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A reasonable approach for the generation of hollow icosahedral kernels in metal nanoclusters

Author

Listed:
  • Xi Kang

    (Anhui University
    Anhui University)

  • Xiao Wei

    (Anhui University
    Anhui University)

  • Xiaokang Liu

    (University of Science and Technology of China)

  • Sicong Wang

    (University of Science and Technology of China)

  • Tao Yao

    (University of Science and Technology of China)

  • Shuxin Wang

    (Anhui University
    Anhui University)

  • Manzhou Zhu

    (Anhui University
    Anhui University)

Abstract

Although the hollow icosahedral M12 kernel has been extensively observed in metal nanoclusters, its origin remains a mystery. Here we report a reasonable avenue for the generation of the hollow icosahedron: the kernel collapse from several small nano-building blocks to an integrated hollow icosahedron. On the basis of the Au alloying processes from Ag28Cu12(SR)24 to the template-maintained AuxAg28-xCu12(SR)24 and then to the template-transformed Au12CuyAg32-y(SR)30, the kernel evolution/collapse from “tetrahedral Ag4 + 4∗Ag3” to “tetrahedral Au4 + 4∗M3 (M = Au/Ag)” and then to “hollow icosahedral Au12” is mapped out. Significantly, the “kernel collapse” from small-sized nano-building blocks to large-sized nanostructures not only unveils the formation of hollow icosahedral M12 in this work, but also might be a very common approach in constructing metallic kernels of nanoclusters and nanoparticles (not limited to the M12 structure).

Suggested Citation

  • Xi Kang & Xiao Wei & Xiaokang Liu & Sicong Wang & Tao Yao & Shuxin Wang & Manzhou Zhu, 2021. "A reasonable approach for the generation of hollow icosahedral kernels in metal nanoclusters," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
    • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-26528-w
    DOI: 10.1038/s41467-021-26528-w
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    References listed on IDEAS

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    1. Huayan Yang & Yu Wang & Huaqi Huang & Lars Gell & Lauri Lehtovaara & Sami Malola & Hannu Häkkinen & Nanfeng Zheng, 2013. "All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures," Nature Communications, Nature, vol. 4(1), pages 1-8, December.
    2. Zhi Wang & Hai-Feng Su & Yi-Wen Gong & Qing-Ping Qu & Yan-Feng Bi & Chen-Ho Tung & Di Sun & Lan-Sun Zheng, 2020. "A hierarchically assembled 88-nuclei silver-thiacalix[4]arene nanocluster," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    3. Juanzhu Yan & Sami Malola & Chengyi Hu & Jian Peng & Birger Dittrich & Boon K. Teo & Hannu Häkkinen & Lansun Zheng & Nanfeng Zheng, 2018. "Co-crystallization of atomically precise metal nanoparticles driven by magic atomic and electronic shells," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    4. Anil Desireddy & Brian E. Conn & Jingshu Guo & Bokwon Yoon & Robert N. Barnett & Bradley M. Monahan & Kristin Kirschbaum & Wendell P. Griffith & Robert L. Whetten & Uzi Landman & Terry P. Bigioni, 2013. "Ultrastable silver nanoparticles," Nature, Nature, vol. 501(7467), pages 399-402, September.
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