IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v16y2023i14p5479-d1197472.html
   My bibliography  Save this article

Utilization of MnFe 2 O 4 Redox Ferrite for Solar Fuel Production via CO 2 Splitting: A Thermodynamic Study

Author

Listed:
  • Rahul R. Bhosale

    (Department of Civil and Chemical Engineering, University of Tennessee at Chattanooga, 615 Mccallie Ave., Chattanooga, TN 37403, USA)

  • Sayma Akhter

    (Department of Chemical Engineering, College of Engineering, Qatar University, Doha P.O. Box 2713, Qatar)

  • Ram B. Gupta

    (Department of Chemical and Life Science Engineering, Virginia Commonwealth University, Richmond, VA 23284, USA)

  • Rajesh V. Shende

    (Department of Chemical and Biological Engineering, South Dakota School of Mines and Technology, Rapid City, SD 57701, USA)

Abstract

A thermodynamic efficiency analysis of M n F e 2 O 4 -based CO 2 splitting (CDS) cycle is reported. HSC Chemistry software is used for performing the calculations allied with the model developed. By maintaining the reduction nonstoichiometry equal to 0.1, variations in the thermal energy required to drive the cycle and solar-to-fuel energy conversion efficiency as a function of the ratio of the molar flow rate of inert sweep gas to the molar flow rate of Mn-ferrite, reduction temperature, and gas-to-gas heat recovery effectiveness are studied. This study confirms that the thermal reduction temperature needed to achieve reduction nonstoichiometry equal to 0.1 is reduced when the inert gas flow rate is increased. Conversely, due to the requirement of the additional energy to heat the inert gas, the thermal energy required to drive the cycle is upsurged considerably. As the solar-to-fuel energy conversion efficiency depends significantly on the thermal energy required to drive the cycle, a reduction in it is recorded. As the ratio of the molar flow rate of inert sweep gas to the molar flow rate of Mn-ferrite is increased from 10 to 100, the solar-to-fuel energy conversion efficiency is decreased from 14.9% to 9.9%. By incorporating gas-to-gas heat recovery, a drastic drop in the thermal energy required to drive the cycle is attained which further resulted in a rise in the solar-to-fuel energy conversion efficiency. The maximum solar-to-fuel energy conversion efficiency (17.5%) is achieved at the ratio of the molar flow rate of inert sweep gas to the molar flow rate of Mn-ferrite equal to 10 as well as 20 when 90% of gas-to-gas heat recovery is applied.

Suggested Citation

  • Rahul R. Bhosale & Sayma Akhter & Ram B. Gupta & Rajesh V. Shende, 2023. "Utilization of MnFe 2 O 4 Redox Ferrite for Solar Fuel Production via CO 2 Splitting: A Thermodynamic Study," Energies, MDPI, vol. 16(14), pages 1-17, July.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:14:p:5479-:d:1197472
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/16/14/5479/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/16/14/5479/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Koepf, E. & Villasmil, W. & Meier, A., 2016. "Pilot-scale solar reactor operation and characterization for fuel production via the Zn/ZnO thermochemical cycle," Applied Energy, Elsevier, vol. 165(C), pages 1004-1023.
    2. Tamaura, Y. & Hasegawa, N. & Kojima, M. & Ueda, Y. & Amano, H. & Tsuji, M., 1998. "Water splitting with the Mn(II)-ferrite–CaO–H2O system at 1273K," Energy, Elsevier, vol. 23(10), pages 879-886.
    3. Kaneko, Hiroshi & Gokon, Nobuyuki & Hasegawa, Noriko & Tamaura, Yutaka, 2005. "Solar thermochemical process for hydrogen production using ferrites," Energy, Elsevier, vol. 30(11), pages 2171-2178.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mao, Yanpeng & Gao, Yibo & Dong, Wei & Wu, Han & Song, Zhanlong & Zhao, Xiqiang & Sun, Jing & Wang, Wenlong, 2020. "Hydrogen production via a two-step water splitting thermochemical cycle based on metal oxide – A review," Applied Energy, Elsevier, vol. 267(C).
    2. Yadav, Deepak & Banerjee, Rangan, 2018. "A comparative life cycle energy and carbon emission analysis of the solar carbothermal and hydrometallurgy routes for zinc production," Applied Energy, Elsevier, vol. 229(C), pages 577-602.
    3. Charvin, Patrice & Abanades, Stéphane & Flamant, Gilles & Lemort, Florent, 2007. "Two-step water splitting thermochemical cycle based on iron oxide redox pair for solar hydrogen production," Energy, Elsevier, vol. 32(7), pages 1124-1133.
    4. Hyun-Seok Cho & Tatsuya Kodama & Nobuyuki Gokon & Selvan Bellan & Jong-Kyu Kim, 2021. "Development of Synthesis and Fabrication Process for Mn-CeO 2 Foam via Two-Step Water-Splitting Cycle Hydrogen Production," Energies, MDPI, vol. 14(21), pages 1-14, October.
    5. Jamey Davies & Stephanus P. Du Preez & Dmitri G. Bessarabov, 2022. "The Hydrolysis of Ball-Milled Aluminum–Bismuth–Nickel Composites for On-Demand Hydrogen Generation," Energies, MDPI, vol. 15(7), pages 1-22, March.
    6. Rahul R. Bhosale & Shelby Adams & Zachary Allen & Gabrielle Bennett & Edvinas Berezniovas & Taylor Bishop & Michael Bonnema & Sequoia Clutter & Ryan Fagan & Jordan Halabrin & Mason Hobbs & Daniel Hunt, 2024. "Assessing the Viability of GeO 2 /GeO Redox Thermochemical Cycle for Converting CO 2 into Solar Fuels," Sustainability, MDPI, vol. 16(6), pages 1-20, March.
    7. Liu, Xiufeng & Hong, Hui & Jin, Hongguang, 2017. "Mid-temperature solar fuel process combining dual thermochemical reactions for effectively utilizing wider solar irradiance," Applied Energy, Elsevier, vol. 185(P2), pages 1031-1039.
    8. Mohsen Fallah Vostakola & Babak Salamatinia & Bahman Amini Horri, 2022. "A Review on Recent Progress in the Integrated Green Hydrogen Production Processes," Energies, MDPI, vol. 15(3), pages 1-41, February.
    9. Gabriel Zsembinszki & Aran Solé & Camila Barreneche & Cristina Prieto & A. Inés Fernández & Luisa F. Cabeza, 2018. "Review of Reactors with Potential Use in Thermochemical Energy Storage in Concentrated Solar Power Plants," Energies, MDPI, vol. 11(9), pages 1-23, September.
    10. Liu, Taixiu & Bai, Zhang & Zheng, Zhimei & Liu, Qibin & Lei, Jing & Sui, Jun & Jin, Hongguang, 2019. "100 kWe power generation pilot plant with a solar thermochemical process: design, modeling, construction, and testing," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    11. Alvarez Rivero, M. & Rodrigues, D. & Pinheiro, C.I.C. & Cardoso, J.P. & Mendes, L.F., 2022. "Solid–gas reactors driven by concentrated solar energy with potential application to calcium looping: A comparative review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 158(C).
    12. Rahul R. Bhosale, 2020. "Terbium oxide‐based solar thermochemical CO2 splitting cycle: A thermodynamic investigation," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 10(4), pages 703-714, August.
    13. Feng Wang & Delun Guan & Yatian Li & Jingxuan Zhong, 2022. "Research Progress on Magnetic Catalysts and Its Application in Hydrogen Production Area," Energies, MDPI, vol. 15(15), pages 1-22, July.
    14. Guo, Yongpeng & Chen, Jing & Song, Hualong & Zheng, Ke & Wang, Jian & Wang, Hongsheng & Kong, Hui, 2024. "A review of solar thermochemical cycles for fuel production," Applied Energy, Elsevier, vol. 357(C).
    15. Stéphane Abanades, 2022. "Redox Cycles, Active Materials, and Reactors Applied to Water and Carbon Dioxide Splitting for Solar Thermochemical Fuel Production: A Review," Energies, MDPI, vol. 15(19), pages 1-28, September.
    16. Liu, Taixiu & Liu, Qibin & Lei, Jing & Sui, Jun & Jin, Hongguang, 2018. "Solar-clean fuel distributed energy system with solar thermochemistry and chemical recuperation," Applied Energy, Elsevier, vol. 225(C), pages 380-391.
    17. Koepf, E. & Alxneit, I. & Wieckert, C. & Meier, A., 2017. "A review of high temperature solar driven reactor technology: 25years of experience in research and development at the Paul Scherrer Institute," Applied Energy, Elsevier, vol. 188(C), pages 620-651.
    18. Nicodemus, Julia Haltiwanger, 2018. "Technological learning and the future of solar H2: A component learning comparison of solar thermochemical cycles and electrolysis with solar PV," Energy Policy, Elsevier, vol. 120(C), pages 100-109.
    19. Lidor, A. & Fend, T. & Roeb, M. & Sattler, C., 2021. "High performance solar receiver–reactor for hydrogen generation," Renewable Energy, Elsevier, vol. 179(C), pages 1217-1232.
    20. Gao, Yibo & Mao, Yanpeng & Song, Zhanlong & Zhao, Xiqiang & Sun, Jing & Wang, Wenlong & Chen, Guifang & Chen, Shouyan, 2020. "Efficient generation of hydrogen by two-step thermochemical cycles: Successive thermal reduction and water splitting reactions using equal-power microwave irradiation and a high entropy material," Applied Energy, Elsevier, vol. 279(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:16:y:2023:i:14:p:5479-:d:1197472. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.