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A hierarchically assembled 88-nuclei silver-thiacalix[4]arene nanocluster

Author

Listed:
  • Zhi Wang

    (State Key Laboratory of Crystal Materials, Shandong University)

  • Hai-Feng Su

    (Xiamen University)

  • Yi-Wen Gong

    (State Key Laboratory of Crystal Materials, Shandong University)

  • Qing-Ping Qu

    (State Key Laboratory of Crystal Materials, Shandong University)

  • Yan-Feng Bi

    (Liaoning Shihua University)

  • Chen-Ho Tung

    (State Key Laboratory of Crystal Materials, Shandong University)

  • Di Sun

    (State Key Laboratory of Crystal Materials, Shandong University)

  • Lan-Sun Zheng

    (Xiamen University)

Abstract

Thiacalix[4]arenes as a family of promising ligands have been widely used to construct polynuclear metal clusters, but scarcely employed in silver nanoclusters. Herein, an anion-templated Ag88 nanocluster (SD/Ag88a) built from p-tert-butylthiacalix[4]arene (H4TC4A) is reported. Single-crystal X-ray diffraction reveals that C4-symmetric SD/Ag88a resembles a metal-organic super calix comprised of eight TC4A4− as walls and 88 silver atoms as base, which can be deconstructed to eight [CrO4@Ag11(TC4A)(EtS)4(OAc)] secondary building units arranged in an annulus encircling a CrO42− in the center. Local and global anion template effects from chromates are individually manifested in SD/Ag88a. The solution stability and hierarchical assembly mechanism of SD/Ag88a are studied by using electrospray mass spectrometry. The Ag88 nanocluster represents the highest nuclearity metal cluster capped by TC4A4−. This work not only exemplify the specific macrocyclic effects of TC4A4− in the construction of silver nanocluster but also realize the shape heredity of TC4A4− to overall silver super calix.

Suggested Citation

  • Zhi Wang & Hai-Feng Su & Yi-Wen Gong & Qing-Ping Qu & Yan-Feng Bi & Chen-Ho Tung & Di Sun & Lan-Sun Zheng, 2020. "A hierarchically assembled 88-nuclei silver-thiacalix[4]arene nanocluster," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:11:y:2020:i:1:d:10.1038_s41467-019-13682-5
    DOI: 10.1038/s41467-019-13682-5
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    Cited by:

    1. Zhan-Hua Zhao & Bao-Liang Han & Hai-Feng Su & Qi-Lin Guo & Wen-Xin Wang & Jing-Qiu Zhuo & Yong-Nan Guo & Jia-Long Liu & Geng-Geng Luo & Ping Cui & Di Sun, 2024. "Buckling cluster-based H-bonded icosahedral capsules and their propagation to a robust zeolite-like supramolecular framework," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    2. Xue-Jing Zhai & Meng-Yu Luo & Xi-Ming Luo & Xi-Yan Dong & Yubing Si & Chong Zhang & Zhen Han & Runping Han & Shuang-Quan Zang & Thomas C. W. Mak, 2024. "Hierarchical assembly of Ag40 nanowheel ranging from building blocks to diverse superstructure regulation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Xi Kang & Xiao Wei & Xiaokang Liu & Sicong Wang & Tao Yao & Shuxin Wang & Manzhou Zhu, 2021. "A reasonable approach for the generation of hollow icosahedral kernels in metal nanoclusters," Nature Communications, Nature, vol. 12(1), pages 1-7, December.

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