IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v15y2022i5p1939-d765883.html
   My bibliography  Save this article

Effective Inhibition of Carbon Steel Corrosion by Waterborne Polyurethane Based on N- tert -Butyl Diethanolamine in 2M HCl: Experimental and Computational Findings

Author

Listed:
  • Yulia F. Zaripova

    (Department of Petroleum Engineering, Kazan Federal University, Kremlevskaya Str. 18, 420008 Kazan, Russia)

  • Sherzod Razhabov

    (Department of Electrochemical Engineering, Kazan National Research Technological University, Karl Marx Str. 68, 420015 Kazan, Russia)

  • Roman S. Pavelyev

    (Department of Petroleum Engineering, Kazan Federal University, Kremlevskaya Str. 18, 420008 Kazan, Russia)

  • Svetlana S. Vinogradova

    (Department of Electrochemical Engineering, Kazan National Research Technological University, Karl Marx Str. 68, 420015 Kazan, Russia)

  • Renat R. Nazmutdinov

    (Department of Electrochemical Engineering, Kazan National Research Technological University, Karl Marx Str. 68, 420015 Kazan, Russia)

  • Iskander R. Vakhitov

    (Department of Physics, Kazan Federal University, Kremlevskaya Str. 18, 420008 Kazan, Russia)

  • Mikhail A. Varfolomeev

    (Department of Petroleum Engineering, Kazan Federal University, Kremlevskaya Str. 18, 420008 Kazan, Russia)

Abstract

The efficiency of corrosion inhibition for waterborne polyurethane based on N- tert -butyl diethanolamine ( tB-WPU ) is investigated using different techniques. Corrosion weight loss, open circuit potential experiments, electrochemical impedance spectroscopy, and potentiodynamic polarization measurements show that both a commercial reagent and a polyurethane-based inhibitor prevent corrosion at increasing temperature to 50 °C. At 75 °C, the activity of both reagents is reduced. In stirring conditions, the effectiveness of acid corrosion inhibition (25 °C, 500 ppm) drops abruptly from 89.5% to 60.7%, which is related presumably to the complexity of binding the polymer molecules to the metal surface. As follows from thermodynamic calculations, the adsorption of tB-WPU on the metal surface in 2M HCl can be treated as a physisorption. Model quantum–chemical calculations support the experimental studies and elucidate the nature of steel surface–inhibitor molecule chemical bond, which is realized mainly by carboxyl and amino groups. It is concluded that WPUs can be considered as a perspective alternative to commercial oilfield reagents due to their versatility.

Suggested Citation

  • Yulia F. Zaripova & Sherzod Razhabov & Roman S. Pavelyev & Svetlana S. Vinogradova & Renat R. Nazmutdinov & Iskander R. Vakhitov & Mikhail A. Varfolomeev, 2022. "Effective Inhibition of Carbon Steel Corrosion by Waterborne Polyurethane Based on N- tert -Butyl Diethanolamine in 2M HCl: Experimental and Computational Findings," Energies, MDPI, vol. 15(5), pages 1-21, March.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:5:p:1939-:d:765883
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/15/5/1939/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/15/5/1939/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Seong-Pil Kang & Dongwon Lee & Jong-Won Lee, 2020. "Anti-Agglomeration Effects of Biodegradable Surfactants from Natural Sources on Natural Gas Hydrate Formation," Energies, MDPI, vol. 13(5), pages 1-11, March.
    2. Faraz Rajput & Milan Maric & Phillip Servio, 2021. "Amphiphilic Block Copolymers with Vinyl Caprolactam as Kinetic Gas Hydrate Inhibitors," Energies, MDPI, vol. 14(2), pages 1-13, January.
    3. E. Dendy Sloan, 2003. "Fundamental principles and applications of natural gas hydrates," Nature, Nature, vol. 426(6964), pages 353-359, November.
    4. Mazlin Idress & Muhammad Afiq Shahril & Ahmad Syahir Zuraidin & Mazuin Jasamai, 2019. "Experimental Investigation of Methane Hydrate Induction Time in the Presence of Cassava Peel as a Hydrate Inhibitor," Energies, MDPI, vol. 12(12), pages 1-11, June.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yue Zhang & Zhi Li & Xiaodeng Yang & Tianduo Li, 2022. "Synthesis of Chitosan Derivatives and Their Inhibition Effects on Methane Hydrates," Energies, MDPI, vol. 15(7), pages 1-14, April.
    2. Yiwei Wang & Lin Wang & Zhen Hu & Youli Li & Qiang Sun & Aixian Liu & Lanying Yang & Jing Gong & Xuqiang Guo, 2021. "The Thermodynamic and Kinetic Effects of Sodium Lignin Sulfonate on Ethylene Hydrate Formation," Energies, MDPI, vol. 14(11), pages 1-19, June.
    3. Lei, Gang & Tang, Jiadi & Zhang, Ling & Wu, Qi & Li, Jun, 2024. "Effective thermal conductivity for hydrate-bearing sediments under stress and local thermal stimulation conditions: A novel analytical model," Energy, Elsevier, vol. 288(C).
    4. Chen, Siyuan & Wang, Yanhong & Lang, Xuemei & Fan, Shuanshi & Li, Gang, 2023. "Rapid and high hydrogen storage in epoxycyclopentane hydrate at moderate pressure," Energy, Elsevier, vol. 268(C).
    5. Chen, Chang & Zhang, Yu & Li, Xiaosen & Gao, Fei & Chen, Yuru & Chen, Zhaoyang, 2024. "Experimental investigation into gas production from methane hydrate in sediments with different contents of illite clay by depressurization," Energy, Elsevier, vol. 296(C).
    6. Maria Filomena Loreto & Umberta Tinivella & Flavio Accaino & Michela Giustiniani, 2010. "Offshore Antarctic Peninsula Gas Hydrate Reservoir Characterization by Geophysical Data Analysis," Energies, MDPI, vol. 4(1), pages 1-18, December.
    7. Yang, Ming & Wang, Yuze & Wu, Hui & Zhang, Pengwei & Ju, Xin, 2024. "Thermo-hydro-chemical modeling and analysis of methane extraction from fractured gas hydrate-bearing sediments," Energy, Elsevier, vol. 292(C).
    8. Xu, Chun-Gang & Cai, Jing & Yu, Yi-Song & Yan, Ke-Feng & Li, Xiao-Sen, 2018. "Effect of pressure on methane recovery from natural gas hydrates by methane-carbon dioxide replacement," Applied Energy, Elsevier, vol. 217(C), pages 527-536.
    9. Guan, Dawei & Qu, Aoxing & Gao, Peng & Fan, Qi & Li, Qingping & Zhang, Lunxiang & Zhao, Jiafei & Song, Yongchen & Yang, Lei, 2023. "Improved temperature distribution upon varying gas producing channel in gas hydrate reservoir: Insights from the Joule-Thomson effect," Applied Energy, Elsevier, vol. 348(C).
    10. Liao, Bo & Wang, Jintang & Li, Mei-Chun & Lv, Kaihe & Wang, Qi & Li, Jian & Huang, Xianbing & Wang, Ren & Lv, Xindi & Chen, Zhangxin & Sun, Jinsheng, 2023. "Microscopic molecular and experimental insights into multi-stage inhibition mechanisms of alkylated hydrate inhibitor," Energy, Elsevier, vol. 279(C).
    11. Choi, Wonjung & Lee, Yohan & Mok, Junghoon & Seo, Yongwon, 2020. "Influence of feed gas composition on structural transformation and guest exchange behaviors in sH hydrate – Flue gas replacement for energy recovery and CO2 sequestration," Energy, Elsevier, vol. 207(C).
    12. Luís Bernardes & Júlio Carneiro & Pedro Madureira & Filipe Brandão & Cristina Roque, 2015. "Determination of Priority Study Areas for Coupling CO2 Storage and CH 4 Gas Hydrates Recovery in the Portuguese Offshore Area," Energies, MDPI, vol. 8(9), pages 1-17, September.
    13. You, Zeshao & Li, Yanghui & Yang, Meixiao & Wu, Peng & Liu, Tao & Li, Jiayu & Hu, Wenkang & Song, Yongchen, 2024. "Investigation of particle-scale mechanical behavior of hydrate-bearing sands using DEM: Focus on hydrate habits," Energy, Elsevier, vol. 289(C).
    14. Nicola Varini & Niall J. English & Christian R. Trott, 2012. "Molecular Dynamics Simulations of Clathrate Hydrates on Specialised Hardware Platforms," Energies, MDPI, vol. 5(9), pages 1-8, September.
    15. Cheng, Fanbao & Sun, Xiang & Li, Yanghui & Ju, Xin & Yang, Yaobin & Liu, Xuanji & Liu, Weiguo & Yang, Mingjun & Song, Yongchen, 2023. "Numerical analysis of coupled thermal-hydro-chemo-mechanical (THCM) behavior to joint production of marine gas hydrate and shallow gas," Energy, Elsevier, vol. 281(C).
    16. Lee, Joonseop & Lee, Dongyoung & Seo, Yongwon, 2021. "Experimental investigation of the exact role of large-molecule guest substances (LMGSs) in determining phase equilibria and structures of natural gas hydrates," Energy, Elsevier, vol. 215(PB).
    17. Zhang, Xuemin & Zhang, Shanling & Liu, Qingqing & Huang, Tingting & Yang, Huijie & Li, Jinping & Wang, Yingmei & Wu, Qingbai & Chen, Chen, 2024. "Experimental study of gas recovery behaviors from methane hydrate-bearing sediments by CO2 replacement below freezing point," Energy, Elsevier, vol. 288(C).
    18. Zhong, Jin-Rong & Sun, Yi-Fei & Li, Wen-Zhi & Xie, Yan & Chen, Guang-Jin & Sun, Chang-Yu & Yang, Lan-Ying & Qin, Hui-Bo & Pang, Wei-Xin & Li, Qing-Ping, 2019. "Structural transition range of methane-ethane gas hydrates during decomposition below ice point," Applied Energy, Elsevier, vol. 250(C), pages 873-881.
    19. Xue, Kunpeng & Liu, Yu & Yu, Tao & Yang, Lei & Zhao, Jiafei & Song, Yongchen, 2023. "Numerical simulation of gas hydrate production in shenhu area using depressurization: The effect of reservoir permeability heterogeneity," Energy, Elsevier, vol. 271(C).
    20. Han Xue & Linhai Li & Yiqun Wang & Youhua Lu & Kai Cui & Zhiyuan He & Guoying Bai & Jie Liu & Xin Zhou & Jianjun Wang, 2024. "Probing the critical nucleus size in tetrahydrofuran clathrate hydrate formation using surface-anchored nanoparticles," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:15:y:2022:i:5:p:1939-:d:765883. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.