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Effect of Chemical Pre-Treatment on the Catalytic Performance of Oil Palm EFB Fibre Supported Magnetic Acid Catalyst

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  • Shamala Gowri Krishnan

    (College of Graduate Studies, Universiti Tenaga Nasional, Kajang 43000, Selangor, Malaysia)

  • Fei Ling Pua

    (Institute of Sustainable Energy (ISE), Universiti Tenaga Nasional, Kajang 43000, Selangor, Malaysia
    Department of Mechanical Engineering, College of Engineering, Universiti Tenaga Nasional, Kajang 43000, Selangor, Malaysia)

  • Zhang Fan

    (Biomass Group, Key Laboratory of Tropical Plant Resources and Sustainable Use, Xishuangbanna Tropical Botanical Garden, Chinese Academy of Sciences, 88 Xuefulu, Kunming 650223, China)

Abstract

The development of heterogenous catalysts using renewable materials has received wide attention. A heterogenous catalyst has been a preferred choice as it evades the disadvantages of homogeneous catalysts, nevertheless, heterogenous catalysts has limited activity and a longer separation process. The current study emphasises the preparation of a new magnetic catalyst using oil palm empty fruit bunch (EFB) fibre as a carbon-based support material. The effect of different alkaline pre-treatments over the methyl ester conversion rate were investigated. The catalyst preparation parameters were studied by using the single factor optimisation approach, including the fibre loading, impregnation time, calcination temperature, and calcination time. Their effects in the esterification of oleic acid were investigated in this study. The optimisation study shows that the Na 2 CO 3 -treated(T)-EFBC magnetic catalyst had the highest esterification rate of 93.5% with 7 g EFB fibre loading, a 2 h impregnation time and a calcination temperature of 500 °C for 2 h. The catalyst possessed a good acidity of 3.5 mmol/g with excellent magnetism properties. This study showed that the catalysts are magnetically separable and exhibited good stability with 82.1% after five cycles. The oil palm EFB supported magnetic acid catalyst indicates it as a potential option to the existing solid catalysts that is economical and environmentally friendly for the esterification process.

Suggested Citation

  • Shamala Gowri Krishnan & Fei Ling Pua & Zhang Fan, 2023. "Effect of Chemical Pre-Treatment on the Catalytic Performance of Oil Palm EFB Fibre Supported Magnetic Acid Catalyst," Sustainability, MDPI, vol. 15(11), pages 1-14, May.
    • Handle: RePEc:gam:jsusta:v:15:y:2023:i:11:p:8637-:d:1156400
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    References listed on IDEAS

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    1. Rath, Badri Narayan & Akram, Vaseem & Bal, Debi Prasad & Mahalik, Mantu Kumar, 2019. "Do fossil fuel and renewable energy consumption affect total factor productivity growth? Evidence from cross-country data with policy insights," Energy Policy, Elsevier, vol. 127(C), pages 186-199.
    2. Bureros, Glorie Mae A. & Tanjay, April A. & Cuizon, Dan Elmer S. & Go, Alchris W. & Cabatingan, Luis K. & Agapay, Ramelito C. & Ju, Yi-Hsu, 2019. "Cacao shell-derived solid acid catalyst for esterification of oleic acid with methanol," Renewable Energy, Elsevier, vol. 138(C), pages 489-501.
    3. Guo, Feng & Xiu, Zhi-Long & Liang, Zhi-Xia, 2012. "Synthesis of biodiesel from acidified soybean soapstock using a lignin-derived carbonaceous catalyst," Applied Energy, Elsevier, vol. 98(C), pages 47-52.
    4. Wang, Yi-Tong & Yang, Xing-Xia & Xu, Jie & Wang, Hong-Li & Wang, Zi-Bing & Zhang, Lei & Wang, Shao-Long & Liang, Jing-Long, 2019. "Biodiesel production from esterification of oleic acid by a sulfonated magnetic solid acid catalyst," Renewable Energy, Elsevier, vol. 139(C), pages 688-695.
    5. Rozzeta Dolah & Rohit Karnik & Halimaton Hamdan, 2021. "A Comprehensive Review on Biofuels from Oil Palm Empty Bunch (EFB): Current Status, Potential, Barriers and Way Forward," Sustainability, MDPI, vol. 13(18), pages 1-29, September.
    6. Liu, Kang & Wang, Rui & Yu, Meiqing, 2018. "An efficient, recoverable solid base catalyst of magnetic bamboo charcoal: Preparation, characterization, and performance in biodiesel production," Renewable Energy, Elsevier, vol. 127(C), pages 531-538.
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