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Torrefaction as a Pretreatment Technology for Chlorine Elimination from Biomass: A Case Study Using Eucalyptus globulus Labill

Author

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  • Letícia C. R. Sá

    (YGE—Yser Green Energy SA, Área de Acolhimento Empresarial de Úl/Loureiro, Lote 17, 3720-075 Loureiro OAZ, Portugal)

  • Liliana M. E. F. Loureiro

    (YGE—Yser Green Energy SA, Área de Acolhimento Empresarial de Úl/Loureiro, Lote 17, 3720-075 Loureiro OAZ, Portugal)

  • Leonel J. R. Nunes

    (proMetheus—Unidade de Investigação em Materiais, Energia e Ambiente para a Sustentabilidade, Escola Superior Agrária, Instituto Politécnico de Viana do Castelo, Rua da Escola Industrial e Comercial de Nun’Alvares, 4900-347 Viana do Castelo, Portugal
    GOVCOPP—Unidade de Investigação em Governança, Competitividade e Políticas Públicas, DEGEIT—Departamento de Economia, Gestão, Engenharia Industrial e Turismo, Universidade de Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro, Portugal)

  • Adélio M. M. Mendes

    (LEPAE—Laboratório de Engenharia de Processos, Ambiente e Energia, FEUP—Faculdade de Engenharia da Universidade do Porto, Rua Roberto Frias, 4200-465 Porto, Portugal)

Abstract

The recognition of the effects of fossil fuel consumption resulted in several agreements, legislation, and projects focusing on the minimization of impacts caused. Biomass is a versatile energy source. Eucalyptus is a fast-growing crop, mainly used by the pulp and paper industry. Torrefaction is a thermochemical conversion process that can improve biomass fuel properties, enabling its use in the energy sector. However, correct management of biomass is crucial for the sustainability of this process. Torrefaction can also be used to eliminate some elements that can hinder subsequent conversion processes. One example is chlorine, which, during combustion or gasification processes, can form hydrochloric acid that leads to corrosion of metal surfaces. In this context, this research aimed to determine the temperature at which chlorine is eliminated during torrefaction process. For this purpose, several tests were performed at different temperatures and residence times. All samples were analyzed before and after the process, and were characterized by proximate and elemental analysis, calorimetry, and chlorine titration. The analysis showed that, even for the lowest torrefaction temperature used, chlorine content was already below the detection value, showing that, even at lower temperatures, thermal treatment is an efficient technique for the elimination of chlorine from biomass.

Suggested Citation

  • Letícia C. R. Sá & Liliana M. E. F. Loureiro & Leonel J. R. Nunes & Adélio M. M. Mendes, 2020. "Torrefaction as a Pretreatment Technology for Chlorine Elimination from Biomass: A Case Study Using Eucalyptus globulus Labill," Resources, MDPI, vol. 9(5), pages 1-25, May.
    • Handle: RePEc:gam:jresou:v:9:y:2020:i:5:p:54-:d:352819
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    References listed on IDEAS

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    1. Kwietniewska, Ewa & Tys, Jerzy, 2014. "Process characteristics, inhibition factors and methane yields of anaerobic digestion process, with particular focus on microalgal biomass fermentation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 34(C), pages 491-500.
    2. Saidur, R. & Abdelaziz, E.A. & Demirbas, A. & Hossain, M.S. & Mekhilef, S., 2011. "A review on biomass as a fuel for boilers," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(5), pages 2262-2289, June.
    3. Niu, Yanqing & Lv, Yuan & Lei, Yu & Liu, Siqi & Liang, Yang & Wang, Denghui & Hui, Shi'en, 2019. "Biomass torrefaction: properties, applications, challenges, and economy," Renewable and Sustainable Energy Reviews, Elsevier, vol. 115(C).
    4. Viana, H. & Cohen, Warren B. & Lopes, D. & Aranha, J., 2010. "Assessment of forest biomass for use as energy. GIS-based analysis of geographical availability and locations of wood-fired power plants in Portugal," Applied Energy, Elsevier, vol. 87(8), pages 2551-2560, August.
    5. Vélez, Fredy & Segovia, José J. & Martín, M. Carmen & Antolín, Gregorio & Chejne, Farid & Quijano, Ana, 2012. "A technical, economical and market review of organic Rankine cycles for the conversion of low-grade heat for power generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 4175-4189.
    6. Demirbas, Ayhan, 2011. "Competitive liquid biofuels from biomass," Applied Energy, Elsevier, vol. 88(1), pages 17-28, January.
    7. Mohammad I. Jahirul & Mohammad G. Rasul & Ashfaque Ahmed Chowdhury & Nanjappa Ashwath, 2012. "Biofuels Production through Biomass Pyrolysis —A Technological Review," Energies, MDPI, vol. 5(12), pages 1-50, November.
    8. Andre Faaij, 2006. "Modern Biomass Conversion Technologies," Mitigation and Adaptation Strategies for Global Change, Springer, vol. 11(2), pages 335-367, March.
    9. Proskurina, Svetlana & Heinimö, Jussi & Schipfer, Fabian & Vakkilainen, Esa, 2017. "Biomass for industrial applications: The role of torrefaction," Renewable Energy, Elsevier, vol. 111(C), pages 265-274.
    10. Omer, Abdeen Mustafa, 2008. "Energy, environment and sustainable development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(9), pages 2265-2300, December.
    11. Li, Jun & Brzdekiewicz, Artur & Yang, Weihong & Blasiak, Wlodzimierz, 2012. "Co-firing based on biomass torrefaction in a pulverized coal boiler with aim of 100% fuel switching," Applied Energy, Elsevier, vol. 99(C), pages 344-354.
    12. Toklu, E., 2017. "Biomass energy potential and utilization in Turkey," Renewable Energy, Elsevier, vol. 107(C), pages 235-244.
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