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Hydrogen-Free Deoxygenation of Oleic Acid and Industrial Vegetable Oil Waste on CuNiAl Catalysts for Biofuel Production

Author

Listed:
  • Jose Sabino

    (Laboratory of Refining and Cleaner Technology (LabRefino/Lateclim), Institute for Petroleum and Energy Research (LITPEG), Department of Chemical Engineering, Center of Technology and Geosciences, Federal University of Pernambuco, Recife 50740-540, PE, Brazil)

  • Denisson O. Liborio

    (Laboratory of Refining and Cleaner Technology (LabRefino/Lateclim), Institute for Petroleum and Energy Research (LITPEG), Department of Chemical Engineering, Center of Technology and Geosciences, Federal University of Pernambuco, Recife 50740-540, PE, Brazil)

  • Santiago Arias

    (Laboratory of Refining and Cleaner Technology (LabRefino/Lateclim), Institute for Petroleum and Energy Research (LITPEG), Department of Chemical Engineering, Center of Technology and Geosciences, Federal University of Pernambuco, Recife 50740-540, PE, Brazil)

  • Juan F. Gonzalez

    (Laboratory of Refining and Cleaner Technology (LabRefino/Lateclim), Institute for Petroleum and Energy Research (LITPEG), Department of Chemical Engineering, Center of Technology and Geosciences, Federal University of Pernambuco, Recife 50740-540, PE, Brazil)

  • Celmy M. B. M. Barbosa

    (Laboratory of Refining and Cleaner Technology (LabRefino/Lateclim), Institute for Petroleum and Energy Research (LITPEG), Department of Chemical Engineering, Center of Technology and Geosciences, Federal University of Pernambuco, Recife 50740-540, PE, Brazil)

  • Florival R. Carvalho

    (Fuel Laboratory, Institute for Petroleum and Energy Research (LITPEG), Department of Chemical Engineering, Center of Technology and Geosciences, Federal University of Pernambuco, Recife 50740-540, PE, Brazil)

  • Roger Frety

    (Laboratory of Refining and Cleaner Technology (LabRefino/Lateclim), Institute for Petroleum and Energy Research (LITPEG), Department of Chemical Engineering, Center of Technology and Geosciences, Federal University of Pernambuco, Recife 50740-540, PE, Brazil)

  • Ivoneide C. L. Barros

    (Department of Chemistry, Federal Rural University of Pernambuco, Recife 52171-900, PE, Brazil)

  • Jose Geraldo A. Pacheco

    (Laboratory of Refining and Cleaner Technology (LabRefino/Lateclim), Institute for Petroleum and Energy Research (LITPEG), Department of Chemical Engineering, Center of Technology and Geosciences, Federal University of Pernambuco, Recife 50740-540, PE, Brazil)

Abstract

The pyrolysis of vegetable oil waste is an alternative way to convert biomass into high-quality second-generation biofuels, with social, economic and environmental sustainability. The present work deals with the pyrolysis of oleic acid as a model compound and an industrial vegetable oil residue on CuNiAl mixed oxide catalysts, derived from layered double hydroxides. Reactions of the oils pre-adsorbed on the catalysts (catalyst:oil mass ratio of 5:1) were performed at 550 °C on a micro-pyrolysis system and the analyses of volatile products were carried out online using GC/MS. Copper addition to NiAl catalysts increased the cracking of oleic acid. Increasing copper content also decreased the formation of aromatics and coke precursors, as well as oxygenated compounds. The CuNiAl catalyst with a Cu/Ni ratio of 0.4 showed strong catalytic activity in the conversion of an industrial vegetable oil residue with a high volume of free fatty acids produced. Compared to the non-catalytic reaction, the catalyst reduced the content of oxygenates and increased the content of hydrocarbons, particularly in the gasoline range (C5–C9). The CuNiAl oxide catalyst was able to convert vegetable oil residues into hydrocarbons in the range of gasoline, kerosene and diesel, and also linear alkylbenzenes as chemical precursors for surfactant production.

Suggested Citation

  • Jose Sabino & Denisson O. Liborio & Santiago Arias & Juan F. Gonzalez & Celmy M. B. M. Barbosa & Florival R. Carvalho & Roger Frety & Ivoneide C. L. Barros & Jose Geraldo A. Pacheco, 2023. "Hydrogen-Free Deoxygenation of Oleic Acid and Industrial Vegetable Oil Waste on CuNiAl Catalysts for Biofuel Production," Energies, MDPI, vol. 16(17), pages 1-20, August.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:17:p:6131-:d:1223136
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    References listed on IDEAS

    as
    1. Krystyna Kurowska & Renata Marks-Bielska & Stanisław Bielski & Hubert Kryszk & Algirdas Jasinskas, 2020. "Food Security in the Context of Liquid Biofuels Production," Energies, MDPI, vol. 13(23), pages 1-16, November.
    2. Stefania Lucantonio & Andrea Di Giuliano & Leucio Rossi & Katia Gallucci, 2023. "Green Diesel Production via Deoxygenation Process: A Review," Energies, MDPI, vol. 16(2), pages 1-44, January.
    3. Anzhelika M. Eremeeva & Natalia K. Kondrasheva & Artyom F. Khasanov & Ivan L. Oleynik, 2023. "Environmentally Friendly Diesel Fuel Obtained from Vegetable Raw Materials and Hydrocarbon Crude," Energies, MDPI, vol. 16(5), pages 1-12, February.
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