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Determination of Sodium Ion Diffusion Coefficient in Tin Sulfide@Carbon Anode Material Using GITT and EIS Techniques

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  • Andrzej P. Nowak

    (Faculty of Chemistry, Gdańsk University of Technology, Narutowicza 11/12, 80-233 Gdańsk, Poland
    Advanced Materials Center, Gdańsk University of Technology, Narutowicza 11/12, 80-233 Gdańsk, Poland)

  • Paweł Rutecki

    (Faculty of Chemistry, Gdańsk University of Technology, Narutowicza 11/12, 80-233 Gdańsk, Poland)

  • Mariusz Szkoda

    (Faculty of Chemistry, Gdańsk University of Technology, Narutowicza 11/12, 80-233 Gdańsk, Poland
    Advanced Materials Center, Gdańsk University of Technology, Narutowicza 11/12, 80-233 Gdańsk, Poland)

  • Konrad Trzciński

    (Faculty of Chemistry, Gdańsk University of Technology, Narutowicza 11/12, 80-233 Gdańsk, Poland
    Advanced Materials Center, Gdańsk University of Technology, Narutowicza 11/12, 80-233 Gdańsk, Poland)

Abstract

The electroanalytical behavior of SnS x (x = 1, 2) encapsulated into a carbon phase was studied using the galvanostatic intermittent titration technique (GITT) and electrochemical impedance spectroscopy (EIS). These techniques are widely utilized in battery systems to investigate the diffusion of alkali metal cations in anode and cathode materials depending on the concentration of ions in the host material. Here, we report different calculation methods showing how the applied model affects the derived diffusion coefficient. The calculated value of the apparent chemical diffusion coefficient of sodium ions ( D N a + ) is in the range of 1 × 10 −10 to 1 × 10 −15 cm 2 /s depending on the technique, mathematical protocol, geometry of the electrode material, and applied potential.

Suggested Citation

  • Andrzej P. Nowak & Paweł Rutecki & Mariusz Szkoda & Konrad Trzciński, 2024. "Determination of Sodium Ion Diffusion Coefficient in Tin Sulfide@Carbon Anode Material Using GITT and EIS Techniques," Energies, MDPI, vol. 17(13), pages 1-11, July.
  • Handle: RePEc:gam:jeners:v:17:y:2024:i:13:p:3233-:d:1426837
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    References listed on IDEAS

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