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Effective Inhibition of Carbon Steel Corrosion by Waterborne Polyurethane Based on N- tert -Butyl Diethanolamine in 2M HCl: Experimental and Computational Findings

Author

Listed:
  • Yulia F. Zaripova

    (Department of Petroleum Engineering, Kazan Federal University, Kremlevskaya Str. 18, 420008 Kazan, Russia)

  • Sherzod Razhabov

    (Department of Electrochemical Engineering, Kazan National Research Technological University, Karl Marx Str. 68, 420015 Kazan, Russia)

  • Roman S. Pavelyev

    (Department of Petroleum Engineering, Kazan Federal University, Kremlevskaya Str. 18, 420008 Kazan, Russia)

  • Svetlana S. Vinogradova

    (Department of Electrochemical Engineering, Kazan National Research Technological University, Karl Marx Str. 68, 420015 Kazan, Russia)

  • Renat R. Nazmutdinov

    (Department of Electrochemical Engineering, Kazan National Research Technological University, Karl Marx Str. 68, 420015 Kazan, Russia)

  • Iskander R. Vakhitov

    (Department of Physics, Kazan Federal University, Kremlevskaya Str. 18, 420008 Kazan, Russia)

  • Mikhail A. Varfolomeev

    (Department of Petroleum Engineering, Kazan Federal University, Kremlevskaya Str. 18, 420008 Kazan, Russia)

Abstract

The efficiency of corrosion inhibition for waterborne polyurethane based on N- tert -butyl diethanolamine ( tB-WPU ) is investigated using different techniques. Corrosion weight loss, open circuit potential experiments, electrochemical impedance spectroscopy, and potentiodynamic polarization measurements show that both a commercial reagent and a polyurethane-based inhibitor prevent corrosion at increasing temperature to 50 °C. At 75 °C, the activity of both reagents is reduced. In stirring conditions, the effectiveness of acid corrosion inhibition (25 °C, 500 ppm) drops abruptly from 89.5% to 60.7%, which is related presumably to the complexity of binding the polymer molecules to the metal surface. As follows from thermodynamic calculations, the adsorption of tB-WPU on the metal surface in 2M HCl can be treated as a physisorption. Model quantum–chemical calculations support the experimental studies and elucidate the nature of steel surface–inhibitor molecule chemical bond, which is realized mainly by carboxyl and amino groups. It is concluded that WPUs can be considered as a perspective alternative to commercial oilfield reagents due to their versatility.

Suggested Citation

  • Yulia F. Zaripova & Sherzod Razhabov & Roman S. Pavelyev & Svetlana S. Vinogradova & Renat R. Nazmutdinov & Iskander R. Vakhitov & Mikhail A. Varfolomeev, 2022. "Effective Inhibition of Carbon Steel Corrosion by Waterborne Polyurethane Based on N- tert -Butyl Diethanolamine in 2M HCl: Experimental and Computational Findings," Energies, MDPI, vol. 15(5), pages 1-21, March.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:5:p:1939-:d:765883
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    References listed on IDEAS

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    1. Seong-Pil Kang & Dongwon Lee & Jong-Won Lee, 2020. "Anti-Agglomeration Effects of Biodegradable Surfactants from Natural Sources on Natural Gas Hydrate Formation," Energies, MDPI, vol. 13(5), pages 1-11, March.
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    3. Mazlin Idress & Muhammad Afiq Shahril & Ahmad Syahir Zuraidin & Mazuin Jasamai, 2019. "Experimental Investigation of Methane Hydrate Induction Time in the Presence of Cassava Peel as a Hydrate Inhibitor," Energies, MDPI, vol. 12(12), pages 1-11, June.
    4. E. Dendy Sloan, 2003. "Fundamental principles and applications of natural gas hydrates," Nature, Nature, vol. 426(6964), pages 353-359, November.
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