

  • Manzhou Zhu

    (Anhui University
    Anhui University)

Abstract

Although the hollow icosahedral M12 kernel has been extensively observed in metal nanoclusters, its origin remains a mystery. Here we report a reasonable avenue for the generation of the hollow icosahedron: the kernel collapse from several small nano-building blocks to an integrated hollow icosahedron. On the basis of the Au alloying processes from Ag28Cu12(SR)24 to the template-maintained AuxAg28-xCu12(SR)24 and then to the template-transformed Au12CuyAg32-y(SR)30, the kernel evolution/collapse from “tetrahedral Ag4 + 4∗Ag3” to “tetrahedral Au4 + 4∗M3 (M = Au/Ag)” and then to “hollow icosahedral Au12” is mapped out. Significantly, the “kernel collapse” from small-sized nano-building blocks to large-sized nanostructures not only unveils the formation of hollow icosahedral M12 in this work, but also might be a very common approach in constructing metallic kernels of nanoclusters and nanoparticles (not limited to the M12 structure).

Suggested Citation

  • Xi Kang & Xiao Wei & Xiaokang Liu & Sicong Wang & Tao Yao & Shuxin Wang & Manzhou Zhu, 2021. "A reasonable approach for the generation of hollow icosahedral kernels in metal nanoclusters," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
  • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-26528-w
    DOI: 10.1038/s41467-021-26528-w
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-021-26528-w
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-021-26528-w?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Zhi Wang & Hai-Feng Su & Yi-Wen Gong & Qing-Ping Qu & Yan-Feng Bi & Chen-Ho Tung & Di Sun & Lan-Sun Zheng, 2020. "A hierarchically assembled 88-nuclei silver-thiacalix[4]arene nanocluster," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    2. Juanzhu Yan & Sami Malola & Chengyi Hu & Jian Peng & Birger Dittrich & Boon K. Teo & Hannu Häkkinen & Lansun Zheng & Nanfeng Zheng, 2018. "Co-crystallization of atomically precise metal nanoparticles driven by magic atomic and electronic shells," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    3. Anil Desireddy & Brian E. Conn & Jingshu Guo & Bokwon Yoon & Robert N. Barnett & Bradley M. Monahan & Kristin Kirschbaum & Wendell P. Griffith & Robert L. Whetten & Uzi Landman & Terry P. Bigioni, 2013. "Ultrastable silver nanoparticles," Nature, Nature, vol. 501(7467), pages 399-402, September.
    4. Huayan Yang & Yu Wang & Huaqi Huang & Lars Gell & Lauri Lehtovaara & Sami Malola & Hannu Häkkinen & Nanfeng Zheng, 2013. "All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures," Nature Communications, Nature, vol. 4(1), pages 1-8, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Hao Li & Tian Wang & Jiaojiao Han & Ying Xu & Xi Kang & Xiaosong Li & Manzhou Zhu, 2024. "Fluorescence resonance energy transfer in atomically precise metal nanoclusters by cocrystallization-induced spatial confinement," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    2. Belessiotis, George V. & Kontos, Athanassios G., 2022. "Plasmonic silver (Ag)-based photocatalysts for H2 production and CO2 conversion: Review, analysis and perspectives," Renewable Energy, Elsevier, vol. 195(C), pages 497-515.
    3. Ji Soo Kim & Hogeun Chang & Sungsu Kang & Seungwoo Cha & Hanguk Cho & Seung Jae Kwak & Namjun Park & Younhwa Kim & Dohun Kang & Chyan Kyung Song & Jimin Kwag & Ji-Sook Hahn & Won Bo Lee & Taeghwan Hye, 2023. "Critical roles of metal–ligand complexes in the controlled synthesis of various metal nanoclusters," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    4. Xi-Ming Luo & Chun-Hua Gong & Fangfang Pan & Yubing Si & Jia-Wang Yuan & Muhammad Asad & Xi-Yan Dong & Shuang-Quan Zang & Thomas C. W. Mak, 2022. "Small symmetry-breaking triggering large chiroptical responses of Ag70 nanoclusters," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    5. Yuan Zhong & Jiangwei Zhang & Tingting Li & Wenwu Xu & Qiaofeng Yao & Min Lu & Xue Bai & Zhennan Wu & Jianping Xie & Yu Zhang, 2023. "Suppression of kernel vibrations by layer-by-layer ligand engineering boosts photoluminescence efficiency of gold nanoclusters," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    6. Claudia Pigliacelli & Angela Acocella & Isabel Díez & Luca Moretti & Valentina Dichiarante & Nicola Demitri & Hua Jiang & Margherita Maiuri & Robin H. A. Ras & Francesca Baldelli Bombelli & Giulio Cer, 2022. "High-resolution crystal structure of a 20 kDa superfluorinated gold nanocluster," Nature Communications, Nature, vol. 13(1), pages 1-8, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-26528-w. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.