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Thermal Analysis of Organic and Nanoencapsulated Electrospun Phase Change Materials

Author

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  • Evdoxia Paroutoglou

    (Department of the Built Environment, Division of Sustainability, Energy and Indoor Environment, Aalborg University, 2450 København SV, Denmark)

  • Peter Fojan

    (Department of Materials and Production, Aalborg University, 9220 Aalborg Ø, Denmark)

  • Leonid Gurevich

    (Department of Materials and Production, Aalborg University, 9220 Aalborg Ø, Denmark)

  • Göran Hultmark

    (Department of the Built Environment, Division of Sustainability, Energy and Indoor Environment, Aalborg University, 2450 København SV, Denmark)

  • Alireza Afshari

    (Department of the Built Environment, Division of Sustainability, Energy and Indoor Environment, Aalborg University, 2450 København SV, Denmark)

Abstract

Latent heat stored in phase change materials (PCM) can greatly improve energy efficiency in indoor heating/cooling applications. This study presents the materials and methods for the formation and characterization of a PCM layer for a latent heat thermal energy storage (LHTES) application. Four commercially available PCMs comprising the classes of organic paraffins and organic non-paraffins were selected for thermal storage application. Pure organic PCM and PCM in water emulsions were experimentally investigated. PCM electrospun microfibers were produced by a co-axial electrospinning technique, where solutions of Polycaprolactone (PCL) 9% w / v and 12% w / v in dichloromethane (DCM) were used as the fiber shell materials. PCM emulsified with sodium dodecyl sulfate (SDS), and Polyvinylalcohol 10% w / v (PVA) constituted the core of the fibers. The thermal behavior of the PCM, PCM emulsions, and PCM electrospun fibers were analyzed with differential scanning calorimetry (DSC). A commercial organic paraffin with a phase change temperature of 18 °C (RT 18) in its pure and emulsified forms was found to be a suitable PCM candidate for LHTES. The PVA-PCM electrospun fiber matrix of the organic paraffin RT18 with a PCL concentration of 12% w / v showed the most promising results leading to an encapsulation efficiency of 67%.

Suggested Citation

  • Evdoxia Paroutoglou & Peter Fojan & Leonid Gurevich & Göran Hultmark & Alireza Afshari, 2021. "Thermal Analysis of Organic and Nanoencapsulated Electrospun Phase Change Materials," Energies, MDPI, vol. 14(4), pages 1-15, February.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:4:p:995-:d:499198
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    References listed on IDEAS

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    1. Behzadi, S. & Farid, M.M., 2014. "Long term thermal stability of organic PCMs," Applied Energy, Elsevier, vol. 122(C), pages 11-16.
    2. Su, Weiguang & Darkwa, Jo & Kokogiannakis, Georgios, 2015. "Review of solid–liquid phase change materials and their encapsulation technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 48(C), pages 373-391.
    3. Rathod, Manish K. & Banerjee, Jyotirmay, 2013. "Thermal stability of phase change materials used in latent heat energy storage systems: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 246-258.
    4. Zhang, Xiyao & Niu, Jianlei & Wu, Jian-Yong, 2019. "Development and characterization of novel and stable silicon nanoparticles-embedded PCM-in-water emulsions for thermal energy storage," Applied Energy, Elsevier, vol. 238(C), pages 1407-1416.
    5. Salunkhe, Pramod B. & Shembekar, Prashant S., 2012. "A review on effect of phase change material encapsulation on the thermal performance of a system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 5603-5616.
    6. Shukla, Anant & Buddhi, D. & Sawhney, R.L., 2008. "Thermal cycling test of few selected inorganic and organic phase change materials," Renewable Energy, Elsevier, vol. 33(12), pages 2606-2614.
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    Cited by:

    1. Tomasz Tietze & Piotr Szulc & Daniel Smykowski & Andrzej Sitka & Romuald Redzicki, 2021. "Application of Phase Change Material and Artificial Neural Networks for Smoothing of Heat Flux Fluctuations," Energies, MDPI, vol. 14(12), pages 1-17, June.
    2. Evdoxia Paroutoglou & Peter Fojan & Leonid Gurevich & Alireza Afshari, 2022. "Thermal Properties of Novel Phase-Change Materials Based on Tamanu and Coconut Oil Encapsulated in Electrospun Fiber Matrices," Sustainability, MDPI, vol. 14(12), pages 1-20, June.
    3. Evdoxia Paroutoglou & Peter Fojan & Leonid Gurevich & Simon Furbo & Jianhua Fan & Marc Medrano & Alireza Afshari, 2022. "A Numerical Parametric Study of a Double-Pipe LHTES Unit with PCM Encapsulated in the Annular Space," Sustainability, MDPI, vol. 14(20), pages 1-16, October.
    4. Liu, Changhui & Xiao, Tong & Zhao, Jiateng & Liu, Qingyi & Sun, Wenjie & Guo, Chenglong & Ali, Hafiz Muhammad & Chen, Xiao & Rao, Zhonghao & Gu, Yanlong, 2023. "Polymer engineering in phase change thermal storage materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).
    5. Aramesh, M. & Shabani, B., 2022. "Metal foam-phase change material composites for thermal energy storage: A review of performance parameters," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).

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