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Polymeric Membranes for H 2 S and CO 2 Removal from Natural Gas for Hydrogen Production: A Review

Author

Listed:
  • Shraavya Rao

    (William G. Lowrie Department of Chemical and Biomolecular Engineering, The Ohio State University, 151 West Woodruff Avenue, Columbus, OH 43210-1350, USA)

  • Babul Prasad

    (William G. Lowrie Department of Chemical and Biomolecular Engineering, The Ohio State University, 151 West Woodruff Avenue, Columbus, OH 43210-1350, USA)

  • Yang Han

    (William G. Lowrie Department of Chemical and Biomolecular Engineering, The Ohio State University, 151 West Woodruff Avenue, Columbus, OH 43210-1350, USA)

  • W.S. Winston Ho

    (William G. Lowrie Department of Chemical and Biomolecular Engineering, The Ohio State University, 151 West Woodruff Avenue, Columbus, OH 43210-1350, USA
    Department of Materials Science and Engineering, The Ohio State University, 2041 College Road, Columbus, OH 43210-1178, USA)

Abstract

Natural gas, an important source of hydrogen, is expected to be crucial in the transition to a hydrogen-based economy. The landscape of the gas processing industry is set to change in the near future with the development of highly acidic sour gas wells. Natural gas purification constitutes a major share of the gas separation membrane market, and the shift to low-quality sour gas wells has been mirrored in the trends of membrane material research. Purification also constitutes the major portion of the cost of natural gas, posing implications for the cost of hydrogen production. This review provides an update on the current state of research regarding polymeric membranes for H 2 S removal, along with CO 2 separation, from natural gas that is used for hydrogen production via steam methane reforming. The challenges of adapting polymeric membranes to ternary H 2 S/CO 2 /CH 4 separations are discussed in detail. Key polymeric materials are highlighted, and the prospects for their application in H 2 S removal from natural gas are evaluated. Finally, the growing interest in H 2 production from H 2 S is discussed. Advances in the membrane industry and the emergence of new membrane materials may significantly improve the commercial viability of such processes.

Suggested Citation

  • Shraavya Rao & Babul Prasad & Yang Han & W.S. Winston Ho, 2023. "Polymeric Membranes for H 2 S and CO 2 Removal from Natural Gas for Hydrogen Production: A Review," Energies, MDPI, vol. 16(15), pages 1-37, July.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:15:p:5713-:d:1207136
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    References listed on IDEAS

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    4. Hunt, Julian David & Nascimento, Andreas & Nascimento, Nazem & Vieira, Lara Werncke & Romero, Oldrich Joel, 2022. "Possible pathways for oil and gas companies in a sustainable future: From the perspective of a hydrogen economy," Renewable and Sustainable Energy Reviews, Elsevier, vol. 160(C).
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    Cited by:

    1. Lou, Minghe & Wang, Ruoyu & Song, Haitao, 2024. "Advances and challenges toward efficient utilization of H2S for H2 production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 199(C).

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