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A Mini-Review on Recent Developments and Improvements in CO 2 Catalytic Conversion to Methanol: Prospects for the Cement Plant Industry

Author

Listed:
  • Luísa Marques

    (c5Lab—Sustainable Construction Materials Association, 2795-242 Linda-a-Velha, Portugal)

  • Maria Vieira

    (c5Lab—Sustainable Construction Materials Association, 2795-242 Linda-a-Velha, Portugal)

  • José Condeço

    (c5Lab—Sustainable Construction Materials Association, 2795-242 Linda-a-Velha, Portugal
    CERENA, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais 1, 1049-001 Lisboa, Portugal)

  • Carlos Henriques

    (Centro de Química Estrutural (CQE), Institute of Molecular Sciences, Departamento de Engenharia Química, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal)

  • Maria Mateus

    (c5Lab—Sustainable Construction Materials Association, 2795-242 Linda-a-Velha, Portugal
    CERENA, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais 1, 1049-001 Lisboa, Portugal)

Abstract

The cement industry significantly impacts the environment due to natural resource extraction and fossil fuel combustion, with carbon dioxide (CO 2 ) emissions being a major concern. The industry emits 0.6 tons of CO 2 per ton of cement, accounting for about 8% of global CO 2 emissions. To meet the 13th United Nations Sustainable Development Goal, cement plants aim for carbon neutrality by 2050 through reducing CO 2 emissions and adopting Carbon Capture and Utilization (CCU) technologies. A promising approach is converting CO 2 into valuable chemicals and fuels, such as methanol (MeOH), using Power-to-Liquid (PtL) technologies. This process involves capturing CO 2 from cement plant flue gas and using hydrogen from renewable sources to produce renewable methanol (e-MeOH). Advancing the development of novel, efficient catalysts for direct CO 2 hydrogenation is crucial. This comprehensive mini-review presents a holistic view of recent advancements in CO 2 catalytic conversion to MeOH, focusing on catalyst performance, selectivity, and stability. It outlines a long-term strategy for utilizing captured CO 2 emissions from cement plants to produce MeOH, offering an experimental roadmap for the decarbonization of the cement industry.

Suggested Citation

  • Luísa Marques & Maria Vieira & José Condeço & Carlos Henriques & Maria Mateus, 2024. "A Mini-Review on Recent Developments and Improvements in CO 2 Catalytic Conversion to Methanol: Prospects for the Cement Plant Industry," Energies, MDPI, vol. 17(21), pages 1-23, October.
    • Handle: RePEc:gam:jeners:v:17:y:2024:i:21:p:5285-:d:1505491
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    References listed on IDEAS

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    1. Mohammad Zahirul Khaiyum & Sudipa Sarker & Golam Kabir, 2023. "Evaluation of Carbon Emission Factors in the Cement Industry: An Emerging Economy Context," Sustainability, MDPI, vol. 15(21), pages 1-15, October.
    2. Sonia Dell’Aversano & Carlo Villante & Katia Gallucci & Giuseppina Vanga & Andrea Di Giuliano, 2024. "E-Fuels: A Comprehensive Review of the Most Promising Technological Alternatives towards an Energy Transition," Energies, MDPI, vol. 17(16), pages 1-43, August.
    3. Lee, Boreum & Lee, Hyunjun & Lim, Dongjun & Brigljević, Boris & Cho, Wonchul & Cho, Hyun-Seok & Kim, Chang-Hee & Lim, Hankwon, 2020. "Renewable methanol synthesis from renewable H2 and captured CO2: How can power-to-liquid technology be economically feasible?," Applied Energy, Elsevier, vol. 279(C).
    4. Uliasz-Bocheńczyk, Alicja & Deja, Jan, 2024. "Potential application of cement kiln dust in carbon capture, utilisation, and storage technology," Energy, Elsevier, vol. 292(C).
    5. Gale, John, 2004. "Geological storage of CO2: What do we know, where are the gaps and what more needs to be done?," Energy, Elsevier, vol. 29(9), pages 1329-1338.
    6. Wen-Hsien Tsai & Wei-Hong Lin, 2024. "Production Decision Model for the Cement Industry in Pursuit of Carbon Neutrality: Analysis of the Impact of Carbon Tax and Carbon Credit Costs," Sustainability, MDPI, vol. 16(6), pages 1-22, March.
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