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Catalytic Decomposition of 2% Methanol in Methane over Metallic Catalyst by Fixed-Bed Catalytic Reactor

Author

Listed:
  • Ali Awad

    (Department of Chemical Engineering, University of Faisalabad, Faisalabad 38000, Pakistan
    Chemical Engineering Department, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia)

  • Israr Ahmed

    (School of Chemical and Material Engineering, National University of Science and Technology, Islamabad 44000, Pakistan)

  • Danial Qadir

    (Chemical Engineering Department, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia)

  • Muhammad Saad Khan

    (Mechanical Engineering Department, Texas A&M University at Qatar, Al Rayyan 5270, Qatar)

  • Alamin Idris

    (Department of Engineering and Chemical Sciences, Karlstad University, 651 88 Karlstad, Sweden)

Abstract

The structure and performance of promoted Ni/Al 2 O 3 with Cu via thermocatalytic decomposition (TCD) of CH 4 mixture (2% CH 3 OH) were studied. Mesoporous Cat-1 and Cat-2 were synthesized by the impregnation method. The corresponding peaks of nickel oxide and copper oxide in the XRD showed the presence of nickel and copper oxides as a mixed alloy in the calcined catalyst. Temperature program reduction (TPR) showed that Cu enhanced the reducibility of the catalyst as the peak of nickel oxide shifted toward a lower temperature due to the interaction strength of the metal particles and support. The impregnation of 10% Cu on Cat-1 drastically improved the catalytic performance and exhibited 68% CH 4 conversion, and endured its activity for 6 h compared with Cat-1, which deactivated after 4 h. The investigation of the spent carbon showed that various forms of carbon were obtained as a by-product of TCD, including graphene fiber (GF), carbon nanofiber (CNF), and multi-wall carbon nanofibers (MWCNFs) on the active sites of Cat-2 and Cat-1, following various kinds of growth mechanisms. The presence of the D and G bands in the Raman spectroscopy confirmed the mixture of amorphous and crystalline morphology of the deposited carbon.

Suggested Citation

  • Ali Awad & Israr Ahmed & Danial Qadir & Muhammad Saad Khan & Alamin Idris, 2021. "Catalytic Decomposition of 2% Methanol in Methane over Metallic Catalyst by Fixed-Bed Catalytic Reactor," Energies, MDPI, vol. 14(8), pages 1-12, April.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:8:p:2220-:d:537276
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    References listed on IDEAS

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    1. Awadallah, Ahmed E. & Aboul-Enein, Ateyya A. & Aboul-Gheit, Ahmed K., 2013. "Various nickel doping in commercial Ni–Mo/Al2O3 as catalysts for natural gas decomposition to COx-free hydrogen production," Renewable Energy, Elsevier, vol. 57(C), pages 671-678.
    2. Ashik, U.P.M. & Wan Daud, W.M.A. & Hayashi, Jun-ichiro, 2017. "A review on methane transformation to hydrogen and nanocarbon: Relevance of catalyst characteristics and experimental parameters on yield," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 743-767.
    3. Chan, Fan Liang & Tanksale, Akshat, 2014. "Review of recent developments in Ni-based catalysts for biomass gasification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 428-438.
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