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Improving the Degradation Kinetics of Industrial Dyes with Chitosan/TiO 2 /Glycerol Films for the Sustainable Recovery of Chitosan from Waste Streams

Author

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  • Nhung T. Tuyet Hoang

    (Faculty of Chemical and Food Technology, Ho Chi Minh City University of Technology and Education, 01 Vo Van Ngan Street, Thu Duc City, Ho Chi Minh City 700000, Vietnam)

  • D. Duc Nguyen

    (Department of Environmental Energy Engineering, Kyonggi University, Suwon 16227, Republic of Korea
    Faculty of Environmental and Food Engineering, Nguyen Tat Thanh University, 300A Nguyen Tat Thanh, District 4, Ho Chi Minh City 755414, Vietnam)

Abstract

This study investigates the potential of a combined photocatalysis–adsorption approach to effectively degrade near wash yellow (NWY), a commonly used and highly persistent dye in the textile industry, notorious for its challenging treatment and removal from wastewater due to its colorfastness. A chitosan–glycerol (CTiG) film combined with titanium dioxide was examined in both batch and continuous-flow experiments under visible solar irradiation. The results show that this combination was more effective than a pure chitosan film (60%) or chitosan–glycerol film (63%), with up to 83% degradation of NWY achieved in just 60 min of visible solar irradiation. The kinetics of the film were evaluated using both pseudo-first-order and Langmuir–Hinshelwood kinetic models. The rate constant values (k, min −1 ) decreased with increasing NWY concentration from 20 to 80 mg/L, and k was found to be greater than twice as high under visible solar irradiation as it was in the dark. The Langmuir–Hinshelwood model’s K LH (reaction rate constant) and K L (adsorption coefficient) values were 0.029 mg/L·min and 0.019 L/mg, respectively. The optimal conditions for NWY degradation were found to be 4% TiO 2 to chitosan ratio, glycerol/chitosan ratio of 40%, and a pH of 7. In the continuous-flow model, the CTiG film was submerged in an 8 L NWY solution (80 mg/L) and degraded at a rate of 22.6 mg NWY/g film under natural sunlight. This study contributes to the development of effective and sustainable methods for the degradation of dyes from textile industry wastewater.

Suggested Citation

  • Nhung T. Tuyet Hoang & D. Duc Nguyen, 2023. "Improving the Degradation Kinetics of Industrial Dyes with Chitosan/TiO 2 /Glycerol Films for the Sustainable Recovery of Chitosan from Waste Streams," Sustainability, MDPI, vol. 15(8), pages 1-16, April.
    • Handle: RePEc:gam:jsusta:v:15:y:2023:i:8:p:6979-:d:1129059
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    References listed on IDEAS

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