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Experimental Thermal Hazard Investigation of Pressure and EC/PC/EMC Mass Ratio on Electrolyte

Author

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  • Changcheng Liu

    (School of Environment and Safety Engineering, North University of China, Taiyuan 030051, China
    Institute of Advanced Energy Materials and Systems, North University of China, Taiyuan 030051, China)

  • Kaihui Zheng

    (School of Environment and Safety Engineering, North University of China, Taiyuan 030051, China)

  • Yong Zhou

    (State Key Laboratory of Fire Science, University of Science and Technology of China, Hefei 230026, China)

  • Kai Zhu

    (Business School, University of Shanghai for Science & Technology, Shanghai 200093, China)

  • Que Huang

    (School of Environment and Safety Engineering, North University of China, Taiyuan 030051, China
    Institute of Advanced Energy Materials and Systems, North University of China, Taiyuan 030051, China)

Abstract

Electrolytes are involved in the thermal runaway (TR) process of cells, which is a potential hazard in lithium-ion batteries (LIBs). Therefore, the effects of different mass ratio of carbonate solvents (ethylene carbonate (EC)/propylene carbonate (PC)/ethyl methyl carbonate (EMC)) with LiBF 4 and different environmental pressure on the combustion characteristics of electrolyte such as flame centerline temperature, mass loss rate (MLR) and heat release rate (HRR) were analyzed. The combustion process could be divided into four stages: ignition, stable combustion stage, stable combustion with flame color change stage and extinguishing; with the decrease of pressure, the MLR of electrolyte declined and the combustion time prolonged, while the temperature of flame centerline increased.

Suggested Citation

  • Changcheng Liu & Kaihui Zheng & Yong Zhou & Kai Zhu & Que Huang, 2021. "Experimental Thermal Hazard Investigation of Pressure and EC/PC/EMC Mass Ratio on Electrolyte," Energies, MDPI, vol. 14(9), pages 1-19, April.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:9:p:2511-:d:544721
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    References listed on IDEAS

    as
    1. Marie Francine Lagadec & Raphael Zahn & Vanessa Wood, 2019. "Characterization and performance evaluation of lithium-ion battery separators," Nature Energy, Nature, vol. 4(1), pages 16-25, January.
    2. M. Armand & J.-M. Tarascon, 2008. "Building better batteries," Nature, Nature, vol. 451(7179), pages 652-657, February.
    3. Changcheng Liu & Que Huang & Kaihui Zheng & Jiawen Qin & Dechuang Zhou & Jian Wang, 2020. "Impact of Lithium Salts on the Combustion Characteristics of Electrolyte under Diverse Pressures," Energies, MDPI, vol. 13(20), pages 1-15, October.
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